Fate and health risk assessment of heavy metals in Brassica chinensis L. (pak-choi) and soil amended by sludge-based biochar.

Biochar is widely used in agriculture to efficiently solve the problem of sludge. In this study, sludge-based biochar (referred to as BC1, BC2, and BC3) was prepared by mixing sludge with FeCl, NaSiO, and Ca (HPO), respectively. Then, it was mixed with fresh soil to plant Brassica chinensis L.

Asymmetric synthesis of aryl/vinyl alkyl carbinol esters Ni-catalyzed reductive arylation/vinylation of 1-chloro-1-alkanol esters.

We report herein an asymmetric Ni-catalyzed cross-electrophile coupling approach to prepare enantioenriched aryl/vinyl alkyl carbinol esters through arylation/vinylation of easily accessible racemic 1-chloro-1-alkanol esters with aryl/vinyl electrophiles. The method features a broad substrate scope as demonstrated by more than 60 examples including the challenging chiral allylic esters. It tolerates a wide array of functional groups including alkenyl, carbonyl and free hydroxyl groups that may not survive in conventional carbonyl reduction and addition methods.

Understanding Motivation, Career Planning, and Socio-Cultural Adaptation Difficulties as Determinants of Higher Education Institution Choice Decision by International Students in the Post-pandemic Era.

The world is facing an unprecedented health crisis with the spread of COVID-19 across different corners of the globe. This pandemic has raised more significant concerns about international students' learning environment, personality development, and career planning, particularly in high-ranked institutes in China. Now the question concerning this dilemma is, would the COVID-19 pandemic negatively affect students' education and the country culture where they are bound to seek information and the subject education? Therefore, this study examines the impact of innovative learning environment, career planning, and socio-cultural adaptation-related difficulties faced by international students as determinants of higher education institution choice decisions made by international students in the post-pandemic era.

CR-GCN: Channel-Relationships-Based Graph Convolutional Network for EEG Emotion Recognition.

Electroencephalography (EEG) is recorded by electrodes from different areas of the brain and is commonly used to measure neuronal activity. EEG-based methods have been widely used for emotion recognition recently. However, most current methods for EEG-based emotion recognition do not fully exploit the relationship of EEG channels, which affects the precision of emotion recognition.

Domain Adaptation with Data Uncertainty Measure Based on Evidence Theory.

Domain adaptation aims to learn a classifier for a target domain task by using related labeled data from the source domain. Because source domain data and target domain task may be mismatched, there is an uncertainty of source domain data with respect to the target domain task. Ignoring the uncertainty may lead to models with unreliable and suboptimal classification results for the target domain task.

Recovery of silver from crystal silicon solar panels in Self-Synthesized choline Chloride-Urea solvents system.

Traditional acid-base leching technology is the primary technology to recycle silver from crystal silicon solar panels, which is fussy and often employs poisonous/harmful chemicals. In the present study, silver was easily recycled from photovoltaic panels in self-synthesized. Deep-Eutectic Solvents System (DESs) without pretreatments and the reaction system could be cyclically utilized.

An online method for monitoring atmospheric intermediate volatile organic compounds with a thermal desorption-gas chromatography/mass spectrometry.

As one of important precursors of secondary organic aerosol (SOA), intermediate volatile organic compounds (IVOCs) have attracted much attention in recent years. Most of the previous studies however largely focused on characteristics of IVOCs from different emission sources, while data from field observations to study their temporal variations was limited for lacking the sufficient time resolution monitoring data. In this study, an online thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS) method was developed to generate monitor data with a three-hour time resolution for gaseous atmospheric IVOCs.

Comparative study on direct and indirect methods for wet desulphurisation and denitrification based on micro-nano bubbles.

The wet desulphurisation and denitrification technique based on micro-nano bubbles, which is available by either D-method or I-method, is a promising novel process. By employing piped water, NaSO aqueous solution and HA-Na aqueous solution as the absorption liquids, a comparative study was conducted in this article on D-method and I-method to analyze their performance, advantages and disadvantages. It was accompanied by an investigation of how initial pH and initial temperature values of the absorption liquids affected the removal efficiency.

CuO/TiCTnanocomposites for detection of triethylamine gas at room temperature.

Triethylamine gas is one of the harmful volatile organic compounds for human health and the ecological environment. Therefore, in order to prevent the detrimental effects of triethylamine gas, it has greatly requirement to be accurately detected. Unfortunately, CuO has a low triethylamine gas response and slow recovery.

Spent LiFePO: An old but vigorous peroxymonosulfate activator for degradation of organic pollutants in water.

Iron-based catalysts have been demonstrated to activate peroxymonosulfate (PMS) to generate reactive radicals, which is however limited by their complex preparation process, high costs and inefficiency for practical applications. Herein we obtain spent LiFePO (SLFP), with powerful catalytic capacity by a simple one-step treatment of the retired LiFePO cathode material, for PMS activation to decontaminate organic pollutants. Lithium defects and oxygen vacancies in SLFP play critical roles for PMS utilization, further confirmed by density functional theory (DFT) calculations.

Cesium lead iodide electrospun fibrous membranes for white light-emitting diodes.

Inorganic perovskite cesium lead iodide nanocrystals (CsPbINCs) are good candidates for optoelectronic devices because of their excellent properties of remarkable luminous performance (high luminous efficiency, narrow luminous spectral line), and high photoelectric conversion efficiency by using simple preparation method. But their inherent poor stability greatly limits its practical applications. In this paper, electrospinning is used to grow fibrous membranes with embedded cesium lead iodide perovskite nanocrystals (PNCs) formedin a one-step process.

Generation estimation and material flow analysis of retired mobile phones in China.

The generation estimation of retired mobile phones is launched with the sales and new method using the revised sales data and amount of the subscribers. Several assumptions have been made due to the insufficient sources of the data. The sales data of legal mobile phones are calculated with the authoritative and continuous official data.

Application of Table Tennis Ball Trajectory and Rotation-Oriented Prediction Algorithm Using Artificial Intelligence.

The present work aims to accelerate sports development in China and promote technological innovation in the artificial intelligence (AI) field. After analyzing the application and development of AI, it is introduced into sports and applied to table tennis competitions and training. The principle of the trajectory prediction of the table tennis ball (TTB) based on AI is briefly introduced.

Research on an Improved Segmentation Recognition Algorithm of Overlapping .

The accurate identification of overlapping in a factory environment is one of the challenges faced by automated picking. In order to better segment the complex adhesion between , this paper proposes a segmentation recognition algorithm for overlapping . This algorithm calculates the global gradient threshold and divides the image according to the image edge gradient feature to obtain the binary image.

Impact of Carbon Tax and Subsidy Policies on Original Equipment Manufacturers and Remanufacturing Companies from the Perspective of Carbon Emissions.

To analyze the impact of government carbon tax and subsidy policies on the manufac turing industry in the context of carbon peaking and carbon neutrality. This paper constructs a game model based on two government policies: a "carbon tax" policy for the original product and a "subsidy" policy for the remanufactured product, taking the original product and the remanufactured product as the objects. The policy game model is used to study the impact of carbon taxes, government subsidies, and carbon emissions on product quality, sales, and corporate profits.

Deep Link-Prediction Based on the Local Structure of Bipartite Networks.

Link prediction based on bipartite networks can not only mine hidden relationships between different types of nodes, but also reveal the inherent law of network evolution. Existing bipartite network link prediction is mainly based on the global structure that cannot analyze the role of the local structure in link prediction. To tackle this problem, this paper proposes a deep link-prediction (DLP) method by leveraging the local structure of bipartite networks.

Mildly Peeling Off and Encapsulating Large MXene Nanosheets with Rigid Biologic Fibrils for Synchronization of Solar Evaporation and Energy Harvest.

Efficient and nondestructive liquid exfoliation of MXene with large lateral size has drawn growing research interest due to its outstanding properties and diverse potential applications. The conventional sonication method, though enabling a high production yield of MXene nanosheets, broke them down into submicrometric sizes or even quantum dots, and thus sacrificed their size-dependent properties, chemical stability, and wide applications. Herein, rigid biological nanofibrils in combination of mild manual shake were found to be capable of peeling off MXene nanosheets by attaching on MXene surfaces and localizing the shear force.

Advances of Drugs Electroanalysis Based on Direct Electrochemical Redox on Electrodes: A Review.

The strong development of mankind is inseparable from the proper use of drugs, and the electroanalytical research of drugs occupies an important position in the field of analytical chemistry. This review mainly elaborates the research progress of drugs electroanalysis based on direct electrochemical redox on various electrodes for the recent decade from 2011 to 2021. At first, we summarize some frequently used electrochemical data processing and electrochemical mechanism research derivation methods in the literature.

CAttSleepNet: Automatic End-to-End Sleep Staging Using Attention-Based Deep Neural Networks on Single-Channel EEG.

Accurate sleep staging results can be used to measure sleep quality, providing a reliable basis for the prevention and diagnosis of sleep-related diseases. The key to sleep staging is the feature representation of EEG signals. Existing approaches rarely consider local features in feature extraction, and fail to distinguish the importance of critical and non-critical local features.

Ion exchange to immobilize Cd(II) at neutral pH into silicate matrix prepared by co-grinding kaolinite with calcium compounds.

A novel silicate-based composite material was simply prepared by co-milling kaolinite and calcium compounds to endow the well studied clay minerals with active calcium for efficient removal of heavy metals. Batch experiments were carried out to investigate the main affecting factors such as raw material ratio, ball milling time, contact time, etc..

Coupling Electronic and Phonon Thermal Transport in Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) Nanofibers.

The thermal transport of Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) nanofiber is contributed by the electronic component of thermal conduction and the phonon component of thermal conduction. The relationship between the electrical conductivity and thermal conductivity of these conducting polymers is of great interest in thermoelectric energy conversation. In this work, we characterized the axial electrical conductivities and thermal conductivities of the single PEDOT:PSS nanofibers and found that the Lorenz number is larger than Sommerfeld value at 300 K.

Insights into antimicrobial agent sulfacetamide transformation during chlorination disinfection process in aquaculture water.

Antibiotic addition and chlorination are two common processes in fishery culture. Antibiotic residues not only pollute aquaculture water, but are also one of the potential precursors of disinfection by-products (DBPs) during chlorination. The degradation kinetics, products identification and reaction mechanism of sulfacetamide (SFA), a new sulfonamides antibiotics, and potential formation of haloacetic acids (HAAs) in chlorination were explored.

Interfacial Electrochemical Polymerization for Spinning Liquid Metals into Core-Shell Wires.

Metal wires are of great significance in applications such as three-dimensional (3D) printing, soft electronics, optics, and metamaterials. Ga-based liquid metals (e.g.

Microstructure and Magnetic Properties of Grain Boundary Insulated Fe/MnZnFeO Soft Magnetic Composites.

MnZnFeO nano-powder was coated on Fe microparticles by mechanical ball milling combined with high-temperature annealing. The effects of milling time on the particle size, phase structure and magnetic properties of core-shell powder were studied. Scanning electron microscopy (SEM), energy-dispersive spectroscopy and X-ray diffraction showed that the surface of the milled composite powder was composed of thin layers of uniform MnZnFeO insulating powder.

Superhydrophilic Modified Elastomeric RGO Aerogel Based Hydrated Salt Phase Change Materials for Effective Solar Thermal Conversion and Storage.

As a typical phase-change material (PCM) with high heat storage capacity and wide distribution, hydrated salts play broad and critical roles in solar energy utilization in recent years. However, the leakage and supercooling problems of hydrated salts have been a constraint to their further practical applications. In the current work, the super-hydrophilic reduced graphene oxide (RGO) aerogels modified by konjac glucomannan (KGM) as supporting structural materials are prepared by the hydrothermal reaction-freeze-drying, which can effectively absorb and convert visible sunlight energy into thermal energy.