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Since the discovery of the high-temperature superconductors HS and LaH under high pressure, compressed hydrides have received extensive attention as promising candidates for room-temperature superconductors. As a result of current high-pressure theoretical and experimental studies, it is now known that almost all the binary hydrides with a high superconducting transition temperature ( ) require extremely high pressure to remain stable, hindering any practical application. In order to further lower the stable pressure and improve superconductivity, researchers have started exploring ternary hydrides and had many achievements in recent years. Here, we discuss recent progress in ternary hydrides, aiming to deepen the understanding of the key factors regulating the structural stability and superconductivity of ternary hydrides, such as structural motifs, bonding features, electronic structures, electron-phonon coupling, etc. Furthermore, the current issues and challenges of superconducting ternary hydrides are presented, together with the prospects and opportunities for future research.
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http://dx.doi.org/10.1093/nsr/nwad307 | DOI Listing |
Adv Sci (Weinh)
September 2025
Institute of High Pressure Physics, School of Physical Science and Technology, Ningbo University, Ningbo, 315211, P. R. China.
Hydride superconductors have attracted significant attention, yet achieving superconductivity at ambient pressure remains a key challenge. Here, a family of high-T (superconducting critical temperature, T) hydrides based on the fluorite-type AXH structure, exhibiting thermodynamic and dynamic stability at low to atmospheric pressure, is proposed. Through comprehensive screening of 150 ternary systems, eight stable hydrides below 35 GPa are identified.
View Article and Find Full Text PDFPhys Chem Chem Phys
July 2025
Bond and Band Engineering Group, School of Physical Science and Technology, Southwest Jiaotong University, Chengdu 610031, People's Republic of China.
Inspired by the high-temperature superconductivity of LaScH at room temperature, we substitute La with the A-site element and investigate the superconducting and stability properties of the ternary hydrides AScH (A = Y, La, Ac) under high-pressure conditions. First-principles calculations reveal that the predicted structure AcScH not only remains dynamically stable under ultrahigh pressures (400-500 GPa) but also exhibits notable superconducting transition temperatures () around 207.6 K at 400 GPa.
View Article and Find Full Text PDFNanomaterials (Basel)
April 2025
Department of Physics, Gachon University, 1342 Seongnam-daero, Sujeong-gu, Gyeonggi-do, Seongnam-si 461-701, Republic of Korea.
The current world is increasingly focusing on renewable energy sources with strong emphasis on the economically viable use of renewable energy to reduce carbon emissions and safeguard human health. Solid-state hydrogen (H) storage materials offer a higher density compared to traditional gaseous and liquid storage methods. In this context, this review evaluates recent advancements in binary, ternary, and complex metal hydrides integrated with 2D TiC MXene for enhancing H storage performance.
View Article and Find Full Text PDFPhys Chem Chem Phys
May 2025
Ames National Laboratory-U.S. DOE and Department of Physics and Astronomy, Iowa State University, Ames, IA 50011, USA.
Driven by the excitement surrounding high-temperature superconductivity in hydrides, we systematically investigated the structures, electronic properties, and superconductivity of ternary Y-B-H compounds using first-principles calculations combined with a genetic algorithm for structure search. Five stable phases (YBH, YBH, YBH, YBH and YBH) were predicted at specified pressures. Several structural building units, such as boron rings, folded boron chains, BH tetrahedrons, and dumbbell-shaped BH, were observed in these stable phases.
View Article and Find Full Text PDFActa Crystallogr C Struct Chem
June 2025
Department of Inorganic Chemistry, Ivan Franko National University, Kyryla and Mefodiya str., 6, 79005 Lviv, Ukraine.
The crystal structure of magnesium nickel tetraboride, MgNiB, was solved and refined based on single-crystal X-ray diffraction data. MgNiB crystallizes in the Pbam space group [a = 5.8791 (2), b = 11.
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