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Single-atom iridium was interfacially engineered on CuFeS quantum dots (QDs) with highly efficient CO photoreduction performance. The electronic structure modulation yielded a remarkable CO yield rate of 32.5 μmol g h with 92.2% selectivity under atmospheric conditions. This work demonstrates the potential of single-atom interfacial engineering for advancing CO photoreduction.
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http://dx.doi.org/10.1039/d4cc05372a | DOI Listing |
J Org Chem
September 2025
State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China.
The first dearomative allylation of -(trialkylsilyl) benzyl chlorides with allyltributylstannane via RSi-Pd-π-benzyl intermediates is described. The reactions proceeded smoothly in the presence of a specific P,N hemilabile ligand to generate vinylsilanes bearing an allyl group in satisfactory to good yields. Systematic evaluation of phosphine ligands identified ESPmin and % Vbur (min) as key parameters correlating ligand structure with catalytic activity.
View Article and Find Full Text PDFPlant Physiol Biochem
August 2025
School of Life Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, China. Electronic address:
The PR10 (Pathogenesis-Related Protein 10) family plays a crucial role in plant defense and growth regulation, with unique hydrophobic cavities that bind various ligands, including phytohormones and alkaloids. Among them, Norcoclaurine Synthases (NCS) are key enzymes in benzylisoquinoline alkaloid (BIAs) biosynthesis, catalyzing the Pictet-Spengler reaction to form the precursor (S)-norcoclaurine. However, the evolutionary origins and functions of the PR10 family in BIA biosynthesis remain unclear.
View Article and Find Full Text PDFMed Eng Phys
October 2025
Department of Engineering Science, University of Oxford, United Kingdom. Electronic address:
Traditionally, clinical devices are designed, tested and improved through lengthy and expensive laboratory experiments and clinical trials [1]. More recently, computational methods have allowed for rapid testing, speeding up the design process and enabling far more complete searches of design space. While computational models cannot fully capture the complexities of biological systems, they provide valuable insights into crucial underlying mechanisms, such as the effects of fluid-structure interactions (FSIs).
View Article and Find Full Text PDFBioresour Technol
September 2025
State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, China.
The pyrolysis of flue-cured tobacco stalks (TS) faces challenges such as low bio-oil value and utilization efficiency. Existing studies have overlooked the anatomical heterogeneity of tobacco stalks, thereby limiting the directional regulation of high-value components, such as nicotine and phenolic compounds. This study divides TS into the husk (TSH), xylem (TSX), and pith (TSP), and investigates their physicochemical properties, pyrolysis behavior (through TGA and fixed-bed pyrolysis experiments), and interactions.
View Article and Find Full Text PDFJ Affect Disord
September 2025
Department of Psychiatry, Psychiatric Centre Copenhagen, Copenhagen, Denmark; Neurobiology Research Unit, Rigshospitalet, Copenhagen, Denmark; Faculty of Health and Medical Sciences, University of Copenhagen, Copenhagen, Denmark.
Background: Patients' beliefs about depression and different antidepressant treatment options may influence help-seeking behaviour, treatment adherence, and ultimately clinical outcomes. The Attitudes Toward Depression and its Treatment (ATDT) questionnaire was developed to assess these attitudes and beliefs; however, subsequent research revealed limitations in its psychometric properties. We sought to develop and validate a shortened version (ATDT-SF) with improved reliability.
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