Occurrence, spatial and temporal distribution, sources and ecological risk assessment of halogenated polycyclic aromatic hydrocarbons (HPAHs) in sediments of the East China Sea.

Halogenated polycyclic aromatic hydrocarbons (HPAHs) in marine environment have attracted increasing attention due to their persistence, bioaccumulation potential, and ecological toxicity. However, systematic investigations on their contamination levels, compositional distribution, and source apportionment in the surface sediments of the East China Sea (ECS) remain limited. In this study, 25 HPAHs were quantitatively analyzed in ECS surface sediments, revealing total concentrations ranging from 14.

Effect of organic carbon enrichment on halogenated organic pollutants in wetland sediments of the Yellow River Estuary and Jiaozhou Bay, China.

Coastal wetlands, vital ecosystems, are threatened by anthropogenic activities and act as significant sinks for halogenated organic pollutants (HOPs). Despite the persistent toxicity and ecological risks associated with HOPs, their spatial distribution and environmental behavior in coastal sediments, particularly the role of total organic carbon (TOC) in modulating their fate, remain poorly understood. We investigated the contamination characteristics of 25 halogenated polycyclic aromatic hydrocarbons (HPAHs) in the surface sediments of two coastal wetlands, the Yellow River estuary and Jiaozhou Bay, with different environmental backgrounds.

Polyhalogenated carbazoles contamination in East China Sea sediments: Spatial distribution, source apportionment, and ecological risk assessment.

Polyhalogenated carbazoles (PHCZs), an emerging class of halogenated organic pollutants, have been widely detected in various environmental media, including sediments, soil, air, and organisms. The East China Sea (ECS) is a vital region for marine and fishery resource development in China, yet research on the pollution levels and sources of PHCZs in its sediments remains limited. This study reports the occurrence of seven PHCZs in the surface sediments of the ECS, with detection rates exceeding 90%.

Occurrence of halogenated organic contaminants in surface sediments of the Yangtze River estuary and its adjacent marine area.

Halogenated organic contaminants, such as chlorinated and brominated polycyclic aromatic hydrocarbons (Cl/Br-PAHs), are some of the most important emerging environmental pollutants. However, empirical data on Cl/Br-PAHs in estuarine and marine ecosystems are limited, rendering assessments of Cl/Br-PAH contamination in estuarine and offshore environments uncertain. Here the occurrence, sources, and ecological risks of 7 Cl-PAHs and 18 Br-PAHs were determined in surface sediments of the Yangtze River Estuary (YRE), a highly urbanized and industrialized area, and its adjacent marine area.

Cyclometalated Iridium(III) Complexes Containing 2-Phenylbenzo[d]oxazole Ligand: Synthesis, X-ray Crystal Structures, Properties and DFT Calculations.

Two new iridium(III) complexes were synthesized and fully characterized, [(bo)2Ir(pzpy)] (2a) and [(bo)2Ir(pzpyz)] (2b) (where bo = 2-phenylbenzo[d]oxazole, pzpy = 2-(1H-pyrazol-3-yl)pyridine, pzpyz = 2-(1H-pyrazol-3-yl)pyrazine). The single crystal structures of 2a-2b have been determined. Considering the relationship between their structures and photophysical properties, DFT calculations have been used to further support this inference.