98%
921
2 minutes
20
The effects of La addition on the microstructure, thermal conductivity and mechanical properties of as-cast and as-extruded Mg-3Al-xLa-0.3Mn (x = 1, 3 and 5 wt.%) alloys were studied. The results showed that the thermal conductivity of the alloys increased with the addition of La element, which was due to the formation of the AlLa phases by consuming the solute Al and the added La element. The yield strength of the as-cast Mg-3Al-xLa-0.3Mn alloys increased with the increase in La concentration. The thermal conductivity of the as-extruded alloys was lower than that of as-cast counterparts owing to lots of defects generated in the process of hot extrusion deformation, particularly the grain boundaries. The anisotropy of thermal conductivity was discovered in the as-extruded alloys on account of the formation of texture. As the La content increases, the tensile strength and yield strength of the as-extruded alloys decreased gradually. In contrast, the elongation first increased and then decreased, resulting from the combined effect of the texture strengthening and second phase strengthening.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8839998 | PMC |
http://dx.doi.org/10.3390/ma15031078 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Chemical and Biological Engineering, University of Ottawa, 161 Louis Pasteur, Ottawa, Ontario K1N 6N5, Canada.
The processes of thermoforming 2D-printed electronics into 3D structures can introduce defects that impact the electrical performance of conductors, making them more susceptible to thermal failure during high electrical power/current applications on temperature-sensitive substrates. We therefore report the use of a thin-film boron nitride nanotube (BNNT) interlayer to directly reduce heat stress on linear and serpentine metallic traces on polycarbonate substrates thermoformed to 3D spherocylindrical geometries at varying elongation percentages. We demonstrate that the BNNT interlayer helps to improve the electrical conductivity of highly elongated thermoformed 3D traces in comparison to traces on bare polycarbonate.
View Article and Find Full Text PDFSmall
September 2025
School of Materials Science and Engineering, East China Jiaotong University, Nanchang, 330013, China.
Covalent organic frameworks (COFs) exhibit outstanding structural tunability, clearly defined ion pathways, and remarkable thermal/chemical stabilities, rendering them highly promising candidates for applications in solid-state electrolytes. However, it remains a challenge to develop a versatile method to incorporate both ionic groups and electron-withdrawing units into a single framework for effectively improving the lithium-ion conductivity. Herein, a series of novel [3+3] defective COFs is successfully synthesized featuring active amine/aldehyde anchoring sites for subsequent post-modification, and regulates the ion conductivity through elaborately tuning the anionic/cationic groups and weak/strong electron-withdrawing units.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, China.
Sulfide solid electrolytes (SEs) exhibit excellent ionic conductivity and good mechanical properties, but their poor air stability and solid-solid contact performance seriously hinder the wide application of sulfide all-solid-state batteries (ASSBs). Herein, this paper reviews the history and the major breakthroughs in the development of sulfide SEs. The theories of hard-soft-acid-base theory and glass structure theory, as well as several strategies to improve the chemical stability of sulfide SEs, are discussed emphatically.
View Article and Find Full Text PDFAdv Mater
September 2025
Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123, P. R. China.
Despite significant advancements in aerogels science, the fabrication of high-performance aerogels with their plastic processability remains unexplored owing to their inherent trade-off between skeletal rigidity and transformable processability. Herein, a universal solubility-pKa coupling-effect to engineer high-performance thermoplastic nylon aerogel family with excellent thermomechanical processing performance is proposed. By modulating solubility parameters and acid dissociation constants in nylon-solvent systems, it is precisely control crystallization to assemble interlaced 1D nanofiber skeletons, yielding nylon aerogels that integrate a high specific surface area (226 m g), exceptional compressive modulus (12.
View Article and Find Full Text PDFFood Res Int
November 2025
Institute of Food Science and Technology, Chinese Academy of Agricultural Sciences (CAAS) / Key Laboratory of Agro-Products Processing, Ministry of Agriculture and Rural Affairs, Beijing 100193, PR China; College of Food Science, Shenyang Agricultural University, Shenyang 110866, China. Electronic a
While restructuring agricultural products enhances heat and mass transfer during freeze-drying, the underlying mechanisms remain poorly understood. This study employed a multiscale approach, combining freezing dynamics, sublimation drying kinetics, X-ray tomography, gas permeability assessments, thermodynamic parameters analysis, and mathematical modeling to systematically investigate the differences in transfer properties between natural and restructured peaches across the freezing and sublimation drying processes. Key results demonstrated that restructuring decreased the freezing time by 21.
View Article and Find Full Text PDF