Suppression of Charge Recombination by Growth of a TiO Passivation Layer on Ti-Doped Hematite Photoanodes for Boosted Photoelectrochemical Water Oxidation.

Hematite (α-FeO) represents a photoelectrode material that holds high potential to realize efficient and stable photoelectrochemical (PEC) hydrogen production due to its narrow bandgap for efficient solar absorption and good stability in alkaline electrolytes. However, pure α-FeO has been plagued by its poor conductivity with low carrier mobility and rapid charge recombination, which greatly hinder its photoelectrochemical applications. Herein, a hybrid photoanode is rationally designed by growing an amorphous TiO overlayer on a Ti-doped α-FeO nanorod photoanode to passivate surface states for improved PEC performance.

Uterine arteriovenous fistula: A case report and literature review.

Rationale: Uterine arteriovenous fistula (UAVF) is not very common and can occur after traumatic activities, such as surgery, delivery, miscarriage, and curettage. Previous studies have reported on the ultrasound and digital subtraction angiography (DSA) findings of UAVF; however, there are few reports on computed tomography (CT), CT angiography (CTA), and magnetic resonance imaging (MRI) findings. We report a case in which residual products of conception were diagnosed during an MRI, with an oversight of the presence of UAVF.

Role of vertebral fat fraction and R2* based on fat analysis and calculation technique in the quantitative assessment of osteoporosis.

Purpose: To investigate the diagnostic efficacy of vertebral fat fraction (FF) and R2* derived from the Fat Analysis and Calculation Technique (FACT) for Osteoporosis (OP) and explore their associations with clinical parameters.

Methods: A total of 123 patients with low back pain (59.1 ± 15.

Improved Hole Extraction in Carbon-Based CsPbIBr Perovskite Solar Cells through Interface Crystalline Reconstruction for High Open-Circuit Voltages over 1.37 V.

The interfacial charge recombination at the interface between the carbon electrode and the perovskite layer is a key factor limiting the device performance in the carbon-based hole-free system. The mainstream of the existing strategies is to improve the film quality through the addition of ligands or passivators. As the deposition process of carbon electrodes requires heat treatment, the use of conventional hole transport layer materials (such as Spiro-OMeTAD) is limited, leaving the hole extraction at the carbon-perovskite interface inefficient.

The value of Gd-EOB-DTPA-enhanced MRI in the differential diagnosis of HCC with hyperintensity on HBP and FNH.

The aim was to investigate the differential diagnostic potential of gadolinium-ethoxybenzyl-diethylenetriamine pentaacetic acid (Gd-EOB-DTPA)-enhanced magnetic resonance imaging (MRI) features and establish a nomogram model for distinguishing hepatocellular carcinoma (HCC) from focal nodular hyperplasia (FNH) presenting with hyperintensity on the hepatobiliary phase (HBP). This retrospective study enrolled 80 patients with pathologically confirmed HCC or FNH who underwent Gd-EOB-DTPA-enhanced MRI between January 2017 and December 2020. All lesions exhibited hyperintensity on HBP.

Exploring the Charge Dynamics in a Synergistically Modified BiVO Photoanode with La Doping and Cobalt-Based Phytate Compound Cocatalyst for Photoelectrochemical Water Oxidation.

Bismuth vanadate (BiVO) is a potential photoelectrode for photoelectrochemical (PEC) applications. Nevertheless, the rapid charge recombination and sluggish water oxidation kinetics greatly limit the PEC activity. To address these drawbacks, this study developed a cooperative modification strategy with simultaneous La doping and amorphous cobalt-phytate compound (Co-phy) as a cocatalyst on BiVO to raise the PEC performance.

CNT-Supported RuNi Composites Enable High Round-Trip Efficiency in Regenerative Fuel Cells.

Regenerative fuel cells hold significant potential for efficient, large-scale energy storage by reversibly converting electrical energy into hydrogen and vice versa, making them essential for leveraging intermittent renewable energy sources. However, their practical implementation is hindered by the unsatisfactory efficiency. Addressing this challenge requires the development of cost-effective electrocatalysts.

Concurrently Boosting Activity and Stability of Oxygen Reduction Reaction Catalysts via Judiciously Crafting Fe-Mn Dual Atoms for Fuel Cells.

The ability to unlock the interplay between the activity and stability of oxygen reduction reaction (ORR) represents an important endeavor toward creating robust ORR catalysts for efficient fuel cells. Herein, we report an effective strategy to concurrent enhance the activity and stability of ORR catalysts via constructing atomically dispersed Fe-Mn dual-metal sites on N-doped carbon (denoted (FeMn-DA)-N-C) for both anion-exchange membrane fuel cells (AEMFC) and proton exchange membrane fuel cells (PEMFC). The (FeMn-DA)-N-C catalysts possess ample dual-metal atoms consisting of adjacent Fe-N and Mn-N sites on the carbon surface, yielded via a facile doping-adsorption-pyrolysis route.

Case report: Clinical, imaging, and genetic characteristics of type B niemann pick disease combined with segawa syndrome diagnosed via dual gene sequencing.

Niemann Pick disease B (NPB) often presents with hepatosplenomegaly and lung pathological changes, but it usually does not present with central nervous system symptoms. This report presents the unique case of a 21-year-old woman with a 10-year history of hard skin and hepatosplenomegaly. Genetic sequencing revealed NPB and also suggested Segawa syndrome.

RuSe and CoSe Nanoparticles Incorporated Nitrogen-Doped Carbon as Efficient Trifunctional Electrocatalyst for Zinc-Air Batteries and Water Splitting.

The development of affordable, highly active, and stable trifunctional electrocatalysts is imperative for sustainable energy applications such as overall water splitting and rechargeable Zn-air battery. Herein, we report a composite electrocatalyst with RuSe and CoSe hybrid nanoparticles embedded in nitrogen-doped carbon (RuSeCoSe/NC) synthesized through a carbonization-adsorption-selenylation strategy. This electrocatalyst is a trifunctional electrocatalyst with excellent hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR) activities.

Enhanced photoelectrochemical performance of NiS-modified TiO nanorods with a surface charge accumulation facet.

Photoelectrochemical (PEC) water splitting for hydrogen production technology is considered as one of the most promising solutions to energy shortage and environmental remediation. TiO/NiS nanorod arrays were successfully prepared using hydrothermal deposition followed by the successive ionic layer adsorption and reaction (SILAR) method. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and photoluminescence (PL) spectra characterization studies indicate the successful deposition of NiS on TiO NRs.

Active sites engineering on FeNi alloy/CrC heterostructure for superior oxygen evolution activity.

Exploring high active electrocatalysts for oxygen evolution reaction (OER) is of great significance for a sustainable hydrogen economy. The development of non-precious transition metals, with sufficient active sites and ample intrinsic activity, remains a challenge. Herein, a new type of FeNi-CrC heterostructure anchored on carbon sheets (FeNi-CrC@C) was reported, which can effectively catalyze OER with swift kinetics and outstanding intrinsic activity.

Structurally Ordered PtNi Intermetallic Nanoparticles as Efficient and Stable Cathode Catalysts for Proton Exchange Membrane Fuel Cells.

Exploring oxygen reduction reaction (ORR) catalysts with superior electrochemical performance and long-term stability is crucial to the development of proton exchange membrane fuel cells (PEMFCs). In this work, graphited carbon with high specific surface area was obtained under relatively low temperature using Ni catalyst, then ordered nanoparticles (NPs) PtNi catalysts attaching to graphited carbon were synthesized via polyol reduction and thermal treatment. Benefiting from graphitized carbon support and appropriate order degree, PtNi/GC-700 NPs catalyst exhibits excellent electrocatalytic ORR performance with specific and mass activities as high as 2.

Wandering small intestinal stromal tumor: A case report.

Background: The occurrence of gastrointestinal stromal tumors (GISTs) in the small intestine is rare, and a case of wandering small intestinal stromal tumor has been rarely reported to date. Dissemination of this case can help inform future diagnosis and effective treatment.

Case Summary: A 68-year-old patient presented to us with tarry stools.

An Experimental Investigation of the Effect of Platinum on the Corrosion of Cathode Carbon Support in a PEMFC.

The possible role of platinum in the carbon corrosion at cell voltage higher than 1.0 V is controversial yet. To gain more insights into this issue, a square-wave potential cycles between 1.

Perspectives on Working Voltage of Aqueous Supercapacitors.

Aqueous supercapacitors have the superiorities of high safety, environmental friendliness, inexpensive, etc. High energy density supercapacitors are not conducive to manufacturing due to the limitation of water thermodynamic decomposition potential, resulting in a narrow working voltage window. To address such challenges, a great endeavor has started to investigate high voltage aqueous supercapacitors as well as making some progress.

Design of a High-Efficiency and -Gain Antenna Using Novel Low-Loss, Temperature-Stable LiTi-(CuNb)O Microwave Dielectric Ceramics.

Microwave dielectric ceramics are vital for filters, dielectric resonators, and dielectric antennas in the 5G era. It was found that the (CuNb) substitution can effectively adjust the TCF (temperature coefficient of resonant frequency) of LiTiO and simultaneously increase its × ( and denote the quality factor and the resonant frequency, respectively) value. Notably, excellent microwave dielectric properties (ε (permittivity) ≈ 18.

An ultra-broadband terahertz metamaterial coherent absorber using multilayer electric ring resonator structures based on anti-reflection coating.

We propose a method for achieving THz ultra-broadband coherent absorption using the anti-reflection theory of metamaterials. The metamaterial absorber consists of a periodic array of electric ring resonators with a multilayered structure which form the desired refractive index dispersion and provide continuous anti-reflection over a wide frequency range. The destructive interference mechanism and resonance absorption of the absorber are determined by simulation analysis and numerical simulation.

Growth of NiMn layered double hydroxides on nanopyramidal BiVO photoanode for enhanced photoelectrochemical performance.

Photoelectrochemical water oxidation for hydrogen generation via utilizing sunlight is considered a very promising pathway for generating sustainable energy in an environmental manner. Here, a composite photoanode, consisting of nanopyramidal BiVO arrays and one layered double hydroxide (NiMn-LDH) was designed and fabricated via a facile route. The obtained BiVO/NiMn-LDH composite photoelectrode presented a significant enhancement in the photoelectrochemical (PEC) current density, conversion efficiency and stability for solar water oxidation.

High-Performance Photoelectrochemical Water Oxidation with Phosphorus-Doped and Metal Phosphide Cocatalyst-Modified g-C N Formation Through Gas Treatment.

Graphitic carbon nitride (g-C N ) has been widely explored as a photocatalyst for water splitting. The anodic water oxidation reaction (WOR) remains a major obstacle for such processes, with issues such as low surface area of g-C N , poor light absorption, and low charge-transfer efficiency. In this work, such longtime concerns have been partially addressed with band gap and surface engineering of nanostructured graphitic carbon nitride (g-C N ).

Facile Synthesis of Ultrafine Hematite Nanowire Arrays in Mixed Water-Ethanol-Acetic Acid Solution for Enhanced Charge Transport and Separation.

Nanostructure engineering is of great significance for semiconductor electrode to achieve high photoelectrochemical performance. Herein, we report a novel strategy to fabricate ultrafine hematite (α-FeO) nanowire arrays in a mixed water-ethanol-acetic acid (WEA) solvent. To the best of our knowledge, this is the first report on direct growth of ultrafine (∼10 nm) α-FeO nanowire arrays on fluorine-doped tin oxide substrates through solution-based fabrication process.

Stability and Performance of Sulfide-, Nitride-, and Phosphide-Based Electrodes for Photocatalytic Solar Water Splitting.

With the past decade of worldwide sustained efforts on artificial photosynthesis for photocatalytic solar water splitting and clean hydrogen generation by dedicated researchers and engineers from different disciplines, substantial progress has been achieved in raising its overall efficiency along with finding new photocatalysts. Various materials, systems, devices, and better fundamental understandings of the interplay between interfacial chemistry, electronic structure, and photogenerated charge dynamics involved have been developed. Nevertheless, the overall photocatalytic performance is yet to achieve its maximum theoretical limit.

Synthesis and application of transition metal phosphides as electrocatalyst for water splitting.

With continuous research on photocatalytic water splitting, searching for efficient catalyst for hydrogen evolution reaction (HER) becomes popular topic in addition to main catalyst research. Transition metal phosphides are receiving intense attention due to its abundance in the Earth's crust and comparable catalytic properties to noble metals. In this review, the synthesis approaches, HER reaction mechanism, photocatalytic activity, approaches to improve the activity of transition metal phosphides were reviewed and discussed.

Enhanced photoelectrochemical water oxidation of bismuth vanadate via a combined strategy of W doping and surface RGO modification.

Nanoporous bismuth vanadate is modified simultaneously via tungsten doping and graphene surface modification for use as an efficient photoanode. The modified films were prepared on a FTO substrate by a drop-cast method followed by photoreduction of graphene oxide. SEM, XRD, Raman and XPS characterization was conducted to confirm the incorporation of tungsten and reduced graphene oxide (RGO), and to look into their influences on the structure and performance of BiVO.

Enhanced Bulk and Interfacial Charge Transfer Dynamics for Efficient Photoelectrochemical Water Splitting: The Case of Hematite Nanorod Arrays.

Charge transport in the bulk and across the semiconductor/electrolyte interface is one of the major issues that limits photoelectrochemical (PEC) performance in hematite photoelectrodes. Efficient charge transport in the entire hematite is of great importance to obtaining high photoelectrochemical properties. Herein, to reach this goal, we employed both TiO2 underlayer and overlayer deposition on hematite nanorod films, followed by a fast annealing treatment.