Exploring the complexity of methylphosphonic acid sorption on marine sediments: The influence of organic matter and environmental factors.

This study investigated the sorption characteristics of methylphosphonic acid (MPn) on marine sediments, focusing on the effects of sediment composition and environmental factors. The results indicated that MPn showed good stability on sediment samples and physical process was the main fraction for MPn sorption. Light fraction organic matter (LFOM) significantly enhanced the sorption ability of the sediments.

Occurrence, spatial and temporal distribution, sources and ecological risk assessment of halogenated polycyclic aromatic hydrocarbons (HPAHs) in sediments of the East China Sea.

Halogenated polycyclic aromatic hydrocarbons (HPAHs) in marine environment have attracted increasing attention due to their persistence, bioaccumulation potential, and ecological toxicity. However, systematic investigations on their contamination levels, compositional distribution, and source apportionment in the surface sediments of the East China Sea (ECS) remain limited. In this study, 25 HPAHs were quantitatively analyzed in ECS surface sediments, revealing total concentrations ranging from 14.

Polystyrene microplastics alter plankton community and enhance greenhouse gas emissions: A case study in the China coastal sea.

Brominated volatile halocarbons (Br-VHCs) emitted from the ocean are the main ozone-depleting substances and greenhouse gases, yet their production dynamics by microorganisms under anthropogenic stressors such as microplastics perturbation are unknown. Here, through coupled ship-based incubations (Yellow Sea) and laboratory experiments, we demonstrate that 1 μm polystyrene (PS) microplastics addition inhibited phytoplankton growth with maximal suppression rates of 82.35% and increased dissolved organic carbon (DOC) accumulation by 91.

Water mass mixing controls methane cycling and emission in highly hydrodynamic regions of the open ocean.

Ocean circulations and water mass exchange can exert significant influences on seawater biogeochemistry, microbial communities, and carbon cycling in marine systems. However, the detailed mechanisms of the impacts of physical processes in the open ocean on the cycle of greenhouse gases, particularly methane, remain poorly understood. In this study, we integrated high-resolution underway observations, experimental incubations, radioisotope labelling, and molecular analysis to constrain the controls of methanogenic pathways, methanotrophic activity, and emission fluxes in the highly hydrodynamic Kuroshio and Oyashio Extension (KOE) region of the Northwest Pacific.

Carbon monoxide cycling in the marginal sea: A case of the yellow sea and the east China sea.

This study investigated carbon monoxide (CO) dynamics in the Yellow Sea (YS) and the East China Sea (ECS) during spring, revealing significant spatial variability in surface CO concentrations (0.23-3.02 nmol L, mean 1.

Spectral characteristics of organic matter from algae and its complexation with copper: a case study of Ulva prolifera.

The changes in dissolved organic matter (DOM) during algal decay play a crucial role in the biochemical processes in nearshore ecosystems. The decay processes of Ulva prolifera under dark and light conditions were simulated in laboratory to investigate the characteristics of the DOM released during its settlement. The spectral characteristics of Ulva prolifera-DOM were analyzed using ultraviolet-visible spectra (UV-Vis) and fluorescence excitation-emission matrix spectroscopy combined with parallel factor analysis (EEMs-PARAFAC), and the copper complexation characteristics were evaluated by anodic stripping voltammetry (ASV).

Decreased Dimethylsulfide and Increased Polybrominated Methanes: Potential Climate Effects of Microplastic Pollution in Acidified Ocean.

Microplastic (MP) pollution and ocean acidification (OA) are pressing marine environmental concerns, but their combined impacts on short-lived biogenic climate-active gases and the resulting climate effects remain unclear. To address this gap, a ship-based microcosm experiment was conducted, where OA and MP pollution were simulated under in situ conditions to explore their effects on the production of dimethylsulfide (DMS), bromoform (CHBr), and dibromomethane (CHBr). The results indicated that both MP and OA inhibited phytoplankton growth and DMS concentration, with OA inducing further reductions in the production rate and yield of DMS.

Effect of organic carbon enrichment on halogenated organic pollutants in wetland sediments of the Yellow River Estuary and Jiaozhou Bay, China.

Coastal wetlands, vital ecosystems, are threatened by anthropogenic activities and act as significant sinks for halogenated organic pollutants (HOPs). Despite the persistent toxicity and ecological risks associated with HOPs, their spatial distribution and environmental behavior in coastal sediments, particularly the role of total organic carbon (TOC) in modulating their fate, remain poorly understood. We investigated the contamination characteristics of 25 halogenated polycyclic aromatic hydrocarbons (HPAHs) in the surface sediments of two coastal wetlands, the Yellow River estuary and Jiaozhou Bay, with different environmental backgrounds.

Photodegradation Mechanism of UV-328 in Natural Organic Matter Contexts Under Simulated Solar Irradiation.

2-(Benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol (UV-328), a widely utilized UV absorber in plastics and diverse products, has been frequently detected in the environment; yet, research on its photochemical degradation is scarce. Dissolved organic matter (DOM) and particulate organic matter (POM), as important components of natural organic matter, can produce photosensitization by absorbing photons. This study examined the influence of DOM from various sources on the photodegradation of UV-328 under simulated daylight conditions.

Vertical distributions of dimethyl sulfide and dimethylsulfoniopropionate and impacts of DMSP lyase and bacteria in the Yellow Sea and East China Sea.

Dimethyl sulfide (DMS), a degradation product of dimethylsulfoniopropionate (DMSP), is a significant trace gas influencing global temperature. This study examined the distribution of DMSP lyase activity (DLA) and the degradation of DMSP and dimethyl sulfoxide (DMSO) by bacteria to elucidate the influences of DMSP lyase and bacteria on the distributions of DMS and DMSP in the Yellow Sea and the East China Sea during the summer. We observed that DMS and DMSP concentrations in transect B, located near the Yellow Sea Cold Water Mass, declined with deepening water depth, coinciding with the changing trend of the temperatures.

Polyhalogenated carbazoles contamination in East China Sea sediments: Spatial distribution, source apportionment, and ecological risk assessment.

Polyhalogenated carbazoles (PHCZs), an emerging class of halogenated organic pollutants, have been widely detected in various environmental media, including sediments, soil, air, and organisms. The East China Sea (ECS) is a vital region for marine and fishery resource development in China, yet research on the pollution levels and sources of PHCZs in its sediments remains limited. This study reports the occurrence of seven PHCZs in the surface sediments of the ECS, with detection rates exceeding 90%.

Impact of salinity gradients on nitric oxide emissions and functional microbes in estuarine wetland sediments.

Estuarine wetland sediments are hotspots for nitrogen cycling and critical sources of atmospheric nitric oxide (NO). Yet studies on the impact of sediment salinity gradients on NO emissions and associated functional microbes at the land-ocean interface remain limited. Here, we measured sediment NO emission rates from incubated sediment samples that were collected from an estuarine wetland in Qingdao, China.

Nitric oxide release as a defense mechanism in marine microalgae against microplastic-induced stress.

Nitric oxide (NO) has garnered significant attention as a critical regulatory factor and signaling molecule in plant growth. However, the effects of microplastic pollution on the release of NO by algae have not been reported. Thus, in this study, the release of NO by Skeletonema costatum and Gymnodinium sp.

Responses of biogenic trace gases to atmospheric deposition and acid-processed atmospheric deposition in the oligotrophic western Pacific Ocean.

Dimethylsulfide (DMS) and very short-lived bromocarbons (VSL) are important biogenic trace gases emitted from oceans that can affect the global climate. Atmospheric deposition (AD) can provide nutrients and trace metals to the ocean, which can enhance primary productivity, but the complex effects of AD on DMS and VSL are still largely unexplored. A deck incubation experiment with aerosol additions was conducted to simulate the effects of acid-processed AD on the production of trace gases, including DMS and four VSL such as bromoform (CHBr), dibromomethane (CHBr), dibromochloromethane (CHBrCl), and bromodichloromethane (CHBrCl), in the oligotrophic western Pacific Ocean (WPO).

Distributions of DMS and DMSP and the influences of planktonic community assemblages in the Bohai Sea and Yellow Sea.

Dimethyl sulfide (DMS) and dimethylsulfoniopropionate (DMSP) are important sulfur compounds influenced by community assemblages of plankton. The distributions of DMS, DMSP, DMSP lyase activity (DLA), DMSP-consuming bacteria (DCB), and community structures of phytoplankton and zooplankton were investigated during summer in the Bohai Sea and Yellow Sea. The variety ranges of DMS, dissolved DMSP (DMSP), and particulate DMSP (DMSP) concentrations in the surface seawater were 1.

Sulfur metabolism and response to light in Ulva prolifera green tides.

The outbreak of Ulva prolifera blooms causes significant changes in the coastal sulfur cycle due to the high production of dimethylsulfoniopropionate (DMSP) and the emission of dimethylsulfide (DMS). However, the sulfur metabolism mechanism of U. prolifera has not been thoroughly investigated.

The Ocean Serves as a Net Source of Atmospheric Nitric Oxide but a Net Sink of Nitrogen Dioxide.

Nitrogen oxides (NO), comprised of nitric oxide (NO) and nitrogen dioxide (NO), play a crucial role in the global nitrogen cycle, but the oceanic occurrence remained unclear. Here, we show an integrated underway observation of oceanic and atmospheric NO and NO from the coastal seas to the open ocean in the northwestern Pacific Ocean (NWPO). The concentrations of NO and NO showed similar distribution patterns that the coastal seas with rich nitrogen nutrients showed higher levels, like the Yellow Sea (7.

Inter-annual and spatial variations of air-sea CO fluxes and acidification mechanism in the coastal waters of Qingdao, China during 2011-2019.

The interplay of global climate change and anthropogenic activities has significantly affected the carbon cycle in coastal ocean environments. Consequently, further investigation into the carbonate system, carbon source and sink processes, and acidification mechanisms is essential. This study examined the surface carbonate system offshore of Qingdao, utilizing data from nine spring cruises in 2011-2019.

Nitrogen oxides emissions from coastal wetland sediments: Experimental assessment of the influence of vegetation and nitrogen input.

Nitrogen oxides (NO = NO + NO) have essential impacts on global climate and the environment, making it essential to study the contribution of wetland-generated NO to environmental problems. With exogenous nitrogen input from anthropogenic activities, wetland sediments become active emission hotspots for NO. In this study, we conducted field experiments in a typical salt marsh wetland to measure nitric oxide (NO, the primary component of NO from sediments) exchange fluxes in both mudflat and vegetated sediments.

Microplastics and copper impacts on feeding, oxidative stress, antioxidant enzyme activity, and dimethylated sulfur compounds production in Manila clam Ruditapes philippinarum.

Microplastics (MPs) are widespread ocean pollutants and many studies have explored their effects. However, research on MPs combined impact with copper (Cu) on dimethylated sulfur compound production is limited. Dimethyl sulfide (DMS) is an important biogenic sulfur compound related to global temperatures.

Rapid cycling and emission of volatile sulfur compounds in the eastern Indian Ocean: Impact of runoff inputs and implications for balancing atmospheric carbonyl sulfide budget.

Volatile sulfur compounds, such as dimethyl sulfide (DMS), carbonyl sulfide (OCS), and carbon disulfide (CS), significantly influence atmospheric chemistry and climate change. Despite the oceans being an important source of these sulfides, the limited understanding of their biogeochemical cycles in seawater introduces considerable uncertainties in quantifying their oceanic emissions and assessing atmospheric OCS budgets. To address this issue, we conducted a comprehensive field survey in the tropical eastern Indian Ocean (EIO) to examine the spatial distributions, source-sink dynamics, and sea-air exchange fluxes of marine DMS, OCS, and CS.

Enhanced release of volatile halocarbons of microalgae in response to antibiotic-induced stress: Based on laboratory and ship-field experiments.

This study investigated the impacts of sulfamethazine (SMZ) and oxytetracycline (OTC) antibiotics on the marine microalgae Nitzschia closterium and its release of volatile halocarbons (VHCs), which contribute to ozone depletion and climate change. High concentrations of SMZ and OTC suppressed cell density, reduced chlorophyll a content, and hindered Fv/Fm elevation in N. closterium, indicating its growth was inhibited.

Comprehensive analysis of benzothiazoles (BTHs), benzotriazoles (BTRs), and benzotriazole ultraviolet absorbers (BUVs) in the western South China Sea: Spatial distributions, migration tendencies and ecotoxicological relevance.

Benzothiazoles (BTHs), benzotriazoles (BTRs), and benzotriazole ultraviolet absorbers (BUVs) have garnered significant attention owing to their persistent nature in the environment and adverse impacts on aquatic organisms. However, there remains a dearth of investigations and studies conducted in tropical marine environments. In this study, we undertook the inaugural distributional survey and ecotoxicological relevance of BTHs, BTRs, and BUVs in seawater and sediments of the western South China Sea (WSCS).

Impacts of nano- and micro-plastics exposure on zooplankton grazing, bacterial communities, and dimethylated sulfur compounds production in the microcosms.

Dimethyl sulfide (DMS) is a prevalent volatile organic sulfur compound relevant to the global climate. Ecotoxicological effects of nano- and microplastics (NPs and MPs) on phytoplankton, zooplankton, and bacteria have been investigated by numerous studies. Yet, the influences of NPs/MPs on dimethylated sulfur compounds remains understudied.