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Tungsten carbide (WC) is an alternative to the costly and resource-constrained Pt-based catalysts for hydrogen evolution reaction (HER). In this work, a one-step facile and easily scalable approach is reported, to synthesize ultrafine WC by molten salt. Benefiting from the ideal synergistic catalytic effect between the highly active WC nanoparticles and the conductive graphitic carbon, and strong charge transfer ability, the unique WC/C hybrids demonstrated excellent HER performance in both acid and alkaline medias with overpotentials of 112 and 122 mV, at a current density of 10 mA cm and Tafel slopes of 54.4 and 68.8 mV dec, in acid and alkaline media, and remarkable stability. With the simplicity and low-cost of the synthetic approach, the strategy presented here can be extendable to the preparation of other transition metal-based/carbon hybrids for versatile applications.
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http://dx.doi.org/10.3390/nano10091621 | DOI Listing |
Phys Chem Chem Phys
September 2025
Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China.
Transition metal dichalcogenides (TMDs) have been extensively studied as efficient photocatalysts for water splitting. However, the utilization efficiency of photogenerated carriers remains a major limitation for their practical applications. An effective approach to address this issue is the construction of Z-scheme heterostructures.
View Article and Find Full Text PDFLangmuir
September 2025
College of Materials Science and Engineering, North University of China, Taiyuan 030051, PR China.
The oxygen evolution reaction (OER), a critical yet kinetically sluggish process in electrochemical water splitting, severely limits efficient hydrogen production. Herein, a simple one-step dynamic hydrogen bubble templated electrodeposition technique is used to prepare a self-supported 3D porous NiCuFeP catalyst with outstanding OER performance. In 1.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Ho Chi Minh City University of Natural Resources and Environment (HCMUNRE), Ho Chi Minh City 70000, Viet Nam.
We herein construct the Ce-O-Ti interface bridge in the CeO/N-TiCT heterojunction through an ultrasonic-assisted hydrothermal route as an efficient Pt-free hydrogen evolution electrocatalyst. The synergistic contribution of the heterogeneous Ce-O-Ti bridge and oxygen vacancies boosts the water dissociation and thus drastically reduces energy barriers of the hydrogen evolution reaction (HER). The optimal CeO/N-TiCT material requires only a small overpotential (51.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Research Center of Advanced Catalytic Materials & Functional Molecular Synthesis, Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, School of Chemistry & Chemical Engineering, Shaoxing University, Shaoxing, 312000, China; Institute of Chemistry, Chinese Academy of Scien
Inspired by "the composition of catechol and amine groups in the adhesive proteins" of marine mussel and "brick-and-mortar" structure of nacre, we use polydopamine (PDA) as "mortar", graphene oxides (GO) nanosheets as "brick", and Pd ions as interfacial reinforcer, to fabricate nacre-like Pd enhanced PDA functionalized GO membranes (Pd@PDA/GO) with vacuum filtration-assisted assembly method. Meanwhile, in situ reduced Pd nanoclusters by PDA chains were well constrained within the resultant Pd@PDA/GO artificial nacre composites. Good interfacial adhesion with dense packing of the GO nanosheets was further confirmed with sub-nano level microstructure characterization by positron annihilation lifetime spectroscopy.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Strategic Research Center for Smart Battery, Korea Basic Science Institute (KBSI), Daejeon 34133, Republic of Korea. Electronic address:
Advancing impactful, economical, and durable Co-based bifunctional electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) has been crucial in developing sustainable energy technologies. In this work, Co and CoN nanoparticles (NPs)-incorporated S, N-doped carbon catalysts (Co/CoN/SNC) were prepared via direct pyrolysis of the CoDATT complex, exhibiting high bifunctional electrocatalytic performance for ORR and OER. The complex precursor, CoDATT, was synthesized for the first time using diaminoterthiophene (DATT) and CoCl.
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