Occurrence, molecular transformation and prioritizing environmental risks of organic nitrogen in aqueous phase from hydrothermal carbonization of waste activated sludge.

Hydrothermal carbonization (HTC) is an energy-efficient and environmentally friendly method for treating waste activated sludge (WAS). However, the aqueous phase by-product (carbonization liquid, CL) presents a significant challenge because of its high nitrogen content and complex organic composition, which remains inadequately explored. This study uses non-targeted screening and mass-difference analysis to research organic nitrogen compounds (Org-Ns) in CL.

Online monitoring of odor compounds in drinking water sources by an integrated robotic sample preparation platform coupled with a gas chromatography-mass spectrometry system.

The odor compounds in drinking water have gained global attention. Timely and accurate determination of odor compounds in drinking water sources is paramount but poses a challenging task in routine laboratory water analysis. In this work, we designed a novel robotic sample preparation platform coupled with a gas chromatography-mass spectrometry (GC-MS) analysis system by integrating automatic headspace solid-phase microextraction (HS-SPME), gas chromatography (GC), and mass spectrometry (MS) for online monitoring of odorants in water.

Per- and polyfluoroalkyl substances (PFAS) in drinking water systems in the lower Yangtze River: source, fate, and health risk assessment.

The Yangtze River is significantly impacted by industrial activities related to per- and polyfluoroalkyl substances (PFAS) in China, posing potential threats to drinking water safety. So far, our knowledge of PFAS occurrence in the river and their fate in the whole drinking water supply systems remains limited. We conducted a comprehensive investigation of PFAS in Jiangsu's drinking water systems, using the target screening method.

Elucidating molecular characteristics of organic compounds during ozone micro-bubbles treatment based on GC × GC-QTOF-MS and non-targeted analysis.

The ozone micro-bubbles (OCBs) technology is increasingly gaining traction as a promising alternative method for organic compounds removal in wastewater. Nevertheless, there is a scarcity of literature addressing the molecular-level transformation of organic compounds during OCBs treatment. In this work, the secondary effluent from a wastewater treatment plant was treated with ozone milli-bubbles (OLBs) and OCBs, and the fate of organic compounds at the molecular level was investigated using comprehensive two-dimensional gas chromatography quadrupole time-of-flight mass spectrometry (GC × GC-QTOF-MS).

Analysis strategy of contamination source using chemical fingerprint information based on GC-HRMS: A case study of landfill leachate.

With the increasing prevalence of emerging contaminants (ECs) in the environment, gaining a deeper understanding of the chemical information pertaining to the contamination source is a crucial step toward effective prevention and control of these ECs. This study presents a novel strategy for analyzing the chemical information of contamination sources using gas chromatography-high resolution mass spectrometry (GC-HRMS) and demonstrates it on landfill leachate, a common and representative environmental contamination source. Initially, a non-targeted screening approach using HRMS was used to characterize a total of 5344 organic compounds with identification confidence levels 1 and 2 in 14 landfill leachate samples.

Automated pretreatment of environmental water samples and non-targeted intelligent screening of organic compounds based on machine experiments.

The complexity of environmental pollutants poses significant challenges for monitoring and analysis, especially with the emergence of numerous emerging contaminants. Traditional analysis methods rely mainly on laboratory analysis, which involves labor-intensive and time-consuming sample preparation procedures and non-target data analysis, greatly limiting the rapid detection of water organic pollutants. In this study, we designed a robot experimenter combined with GC × GC-TOFMS.

Online sequential analysis of volatile and semivolatile organic compounds in water matrices by double robotic sample preparations and dual-channel mono and comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry system.

The monitoring of organic compounds in aquatic matrices poses challenges due to its complexity and time-intensive nature. To address these challenges, we introduce a novel approach utilizing a dual-channel mono (D) and comprehensive two-dimensional (D) gas chromatography coupled with time-of-flight mass spectrometry (GC × GC-TOFMS) system, integrated with a robotic pretreatment platform, for online monitoring of both volatile organic compounds (VOCs) and semivolatile organic compounds (SVOCs) in water matrices. Employing the robotic platform, we establish a suite of online liquid-liquid extraction (LLE) pretreatment processes for water samples, marking the first instance of such procedures.

Transport and health risk of legacy and emerging per-and polyfluoroalkyl substances in the water cycle in an urban area, China: Polyfluoroalkyl phosphate esters are of concern.

Polyfluoroalkyl phosphate esters (PAPs) are a group of emerging alternatives to the legacy per- and polyfluoroalkyl substances (PFAS). To better understand the transport and risk of PAPs in the water cycle, 21 PFAS including 4 PAPs and 17 perfluoroalkyl acids were investigated in multiple waterbodies in an urban area, China. PFAS concentrations ranged from 85.

Emerging and legacy per- and polyfluoroalkyl substances (PFAS) in fluorochemical wastewater along full-scale treatment processes: Source, fate, and ecological risk.

The increasing applications of emerging per- and polyfluoroalkyl substances (PFAS) have raised global concern. However, the release of emerging PFAS from the fluorochemical industry remains unclear. Herein, the occurrence of 48 emerging and legacy PFAS in wastewater from 10 fluorochemical manufacturers and mass flows of PFAS in a centralized wastewater treatment plant were investigated.

Investigation on molecular characteristics of organic compounds during a full-scale landfill leachate treatment process based on non-targeted analysis.

In this study, a new methodology for evaluating full-scale landfill leachate treatment processes by non-targeted analysis using comprehensive two-dimensional gas chromatography quadrupole time-of-flight mass spectrometry (GC × GC-QTOF-MS) was proposed. The method revealed the chemical complexity of organic compounds in landfill leachate samples at the molecular level and evaluated the removal efficiency of the anaerobic-anoxic-oxic (AO) - membrane bioreactor (MBR) - nanofiltration (NF) treatment process in conjunction with multi-level classification of organic compounds. Results showed that the results of non-targeted analysis combined with multi-level classification of organic compounds had a significant correlation with the conventional water quality parameters and can be used to evaluate the treatment process.

Wearable sensor platforms for real-time monitoring and early warning of metabolic disorders in humans.

Nowadays, the prevalence of metabolic syndromes (MSs) has attracted increasing concerns as it is closely related to overweight and obesity, physical inactivity and overconsumption of energy, making the diagnosis and real-time monitoring of the physiological range essential and necessary for avoiding illness due to defects in the human body such as higher risk of cardiovascular disease, diabetes, stroke and diseases related to artery walls. However, the current sensing techniques are inconvenient and do not continuously monitor the health status of humans. Alternatively, the use of recent wearable device technology is a preferable method for the prevention of these diseases.

Chemical characterization and source attribution of organic pollutants in industrial wastewaters from a Chinese chemical industrial park.

Accelerated urbanization and industrialization have led to an alarming increase in the generation of wastewater with complex chemical contents. Industrial wastewaters are often a primary source of water contamination. The chemical characterization of different industrial wastewater types is an essential task to interpret the chemical fingerprints of wastewater to identify pollution sources and develop efficient water treatment strategies.

Bifunctional catalytic degradation of diclofenac over Cu-Pd co-modified sponge iron-based trimetal: Parameter optimization.

Currently, the pharmaceutical and personal care products (PPCPs) have posed great challenge to advanced oxidation techniques (AOTs). In this study, we decorated sponge iron (s-Fe) with Cu and Pd (s-Fe-Cu-Pd) and further optimized the synthesis parameters with a response surface method (RSM) to rapidly degrade diclofenac sodium (DCF). Under the RSM-optimized conditions of Fe: Cu: Pd = 100: 4.

New insight into fate and transport of organic compounds from pollution sources to aquatic environment using non-targeted screening: A wastewater treatment plant case study.

A variety of chemicals discharged into the aquatic environment by the wastewater treatment plant (WWTP), which is a potential source of hazard to the ecological environment and human health. This study established a novel analytical method for all compounds using non-targeted screening to comprehensively explore the fate and transport of organic compounds from WWTP to aquatic environment. 3967 and 3636 features were detected in WWTP samples and river samples, respectively.

Multi-Pesticide Residue Analysis Method Designed for the Robot Experimenters.

Robots replacing humans as the executioners is crucial work for intelligent multi-pesticide residue analysis to maximize reproducibility and throughput while minimizing the expertise required to perform the entire process. Traditional analysis methods are predicated on manual execution, so we configured our robot experimenter, automated the analytical workflow, and achieved the goal of robotics execution. Our robot experimenter with an -- axis robotic arm was interfaced with seven modules and ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) for automated standard solution preparation, sample pre-treatment, and UPLC-MS/MS detection.

Understanding the membrane fouling control process at molecular level in the heated persulfate activation- membrane distillation hybrid system.

Sulfate radical (SO) based advanced oxidation is considered as a promising pretreatment strategy to degrade organic pollutants and thereby mitigate the membrane fouling in the membrane process. In this study, heat-activated persulfate (PS) activation was integrated with the membrane distillation (MD) process for the alleviation of membrane fouling in treatment of wastewater treatment plant (WWTP) secondary effluent and surface water. In-depth understanding of the molecular fate during membrane fouling control process was performed by using a non-targeted screening method of two-dimensional gas chromatography-time-of-flight mass spectrometry (GC × GC-TOF-MS) coupling with multiple characterizations.

Spatial and temporal characteristics of air pollutants and their health effects in China during 2019-2020.

This work presents the temporal and spatial characteristics of the major air pollutants and their associated health risks in China from 2019 to 2020, by using the monitoring data from 367 cities. The annual average PM, PM, NO, SO, CO, and O concentrations decreased by 10.9%, 13.

[Simultaneous determination of seven metabolites of organophosphate esters and 8-hydroxy-2'-deoxyguanosine in urine by high-performance liquid chromatography-tandem mass spectrometry with homemade mixed column purification].

A method based on high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) with a small homemade mixed column was developed for the simultaneous determination of seven metabolites of organophosphate esters (OPEs) and 8-hydroxy-2'-deoxyguanosine (8-OHdG), an DNA oxidative damage marker, in urine. The urine samples were extracted by acetonitrile and enriched by the self-made column. All the samples were separated by gradient elution with acetonitrile-0.

The use of different sublethal endpoints to monitor atrazine toxicity in nematode Caenorhabditis elegans.

In this work, Caenorhabditis elegans was employed as an in vivo model to determine the toxic effects of atrazine at different concentrations. After the exposure period from the larval stage L1 to adulthood day 1, atrazine (10 mg/L) significantly decreased the body length and lifespan of nematodes. In addition, exposure to ≥0.

Indirect competitive-structured electrochemical immunosensor for tetrabromobisphenol A sensing using CTAB-MnO nanosheet hybrid as a label for signal amplification.

Tetrabromobisphenol A (TBBPA) is a kind of brominated flame retardant that is usually added to products to reduce their flame retardancy. However, its extensive use has resulted in their residues being found in the environment, which is very harmful. Herein, an indirect competitive immunosensor has been established for TBBPA detection based on the signal amplification system.

Correction to: Organic Matter Pollution During the Spring Thaw in Hulun Lake Basin: Contribution of Multiform Human Activities.

In the original publication of the article, there was an error in the name of institution. The incorrect name of institution "Nanjing Institute of Environmental Sciences, Ministry of Environmental Protection, 8, Jiangwangmiao Road, XuanWu District, 210042 Nanjing, People's Republic of China" should be revised to "Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environmental, 8, Jiangwangmiao Road, XuanWu District, 210042 Nanjing, People's Republic of China". The institution was still the same, but the name of the institution was changed.

Characterization and health risk assessment of organophosphate esters in indoor dust from urban and rural domestic house and college dormitory in Nanjing, China.

Indoor dust is an important route of exposure for organophosphate esters (OPEs), which are associated with adverse health effects. In the present study, the pollution occurrence and potential health risks of 13 OPEs in indoor dust from urban homes, college dormitories, and rural homes in Nanjing were investigated. Most OPEs were detected in the tested samples.

[Determination of 1, 4-dioxane in aerosol cosmetic by new isotope dilution-headspace gas chromatography-mass spectrometry].

Objective: To develop a simple, fast and sensitive analytical method based on isotope dilution-headspace gas chromatography-mass spectrometry for the determination of 1, 4-dioxane residue in the aerosol cosmetics.

Methods: Sample was successive weighed and dissolved in 1, 3-dimehyl-2-imidazolidinone(DMI)solvent and isotope internal standard was added. Then transfered to a 20 mL headspace vial.

[Occurrence and Risk Assessment of Organophosphate Esters in Source Water of the Nanjing Section of the Yangtze River].

We explored the pollution characteristics, spatial and temporal distribution, ecological risk, and human health risk of organophosphate esters (OPEs) in the source water of the Nanjing section of the Yangtze River. Thirteen OPEs were determined by solid phase extraction-high performance liquid chromatography-tandem mass spectrometry. The results showed that twelve OPEs were detected to different extents with total concentrations ranging from 85.

[Occurrence Characteristics and Risk Assessment of Antibiotics in Source Water of the Nanjing Reach of the Yangtze River].

Occurrence characteristics of antibiotics in the source water of the Nanjing section of the Yangtze River were analyzed preliminarily by solid-phase extraction and high-performance liquid chromatography-tandem mass spectrometry (SPE-HPLC-MS/MS). The results showed that the cumulative concentration of 16 sampling points ranged from 13.37 ng·L to 780.