Efficient cleavage of CO bond of lignin by synergistic electrocatalysis using a polyoxometalate catalyst with bimetallic sites.

This study reported a low-cost and highly efficient Dexter-Silverton polyoxometalate (POM)/Ni foam composite (NiCo-POM/NF) with bimetallic sites for acetophenone production. With this novel composite as an electrocatalyst, β-O-4 in 2-phenoxy-1-phenylethanol (PPE), a typical β-O-4 model, can be selectively oxidized to aromatic chemicals with excellent yields (62 %-74 %) by controlled-potential electrolysis. A PPE conversion of 99.

2D Porous TiC MXene as Anode Material for Sodium-Ion Batteries with Excellent Reaction Kinetics.

Sodium-ion batteries (SIBs) are a promising electrochemical energy storage system but face great challenges in developing fast-charging anodes. MXene-based composites are a new class of two-dimensional materials that are expected to be widely used in SIB energy storage due to their excellent electrical conductivity and stable structure. However, MXenes tend to experience interlayer stacking during preparation, which can result in poor electrochemical performance and a lower actual capacity compared to the theoretical value.

Construction of MnOMnO heterostructures to facilitate high-performance aqueous magnesium ion energy storage.

MnO-MnO heterostructure materials are applied in aqueous magnesium ion energy storage for the first time. The heterostructure yields an exceptionally high pseudocapacitance contribution, resulting in a specific capacitance of 313.5 F g at 1 A g, which contrasts with that of MnO (108.

K-birnessite-MnO/hollow mulberry-like carbon complexes with stabilized and superior rate performance for aqueous magnesium ion storage.

Manganese oxides are commonly employed as a cathode for magnesium ion storage in aqueous magnesium ion hybrid supercapacitors (MHS). However, sluggish reaction kinetics still hinders their practical application. Herein, we designed K-birnessite-MnO and electrostatically spun mulberry-like carbon composites (K-MnO/HMCs) an growth technique.

Simultaneously realizing enhancement of sensitivity for freshness monitoring and multinomial properties of carrageenan/konjac glucomannan/blueberry anthocyanin-based intelligent film by diatomite.

Here, highly sensitive blueberry anthocyanin (BBA)-induced intelligent indicating films were fabricated by incorporating a novel composite ingredient, diatomite (DA), into a matrix of konjac glucomannan (KGM), carrageenan (CAR) and BBA. We systematically investigated the effects of introducing DA and BBA on the structure, physical properties, colorimetric response, and practical application of the KGM/CAR film. Our findings revealed that the DA particles and BBA were well-distributed in the KGM/CAR matrix through hydrogen bonding interactions.

Probabilistic Keyphrase Generation From Copy and Generating Spaces.

Keyphrase generation is one of the most fundamental tasks in natural language processing (NLP). Most existing works on keyphrase generation mainly focus on using holistic distribution to optimize the negative log-likelihood loss, but they do not directly manipulate the copy and generating spaces, which may reduce the generability of the decoder. Additionally, existing keyphrase models are either unable to determine the dynamic numbers of keyphrases or produce the number of keyphrases implicitly.

Progress in the Study of Vortex Pinning Centers in High-Temperature Superconducting Films.

Since the discovery of high-temperature superconductors (HTSs), significant progress in the fabrication of HTS films has been achieved. In this review, we intend to provide an overview of recent progress in how and why superconductivity can be enhanced by introducing nanoscale vortex pinning centers. The comprehensive control of morphology, dimension, orientation and concentration of artificial pinning centers (APCs) and the principle of vortex pinning are the focus of this review.

Rumor detection driven by graph attention capsule network on dynamic propagation structures.

Rumor detection aims to judge the authenticity of posts on social media (such as Weibo and Twitter), which can effectively prevent the spread of rumors. While many recent rumor detection methods based on graph neural networks can be conducive to extracting the global features of rumors, each node of the rumor propagation structure learned from graph neural networks is considered to have multiple individual scalar features, which are insufficient for reflecting the deep-level rumor properties. To address the above challenge, we propose a novel model named graph attention capsule network on dynamic propagation structures (GACN) for rumor detection.

A Review on Strain Study of Cuprate Superconductors.

Cuprate superconductors have attracted extensive attention due to their broad promising application prospects. Among the factors affecting superconductivity, the effect of strain cannot be ignored, which can significantly enhance or degrade superconductivity. In this review, we discuss and summarize the methods of applying strain to cuprate superconductors, strain measurement techniques, and the influence of strain on superconductivity.

Optimized mesopores enable enhanced capacitance of electrochemical capacitors using ultrahigh surface area carbon derived from waste feathers.

Porous carbons with high specific surface area are critical engineering materials for current electrochemical capacitors (ECs) technology. Controlling the pore size distribution of porous carbons remains a significant challenge as it is a key aspect in many applications. Herein, we synthesized porous carbon as the electrode material of ECs by means of a two-step synthesis procedure using abandoned feathers as carbon precursor and potassium hydroxide as activating agent.

Polyaniline coated MOF-derived MnO nanorods for efficient hybrid capacitive deionization.

Mn-based oxides are efficient pseudocapacitive electrode materials and have been investigated for capacitive deionization (CDI). However, their poor conductivity seriously affects their desalination performance. In this work, polyaniline coated MnO nanorods (PANI/MnO) are synthesized by oxidizing a Mn-based metal organic framework (MOF) and subsequent in-situ chemical polymerization.

One-step production of N-O-P-S co-doped porous carbon from bean worms for supercapacitors with high performance.

In recent years, multi-heteroatom-doped hierarchical porous carbons (HPCs) derived from natural potential precursors and synthesized in a simple, efficient and environmentally friendly manner have received extensive attention in many critical technology applications. Herein, bean worms (BWs), a pest in bean fields, were innovatively employed as a precursor a one-step method to prepare N-O-P-S co-doped porous carbon materials. The pore structure and surface elemental composition of carbon can be modified by adjusting KOH dosage, exhibiting a high surface area ( ) of 1967.

A carbon-coated shuttle-like FeO/Fe S heterostructure derived from metal-organic frameworks with high pseudocapacitance for ultrafast lithium storage.

Pursuing active, low-cost, and stable electrode materials with superior rate capability and long-life cycling performances for lithium-ion batteries remains a big challenge. In this study, a carbon-coated shuttle-like FeO/Fe S heterostructure is synthesized by simply annealing Fe-based metal-organic frameworks (MIL-88(Fe)) as precursors and sublimed sulfur. Carbon-coated FeO/Fe S displays a unique structure with ultrafine FeO/Fe S nanoparticles distributed in the hollow and porous carbon matrix, which offers a large specific surface area and fast charge transfer ability, and alleviates the volume change upon cycling.

N, O and P co-doped honeycomb-like hierarchical porous carbon derived from for high performance supercapacitors.

Novel N, O and P co-doped honeycomb-like hierarchically porous carbon (N-O-P-HHPC) materials with a large specific surface area from were prepared a one-step activation and carbonization method and used as an electrode for supercapacitors. The results indicate that as-prepared N-P-HHPC with a large specific surface area (2068.9 m g) and N (1.

One-step preparation of N,O co-doped 3D hierarchically porous carbon derived from soybean dregs for high-performance supercapacitors.

Hierarchically porous carbon (HPC) material based on environmental friendliness biomass has spurred much attention, due to its high surface area and porous structure. Herein, three-dimensional (3D) N,O co-doped HPC (N-O-HPC) was prepared by using a one-step fabrication process of simultaneously carbonizing and activating soybean dregs and used as an electrode for supercapacitors (SCs). The obtained N-O-HPC with 4.

Electronic and Steric Tuning of an Atropisomeric Disulfoxide Ligand Motif and Its Use in the Rh(I)-Catalyzed Addition Reactions of Boronic Acids to a Wide Range of Acceptors.

A novel chiral disulfoxide ligand pair bearing fluorine atoms at the 6 and 6' position of its atropisomeric backbone, ( M, S, S)- and ( P, S, S)- p-Tol-6F-BIPHESO, was synthesized. Complexation to a rhodium(I) precursor gave rise to μ-Cl- and μ-OH-bridged rhodium dimer complexes incorporating the new ( M, S, S)- p-Tol-6F-BIPHESO ligand, while its sibling ( P, S, S)- p-Tol-6F-BIPHESO was not complexed efficiently to the rhodium precursor. The performance of this disulfoxide ligand [( M, S, S)- p-Tol-6F-BIPHESO] in catalysis was tested in both 1,4- and 1,2-addition reactions of arylboronic acids.

New, potentially chelating NHC ligands; synthesis, complexation studies, and preliminary catalytic evaluation.

Two new N-heterocyclic carbene (NHC) ligands bearing 2-morpholino and 2-piperidinyl naphthyl wingtips were synthesised (2-SIMorNap and 2-SIPipNap). Nuclear magnetic resonance studies, in conjunction with crystal structures and derivatisation of the NHC salts using a chiral counteranion, revealed that the ligand wingtips are oriented anti with respect to each other. From the free carbene, palladium, ruthenium and iridium complexes were prepared.

Smart stimuli-responsive spherical nanostructures constructed from supramolecular metallodendrimers via hierarchical self-assembly.

In this article, we present the design and construction of a series of supramolecular poly(benzyl ether) metallodendrimers featuring a well-defined hexagonal metallacycle at their cores via coordination-driven self-assembly. It was found that the second generation metallodendrimer 3c was able to hierarchically self-assemble into the regular vesicle-like structures. These nanoscale vesicles were monodisperse in shape and relatively monodisperse in size as detected in SEM, TEM, AFM, and DLS experiments.

Stimuli-responsive supramolecular gels through hierarchical self-assembly of discrete rhomboidal metallacycles.

A new class of supramolecular organometallic gels with a discrete rhomboidal metallacycle as the main skeleton was fabricated through hierarchical self-assembly (see figure). More importantly, by taking advantage of the dynamic nature of metal-ligand bonds, the stimuli-responsive gel-sol transition of the obtained gels was realized by disassembly and reassembly of the rhomboidal scaffold as controlled by bromide anions.

Synthesis of triangular metallodendrimers via coordination-driven self-assembly.

A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel "three-component" triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR ((1)H and (31)P), (1)H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.

Suppression of continuous lasing in a carbon nanotube polyimide film mode-locked erbium-doped fiber laser.

We demonstrated an erbium-doped mode-locked fiber laser using a single-walled carbon nanotube-dispersed polyimide (SWNT-PI) film. Different mode-locking operations were compared and analyzed utilizing SWNT-PI films with different concentrations (2, 1, and 0.25 wt.