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Inspired by electronic transistors, electric field gating has been adopted to manipulate ionic currents of smart nanofluidic devices. Here, we report a PNP nanofluidic bipolar junction transistor (nBJT) consisting of one polyaniline (PANI) layer sandwiched between two polyethylene terephthalate (PET) nanoporous membranes. The PNP nBJT exhibits three different responses of currents (quasi-linear, rectification, and sigmoid) due to the counterbalance between surface charge distribution and base voltage applied in the nanofluidic channels; thus, they can be switched by base voltage. Four operating modes (cutoff, active, saturation, and breakdown mode) occur in the collector response currents. Under optimal conditions, the PNP nBJT exhibits an average current gain of up to 95 in 100 mM KCl solution at a low base voltage of 0.2 V. The present nBJT is promising for fabrication of nanofluidic devices with logical-control functions for analysis of single molecules.
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http://dx.doi.org/10.1021/acs.nanolett.2c00312 | DOI Listing |
Angew Chem Int Ed Engl
September 2025
Yunnan Key Laboratory of Non-ferrous Metals Vacuum Metallurgy, Kunming University of Science and Technology, Kunming, 650093, China.
To address palladium supply-demand challenges and conventional recovery inefficiencies, this study develops a lithium-mediated electrodeposition process for efficient palladium recycling from spent catalysts. Density functional theory calculations identified a controlled Pd→LiPd (Pd)→LiPdO (Pd) transformation pathway, and experimental verification confirmed that LiPd precursors underwent oxidative transformation into LiPdO with structural inheritance. LiPdO exhibited Pd-O coordination and underwent rapid dissolution in dilute hydrochloric acid.
View Article and Find Full Text PDFAppl Radiat Isot
August 2025
Hunan University, Changsha, 410082, China.
Optimizing the collection chamber structure is critical for improving the reliability of electrostatic radon detectors, which are key to environmental and health risk monitoring. This study used COMSOL simulations to explore polonium-218 (Po, a radon progeny) ion collection parameters: chamber geometry, voltage, base material and structure, detector configuration, and edge electrification. Results showed that an uncharged base, combined with a detector protruding 2 mm above the base, enhances collection efficiency (CE); charged metal edge shielding boosts CE by 4-10 % without increasing collection time (CT); ∼2000 V balances peak CE and electromagnetic interference suppression.
View Article and Find Full Text PDFNat Commun
September 2025
National Key Laboratory of Advanced Micro and Nano Manufacture Technology, Shanghai Jiao Tong University, Shanghai, China.
The polarization switching pathway in HfZrO-based ferroelectric thin film is still not well clarified and agreed, limiting the fundamental physical understanding and performance engineering. The key question lies in clarifying the transient intermediate state during the polarization switching of orthorhombic phase. In this work, by designing the ferroelectric and dielectric stacks, we theoretically and experimentally demonstrate a polarization switching pathway through an orthorhombic-tetragonal-orthorhombic phase transition in ferroelectric HfZrO where the non-polar tetragonal phase is metastable.
View Article and Find Full Text PDFWien Klin Wochenschr
September 2025
Private Clinic, Spitalgasse 19, 1090, Vienna, Austria.
Introduction: High-voltage electrical injuries from train surfing pose a unique challenge, often involving severe burns and multisystem trauma. This study retrospectively analyzed train surfing injuries over 30 years, with a focus on trauma-associated diagnoses and comparing them to work-related high-voltage injuries.
Methods: A retrospective review of 87 high-voltage injury cases was conducted, including 30 train surfing and 57 work-related cases.
Angew Chem Int Ed Engl
September 2025
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 585 He Shuo Road, Shanghai, 201899, China.
Fluoride ion batteries (FIBs), as a promising next-generation high-energy-density storage technology, have attracted significant attention. However, developing an ideal fluoride-ion electrolyte that suppresses the β-H abstraction (caused by strong Lewis-basicity F) and electrolyte decomposition remains challenging. To address this bottleneck, we design an electrolyte system based on commercial tetrabutylammonium fluoride (TBAF) salt and 1-butyl-3-methylimidazolium tetrafluoroborate (BMImBF) ionic liquid solvent through anion-cation coordination engineering and hard-soft-acid-base (HSAB) balance modulation, unveiling its multiscale mechanisms for mitigating interfacial parasitic reaction and enhancing metal anode stability.
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