Piezocatalytic HO Production from Pure Water over a TiO/ZnO Heterojunction through a Dual-Channel Pathway.

Langmuir

Guangxi Key Laboratory of Low Carbon Energy Materials, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, China.

Published: September 2025


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Article Abstract

Piezocatalytic HO generation has emerged as a promising alternative for sustainable HO synthesis, yet its development is hindered by unsatisfactory energy conversion efficiency. Herein, a TiO/ZnO piezocatalyst was developed by dispersing ZnO nanorods within a TiO nanosheet substrate, enabling efficient HO generation in pure water. By constructing a heterostructure, we developed an effective strategy to enhance charge carrier separation and migration through a built-in electric-field-induced piezoelectric effect, thereby demonstrating the superior piezocatalytic performance of the TiO/ZnO composite. Compared to pure TiO and ZnO, the TiO/ZnO heterojunction exhibited significantly enhanced piezocatalytic HO production, achieving a yield of 2078.14 μmol·g·h in pure water, surpassing most reported piezocatalysts. Reactive species analysis revealed a dual-channel HO generation mechanism, featuring an oxygen reduction reaction (ORR)-dominated pathway with a minor contribution from the water oxidation reaction (WOR). Furthermore, TiO/ZnO exhibits excellent piezocatalytic performance in degrading various pollutants. This work provides valuable insights into piezocatalytic HO generation and offers a potential pathway for the green and sustainable synthesis of HO.

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http://dx.doi.org/10.1021/acs.langmuir.5c03399DOI Listing

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