Insight into the characteristics of carbonaceous aerosols at urban and regional sites in the downwind area of Pearl River Delta region, China.

Carbonaceous aerosols (CAs) take up a substantial fraction of fine particle (PM) in the atmosphere, yet high temporal resolution and seasonal variations of their emission sources and formation mechanisms are still poorly characterized in the regions with strong anthropogenic activities. In this study, the spatiotemporal characteristics of CAs and their subfractions, i.e., organic carbon (OC) and elemental carbon (EC), were studied in one of China's key city clusters, the Pearl River Delta (PRD) region. Results show that the annual mean OC and EC concentrations are 5.89 ± 3.32 μg/m and 1.60 ± 1.00 μg/m at the urban site, respectively. Such levels are consistently higher than those at the regional site (4.94 ± 3.34 μg/m of OC and 1.45 ± 0.82 μg/m of EC), suggesting the strong impact of human activities on OC and EC concentration. Moreover, the OC concentration peak sharply appears at 19:00 across all seasons at the urban site due to the direct influence of traffic exhaust and cooking activities. At regional site, OC peaks in fall afternoon due to intensive photochemical reactions derived combustion-related secondary organic carbon (SOC) contributions to the downwind PRD region. Correlations between SOC and influence factors were found at both regional and urban sites, suggesting that SOC formation is more regionally homogenous and mainly originates from the Zhaoqing-Foshan-Jiangmen belt. In addition, there are significantly different formation mechanisms of non-combustion-related secondary organic carbon (SOC) in the downwind PRD region. This study provides a solid evidence for collaborative efforts in the mitigation of secondary aerosols in the PRD region.