Multi-spectral GeSe/PbTe phototransistor for wearable optical medicine.

Flexible photodetectors play a crucial role in improving human healthcare. However, the narrow spectral detection range, poor stress stability, and non-degradability of traditional flexible photodetectors significantly hinder the further development of wearable medical devices. In this study, a printable phototransistor was developed with excellent dynamic performance (detectivity of 7.

The Impact of Attribution Training on Emotional and Functional Recovery in Elderly Patients Undergoing Total Knee Arthroplasty: A Single-Center Randomized Controlled Trial.

Objective: This study aims to explore the effects of attribution training on postoperative negative emotions, attributional styles, and knee joint function in elderly patients who have undergone total knee arthroplasty (TKA).

Methods: A total of 76 elderly patients who underwent TKA were selected and randomly divided into an intervention group and a control group in this prospective randomized controlled study. All patients received routine postoperative care, while the intervention group also underwent eight sessions of attribution training intervention, each lasting 60 minutes.

Hollow mesoporous metal-nitrogen-carbon electrocatalysts with enhanced oxygen reduction activity for zinc-air batteries.

While great advances have been achieved in Zn-air batteries, porous cathode catalysts remain crucial and challenging to promote diffusion and boost oxygen reduction reaction (ORR). Herein, an effective strategy has been developed for the synthesis of hollow metal-nitrogen-carbon electrocatalysts to achieve the macro-/meso-/microporous structure. The h-CuNC electrocatalyst exhibits good stability and high ORR activity with a half-wave potential of 0.

Structural Basis of Ultralow Capacitances at Metal-Nonaqueous Solution Interfaces.

Metal-nonaqueous solution interfaces, a key to many electrochemical technologies, including lithium metal batteries, are much less understood than their aqueous counterparts. Herein, on several metal-nonaqueous solution interfaces, we observe capacitances that are 2 orders of magnitude lower than the usual double-layer capacitance. Combining electrochemical impedance spectroscopy, atomic force microscopy, and physical modeling, we ascribe the ultralow capacitance to an interfacial layer of 10-100 nm above the metal surface.

In Situ Optical Observation of Lithium Dendrite Pattern in Solid Polymer Electrolytes.

Solid polymer electrolytes (SPEs) have been treated as a viable solution to build high-performance solid-state lithium metal batteries (SSLMBs) at the industrial level, bypassing the safety and energy density dilemmas experienced by today's lithium-ion battery technology. To promote a wider application of SPEs-based SSLMBs, the chemical and electrochemical characteristics of lithium metal (Li°) electrode in SPEs have to be clearly elucidated. In this work, the morphological evolution of Li° electrode in the SPEs-based SSLMBs is comprehensively investigated, via a customized electrochemical cell allowing optical microscopic analyses.

Evaluation of Polymetallic Phosphide Cathodes for Sodium-Air Batteries by Distribution of Relaxation Time.

Sodium-oxygen batteries are emerging as a new energy storage system because of their high energy density and low cost. However, the cycling performance of the battery is not satisfying due to its insulating discharge product. Here, we synthesized metallic phosphides with gradient concentration (g-CoNiFe-P) and their uniform counterpart (CoNiFe-P) as cathode catalysts in a Na-O battery.

Determinants of the Surface Film during the Discharging Process in Lithium-Oxygen Batteries.

Lithium-oxygen batteries have one of the highest theoretical capacities and specific energies, but several challenges remain. One of them is premature death caused by a passivation layer with poor conductivities (both electronic and ionic) on the electrode surface during the discharge process. Once this thin layer forms on the surface of the catalyst and substrate, the overpotential significantly increases and causes early cell death.

Thoracic empyema due to nontuberculous mycobacteria in an immunocompetent patient without pulmonary disease: a case report.

Background: Pleural involvement by non-tuberculous mycobacteria (NTM), especially NTM empyema in the immunocompetent patient without pulmonary diseases is a rare disease. It is difficult to diagnose with only a few cases of immunodeficient patients in the literature.

Case Presentation: We describe a 63-year-old male with empyema due to NTM and highlight the challenges of diagnosis.

One-step cladding metal oxide nanowires with a carbon-dots-embedded ZnO amorphous layer toward boosted photoelectrochemical water oxidation.

An effective method was proposed for constructing carbon dots (CDs)-sensitized multijunction composite photoelectrodes via one-step cladding a CDs-embedded ZnO amorphous overlayer on vertically aligned metal oxide nanowires. This strategy involved the double role of hexamethylenetetramine (HMTA) in the ethylene glycol (EG) solvent mixed with a controllable trace amount of water. In the water-deficient synthetic system, a limited portion of HMTA served as the pH buffer and hydroxyl source to force the hydrolytic process of zinc ions for the production of ZnO.

Highly selective CO electroreduction to CO by the synergy between Ni-N-C and encapsulated Ni nanoparticles.

Efficient catalysts are highly desirable for the selective electrochemical CO reduction reaction (CORR). Ni single-atom catalysts are known as promising CORR catalysts, while Ni NPs are expected to catalyze the competing HER. In this work, we have modified the Ni NPs by encapsulating them into porous Ni-N-C nanosheets (Ni@Ni-N-C), to boost the synergy between Ni NPs and dispersed Ni-N species towards CORR.

Heteroatom-doped carbon sheets as metal-free electrocatalysts for promoting the oxygen reduction reaction in Zn-air batteries.

Zn-air batteries are promising energy devices for future sustainable development. It is crucial to promote the cathodic reaction, oxygen reduction reaction (ORR), by applying active electrocatalysts. Herein, a metal-free ORR electrocatalyst has been fabricated by doping S and N atoms into carbon sheets (S-N-C), and it displays high ORR activity and outstanding performance in Zn-air batteries.

Molecular sieving of semiconductive NTU-9 coatings on titanium dioxide nanowire arrays: Augmented yet selective photoelectrochemical response enabled by boosting charge separation and transfer in confined space.

Radial heterostructures with titanium dioxide (TiO) nanowire as core and NTU-9 as shell are synthesized via a surfactant-free approach based on the favorable bonding of linkers with TiO nanowire. Relative to the traditional growth strategy of surface modification, the thin NTU-9 shell with ordered arrangement of two-dimensional networks is uniformly formed on the sidewalls of TiO nanowire through the orientational growth process. Using the core-shell nanowire arrays as photoanodes, wide-range light absorption and high charge carrier separation efficiency are achieved due to the conjugation of NTU-9, leading to enhanced water oxidation performance in photoelectrochemical (PEC) water splitting.

Successful treatment of rapid progressive interstitial lung disease in a case of anti-Zo antibody positive anti-synthetase syndrome.

Background: Anti-synthetase syndrome (ASS) is a chronic multisystemic autoimmune disease characterized by detectable anti-aminoacyl-transfer-RNA antibodies. Interstitial lung disease (ILD) in anti-synthetase syndrome patients is often severe and rapidly progressive. Anti-Zo (phenylalanyl) antibody is reported rarely in ASS.

Enhanced activity towards oxygen electrocatalysis for rechargeable Zn-air batteries by alloying Fe and Co in N-doped carbon.

Large-scale application of rechargeable Zn-air batteries requires low-cost electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as alternatives to noble metals. Herein, FeCo nanoparticles embedded in N-doped carbon (FeCo/N-C) were prepared by a two-step pyrolysis route. FeCo/N-C exhibits excellent activities toward both the ORR (half-wave potential of 0.

Redox Mediator-Enhanced Performance and Generation of Singlet Oxygen in Li-CO Batteries.

Rechargeable Li-CO batteries as a novel system developed in recent years directly use CO as the reactant, which enables deeper penetration of energy storage and CO utilization. The Li-CO battery system, however, is at an early stage, and many challenges remained to be overcome urgently, especially the problem of high over-potential during the charging process. Here, we report a redox mediator, phenoxathiin, to assist the decomposition of LiCO during the charging process, which effectively reduces the over-potential and improves the cycling performance of the battery.

Diagnosing the SEI Layer in a Potassium Ion Battery Using Distribution of Relaxation Time.

Understanding the solid electrolyte interphase (SEI) formation process in novel battery systems is of primary importance. Alongside increasingly powerful in situ techniques, searching for readily accessible, noninvasive, and low-cost tools to probe battery chemistry is highly demanded. Here, we applied distribution of relaxation time analysis to interpret in situ electrochemical impedance spectroscopy results during cycling, which is able to distinguish various electrochemical processes based on their time constants.

Fast operando spectroscopy tracking in situ generation of rich defects in silver nanocrystals for highly selective electrochemical CO reduction.

Electrochemical CO reduction (ECR) is highly attractive to curb global warming. The knowledge on the evolution of catalysts and identification of active sites during the reaction is important, but still limited. Here, we report an efficient catalyst (Ag-D) with suitable defect concentration operando formed during ECR within several minutes.

Optimal utilization of fluoroethylene carbonate in potassium ion batteries.

This work provides a novel strategy of optimal utilization of fluoroethylene carbonate to generate a uniform and compact solid electrolyte interface film, enhancing the cycle life of potassium ion batteries. With K foil being treated with fluoroethylene carbonate prior to use, enhanced cycling performance up to 1200 hours was achieved. Combining in situ electrochemical impedance spectroscopy with the distribution of relaxation time analysis and XPS analysis, the solubility of KF in the electrolyte is proposed as a crucial factor to determine the quality of a solid electrolyte interface.

A defective g-CN/RGO/TiO composite from hydrogen treatment for enhanced visible-light photocatalytic H production.

Photocatalytic H2 evolution is a clean technology to alleviate energy and environmental issues. The limited light absorption and the separation efficiency of photogenerated charge carriers are the major hurdles constraining the application of numerous photocatalysts. Herein, we report a simple and effective strategy, a multistep heat-treatment method, to synthesise a defective g-C3N4/RGO/TiO2 composite to increase its rate of activity for H2 production.

A β-FeOOH/MXene sandwich for high-performance anodes in lithium-ion batteries.

FeOOH is one of the earth abundant and high-capacity anode materials for lithium-ion batteries (LIBs), but faces problems of inevitable structure collapse and thus poor capacity retention. Herein, we report a composite of β-FeOOH/TiCT MXene sandwich by an intercalation of β-FeOOH nanorods within single-layer TiCT MXene flakes. After 100 cycles, the β-FeOOH/TiCT composite retains a capacity of 937.

Interlaced Pd-Ag nanowires rich in grain boundary defects for boosting oxygen reduction electrocatalysis.

Given the high cost and poisoning issues of Pt, developing Pd-based catalysts as substitutes is highly essential. Although substantial progress has been made, the synthesis of Pd-based electrocatalysts with both high activity and stability in the oxygen reduction reaction (ORR) remains a challenge. In this work, we prepared Pd-Ag nanowires with up to micro-sized length and a diameter of ∼17 nm via a facile modified polyol method.

Improving photoelectrochemical response of ZnO nanowire arrays by coating with p-type ZnO-resembling metal-organic framework.

Coupling semiconducting metal-organic frameworks (MOFs) with metal oxide (MO) semiconductor nanowires is an efficient solution to tune the photoelectric properties of both the parties. In this report, we demonstrate a facile surfactant-free growth strategy for modification of zinc oxide (ZnO) single-crystal nanowire arrays (NWAs) with the MOF zinc glycolate (noted as Zn-GA) that contains an embedded continuous 3D Zn-O network. Due to the structural resemblance of the Zn-O network between Zn-GA and ZnO, the prepared ZnO@Zn-GA nanowires present a tight contact at the core-shell interface in a partially epitaxial manner, and the loading amount of Zn-GA can be well controlled in the synthetic process.

Disproportionation of Sodium Superoxide in Metal-Air Batteries.

The sodium oxygen battery is a promising metal-air battery; however, the discharge process is not well understood and the major discharge product is still under debate. The discharge products determined the theoretical specific energy and electrochemical performance of the battery. Now it is demonstrated that NaO spontaneously disproportionates to Na O , no matter whether it is dissolved in solution or stays on the surface.