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Piezocatalytic HO generation has emerged as a promising alternative for sustainable HO synthesis, yet its development is hindered by unsatisfactory energy conversion efficiency. Herein, a TiO/ZnO piezocatalyst was developed by dispersing ZnO nanorods within a TiO nanosheet substrate, enabling efficient HO generation in pure water. By constructing a heterostructure, we developed an effective strategy to enhance charge carrier separation and migration through a built-in electric-field-induced piezoelectric effect, thereby demonstrating the superior piezocatalytic performance of the TiO/ZnO composite. Compared to pure TiO and ZnO, the TiO/ZnO heterojunction exhibited significantly enhanced piezocatalytic HO production, achieving a yield of 2078.14 μmol·g·h in pure water, surpassing most reported piezocatalysts. Reactive species analysis revealed a dual-channel HO generation mechanism, featuring an oxygen reduction reaction (ORR)-dominated pathway with a minor contribution from the water oxidation reaction (WOR). Furthermore, TiO/ZnO exhibits excellent piezocatalytic performance in degrading various pollutants. This work provides valuable insights into piezocatalytic HO generation and offers a potential pathway for the green and sustainable synthesis of HO.
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http://dx.doi.org/10.1021/acs.langmuir.5c03399 | DOI Listing |
Inorg Chem
September 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China.
Photocatalysis has emerged as a promising strategy to address water pollution caused by heavy metals and antibiotics. Zeolites exhibit significant potential in petrochemical catalysis; however, the development of zeolite-based photocatalysts remains a critical challenge for researchers. Herein, a novel Z-scheme heterojunction was designed and fabricated on the titanium-silicon zeolite TS-1 by modifying g-CN via a simple calcination process.
View Article and Find Full Text PDFGen Physiol Biophys
September 2025
Faculty of Exact and Natural Sciences, I. Javakhishvili Tbilisi State University, Tbilisi, Georgia.
In this study, both pure and calcium-containing complex liposomes made from DPPC phospholipids were investigated using calorimetric and spectrophotometric methods. Liposomes were prepared using a new technology in both water and a 20% glycerol aqueous solution. Glycerol allows drug-containing DPPC liposomes to penetrate the dermis of the skin through the epidermis.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
School of Chemical Sciences & Technology, School of Materials and Energy, Yunnan Provincial Center of Technology Innovation for New Materials and Equipment in Water Pollution Control, Yunnan Institute of Frontier Technologies in Water Treatment, Yunnan University, Kunming 650091, P. R. China. jqwang
In this work, a novel organic heterojunction of polydopamine (PDA)@covalent organic framework (COF) was efficiently synthesized the sonochemical method, leveraging the multifunctional properties of PDA as nucleation sites for COF shell (sonoTp-TAPB) growth. The as-prepared PDA@sonoTp-TAPB hierarchical structure delivers a photocatalytic HO production rate of 728.4 μmol g h in pure water.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, P.R. China.
Urea photosynthesis from CO and N has profound environmental and energy implications. However, the simultaneous activation of CO and N, along with the promotion of C─N bond formation, remains a major challenge. Herein, the asymmetric interfacial sites (Zn─O─Ti) were engineered by building oxygen atom bridges between ZIF-8 and MIL-125 to enable efficient photocatalytic urea synthesis.
View Article and Find Full Text PDFNano Lett
September 2025
KU-KIST Graduate School of Converging Science and Technology, Korea University, Seoul 02841, Republic of Korea.
Sorafenib, a clinically approved multityrosine kinase inhibitor, exhibits poor aqueous solubility, which limits its bioavailability and therapeutic efficacy. In this study, we introduce a solvent-directed self-assembly strategy to modulate the nanostructure of sorafenib without the use of external carriers or complex formulation techniques. In pure water, sorafenib forms large lamellar aggregates, whereas in 30% methanol-water mixtures, it self-assembles into uniform spherical particles approximately 450 nm in diameter.
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