Adv Sci (Weinh)
August 2025
Broadband photodetection plays a vital role in aerospace applications, biomedical imaging, and advanced communication systems. While molybdenum dioxide (MoO) exhibits exceptional electrical conductivity, carrier mobility, and environmental stability, its potential for photodetection has remained unrealized, with existing literature reporting negligible optoelectronic responses. Here, we unlock latent photoresponsivity of MoO by facet engineering, demonstrating that exposing the (100) crystallographic plane activates its intrinsic photoelectric conversion.
View Article and Find Full Text PDFMaterials with electromagnetic interference (EMI) shielding in the terahertz (THz) regime, while minimizing the quantity used, are highly demanded for future information communication, healthcare, and mineral resource exploration applications. Currently, there is often a trade-off between the amount of material used and the absolute EMI shielding effectiveness (EES) for the EMI shielding materials. Here, we address this trade-off by harnessing the unique properties of two-dimensional (2D) β-borophene (β-Br) nanosheets.
View Article and Find Full Text PDFIntroduction: Motor imagery functional near-infrared spectroscopy (MI-fNIRS) offers precise monitoring of neural activity in stroke rehabilitation, yet accurate cross-subject classification remains challenging due to limited training samples and significant inter-subject variability. This study proposes a Cross-Subject Heterogeneous Transfer Learning Model (CHTLM) to enhance the generalization of MI-fNIRS signal classification in stroke patients.
Methods: CHTLM leverages labeled electroencephalogram (EEG) data from healthy individuals as the source domain.
Terahertz (THz) signals are crucial for ultrawideband communication and high-resolution radar, demanding miniaturized detectors that can simultaneously measure multiple parameters such as intensity, frequency, polarization, and phase. Traditional detectors fail to meet these needs. To address this, we introduce a plasmon polariton atomic cavity (PPAC) detector based on monolayer graphene, offering a multifunctional, monolithic, and miniaturized solution.
View Article and Find Full Text PDFOptical responses of twisted bilayer graphene at targeted wavelengths can be amplified by leveraging energy levels of van Hove singularities (VHS) via tuning periods of moiré superlattices. Therefore, precise control of twist angles as well as the moiré superlattices is necessary for fabricating integrated optoelectronic devices such as photodetectors and emitters. Although recent advances in twist angle control help the observation of correlated states in twisted magic-angle graphene structures, the impact of such precise control on enhanced optical absorption is still under investigation.
View Article and Find Full Text PDFObjective: Accurate preoperative evaluation of myometrial invasion (MI) is essential for treatment decisions in endometrial cancer (EC). However, the diagnostic accuracy of commonly utilized magnetic resonance imaging (MRI) techniques for this assessment exhibits considerable variability. This study aims to enhance preoperative discrimination of absence or presence of MI by developing and validating a multimodal deep learning radiomics (MDLR) model based on MRI.
View Article and Find Full Text PDFBackground: Some clinicopathological risk stratification systems (CRSSs) such as the leibovich score have been used to predict the postoperative prognosis of patients with clear cell renal cell carcinoma (ccRCC), but there are no reliable noninvasive preoperative indicators for predicting postoperative prognosis in clinical practice.
Purpose: To assess the value of a deep learning (DL) model based on CT images in predicting the postoperative prognosis of patients with ccRCC.
Materials And Methods: A total of 382 patients with ccRCC were retrospectively enrolled andallocated to training (n = 229) or testing (n = 153) cohorts at a 6:4 ratio.
Nano Lett
September 2024
Gap surface plasmon (GSP) modes enhance graphene photodetectors (GPDs)' performance by confining the incident light within nanogaps, giving rise to strong light absorption. Here, we propose an asymmetric plasmonic nanostructure array on planar graphene comprising stripe- and triangle-shaped sharp tip arrays. Upon light excitation, the noncentrosymmetric metallic nanostructures show strong light-matter interactions with localized field close to the surface of tips, causing an asymmetric electric field.
View Article and Find Full Text PDFFlexible and miniaturized photodetectors, offering a fast response across the ultraviolet (UV) to millimeter (MM) wave spectrum, are crucial for applications like healthcare monitoring and wearable optoelectronics. Despite their potential, developing such photodetectors faces challenges due to the lack of suitable materials and operational mechanisms. Here, the study proposes a flexible photodetector composed of a monolayer graphene connected by two distinct metal electrodes.
View Article and Find Full Text PDFWith the increasing demand for terahertz (THz) technology in security inspection, medical imaging, and flexible electronics, there is a significant need for stretchable and transparent THz electromagnetic interference (EMI) shielding materials. Existing EMI shielding materials, like opaque metals and carbon-based films, face challenges in achieving both high transparency and high shielding efficiency (SE). Here, a wrinkled structure strategy was proposed to construct ultra-thin, stretchable, and transparent terahertz shielding MXene films, which possesses both isotropous wrinkles (height about 50 nm) and periodic wrinkles (height about 500 nm).
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2023
Highly sensitive photodetectors in the mid-infrared (MIR, 3-15 μm) are highly desired in a growing number of applications. However, only a handful of narrow-band-gap semiconductors are suitable for this purpose, most of which require cryogenic cooling to increase the signal-to-noise ratio. The realization of high-performance MIR photodetectors operating at room temperature remains a challenge.
View Article and Find Full Text PDFOptical skyrmions have recently attracted growing interest due to their potential applications in deep-subwavelength imaging and nanometrology. While optical skyrmions have been successfully demonstrated using different field vectors, the study of their generation and control, as well as their general correlation with electromagnetic (EM) fields, is still in its infancy. Here, we theoretically propose that evanescent transverse-magnetic-polarized (TM-polarized) EM fields with rotational symmetry are actually Néel-type optical target skyrmions of the electric field vectors.
View Article and Find Full Text PDFIntroduction: Motor imagery electroencephalography (MI-EEG) has significant application value in the field of rehabilitation, and is a research hotspot in the brain-computer interface (BCI) field. Due to the small training sample size of MI-EEG of a single subject and the large individual differences among different subjects, existing classification models have low accuracy and poor generalization ability in MI classification tasks.
Methods: To solve this problem, this paper proposes a electroencephalography (EEG) joint feature classification algorithm based on instance transfer and ensemble learning.
Flexible photodetectors with ultra-broadband sensitivities, fast response, and high responsivity are crucial for wearable applications. Recently, van der Waals (vdW) Weyl semimetals have gained much attention due to their unique electronic band structure, making them an ideal material platform for developing broadband photodetectors from ultraviolet (UV) to the terahertz (THz) regime. However, large-area synthesis of vdW semimetals on a flexible substrate is still a challenge, limiting their application in flexible devices.
View Article and Find Full Text PDFAs the limited carrier densities in atomic thin materials can be well controlled by electrostatic gates, p-n junctions based on two-dimensional materials in the coplanar split-gate configuration can work as photodetectors or light-emitting diodes. These coplanar gates can be fabricated in a simple one-step lithography process and are frequently used in hybrid integration with on-chip optical structures. However, the polarization-dependent responsivity of such a configuration is less explored in the near-infrared band, and a clear understanding is still missing.
View Article and Find Full Text PDFNanoscale
September 2022
Gap surface plasmon (GSP) modes, the localized electromagnetic modes existing between two metal structures separated by a nano-gap, are able to support subwavelength confinement and enhancement of a light field upon resonance excitation. Such features can greatly facilitate various light-matter interactions at the nanoscale. Here, we demonstrate a planar nano-gap architecture existing between a pair of tip-shaped gold pads.
View Article and Find Full Text PDFNano Lett
January 2022
In this study, Wadsley B phase vanadium oxide (VO(B)) with broad-band photoabsorption ability, a large temperature coefficient of resistance (TCR), and low noise was developed for uncooled broad-band detection. By using a freestanding structure and reducing the size of active area, the VO(B) photodetector shows stable and excellent performances in the visible to the terahertz region (405 nm to 0.88 mm), with a peak TCR of -4.
View Article and Find Full Text PDFHyperbolic phonon polaritons (HPhPs) sustained in polar van der Waals (vdW) crystals exhibit extraordinary confinement of long-wave electromagnetic fields to the deep subwavelength scale. In stark contrast to uniaxial vdW hyperbolic materials, recently emerged biaxial hyperbolic materials, such as α-MoO and α-V O , offer new degrees of freedom for controlling light in two-dimensions due to their distinctive in-plane hyperbolic dispersions. However, the control and focusing of these in-plane HPhPs remain elusive.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2021
Chemical vapor deposition (CVD) is a promising method to obtain monolayer transition metal dichalcogenides (TMDCs) with high quality and enough size to meet the requirements of practical photoelectric devices. However, the as-grown monolayers often exhibit a lower PL performance due to the stress between the as-grown TMDCs flakes and the substrate. Therefore, finding a facile method to effectively promote the photoluminescence quantum yield (PL QY) of CVD monolayer TMDCs with a clean surface is highly desirable for practical applications.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2021
Mid-infrared (MIR) photodetection is of significance in civil and military applications because it shows superiority in absorbing the vibration of various molecules and covering atmospheric transmission windows. Recently, the PtTe, a typical type-II Dirac semimetal, has come under the spotlight due to its unique photodetection sensibility in the MIR region and robust stability in the atmosphere. Here, the high-quality and large-scale 1T-PtTe thin films with air stability were grown by molecular beam epitaxy.
View Article and Find Full Text PDFWhen the geometric features of plasmonic nanostructures approach the subnanometric regime, nonlocal screening and charge spill-out of metallic electrons will strongly modify the optical responses of the structures. While quantum tunneling resulting from charge spill-out has been widely discussed in the literature, the near-field enhancement saturation caused by the nonlocal screening effect still lacks a direct experimental verification. In this work, we use surface-enhanced Raman spectroscopy (SERS) of graphene to probe the in-plane near-field enhancement limit in gold nanosphere-on-film nanocavities where different layers of graphene are sandwiched between a gold nanosphere and a gold film.
View Article and Find Full Text PDFLight-driven electron emission plays an important role in modern optoelectronic devices. However, such a process usually requires a light field with either a high intensity or a high frequency, which is not favorable for its implementations and difficult for its integrations. To solve these issues, we propose to combine plasmonic nanostructures with nanoelectron emitters of low work function.
View Article and Find Full Text PDFJ Am Chem Soc
July 2018
Plasmon-free surface enhanced Raman scattering (SERS) based on the chemical mechanism (CM) is drawing great attention due to its capability for controllable molecular detection. However, in comparison to the conventional noble-metal-based SERS technique driven by plasmonic electromagnetic mechanism (EM), the low sensitivity in the CM-based SERS is the dominant barrier toward its practical applications. Herein, we demonstrate the 1T' transition metal telluride atomic layers (WTe and MoTe) as ultrasensitive platforms for CM-based SERS.
View Article and Find Full Text PDF2D van der Waals (vdW) layered polar crystals sustaining phonon polaritons (PhPs) have opened up new avenues for fundamental research and optoelectronic applications in the mid-infrared to terahertz ranges. To date, 2D vdW crystals with PhPs are only experimentally demonstrated in hexagonal boron nitride (hBN) slabs. For optoelectronic and active photonic applications, semiconductors with tunable charges, finite conductivity, and moderate bandgaps are preferred.
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