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Article Abstract

Negatively charged boron vacancy (V) ensembles in hexagonal boron nitride (h-BN) have attracted considerable attention as a promising platform for quantum sensing. Current challenges include the experimental validation of the spatial distribution and electronic states of optically active V and optically inactive neutral boron vacancy (V) defects. To address these issues, we employ electron energy loss spectroscopy (EELS) combined with scanning transmission electron microscopy (STEM) using monochromated 30-keV electrons, effectively reducing background interference. This approach unveils distinct spectral peaks at 2.5 and 1.9 eV, corresponding to V and V defects, respectively. Furthermore, we achieve nanometer-scale concentration mapping for V and V defects, advancing insights into spin defect configurations crucial for optimizing quantum sensor performance.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12412148PMC
http://dx.doi.org/10.1021/acs.nanolett.5c02988DOI Listing

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