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Negatively charged boron vacancy (V) ensembles in hexagonal boron nitride (h-BN) have attracted considerable attention as a promising platform for quantum sensing. Current challenges include the experimental validation of the spatial distribution and electronic states of optically active V and optically inactive neutral boron vacancy (V) defects. To address these issues, we employ electron energy loss spectroscopy (EELS) combined with scanning transmission electron microscopy (STEM) using monochromated 30-keV electrons, effectively reducing background interference. This approach unveils distinct spectral peaks at 2.5 and 1.9 eV, corresponding to V and V defects, respectively. Furthermore, we achieve nanometer-scale concentration mapping for V and V defects, advancing insights into spin defect configurations crucial for optimizing quantum sensor performance.
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http://dx.doi.org/10.1021/acs.nanolett.5c02988 | DOI Listing |
Inorg Chem
September 2025
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China.
Ionic doping is widely used to regulate surface acidity in catalytic materials, yet the microscopic mechanisms remain difficult to observe. Clarifying them is essential for acid catalysis design. Prior work showed that Cr doping into the AlO-based open-framework aluminoborate PKU-1 alters acidity.
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2025
College of Mathematics and Physics, Shanghai University of Electric Power, Shanghai 200090, China.
In this paper, we employ density functional theory (DFT) and non-equilibrium Green's function (NEGF) calculations to investigate the gas-sensing properties of monolayer HfCO MXene, focusing on intrinsic vacancy defects and carbon-site substitutional doping. Among tested gases, NO exhibits exceptional sensitivity due to strong adsorption energy and significant charge transfer. Boron doping at carbon sites enhances charge transfer and adsorption strength through d-band center upshift (-0.
View Article and Find Full Text PDFLangmuir
September 2025
School of Mechanical and Electrical Engineering, Lanzhou University of Technology, Lanzhou 730050, China.
Thermal transfer regulation of one-dimensional heterostructure is essential, but the influence of vacancy defects on interfacial thermal conductance (ITC) remains unclear. In this paper, we demonstrate that vacancy defects at the carbon/boron nitride heteronanotubes (CBNNT) significantly reduce the ITC, with N atoms vacancy exhibiting a more pronounced inhibitory effect than C atoms vacancy. This decline in ITC is attributed to vacancy-induced lattice distortions that diminish the overlap of the phonon density of states, ultimately enhancing phonon localization.
View Article and Find Full Text PDFNano Lett
September 2025
National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan.
Negatively charged boron vacancy (V) ensembles in hexagonal boron nitride (h-BN) have attracted considerable attention as a promising platform for quantum sensing. Current challenges include the experimental validation of the spatial distribution and electronic states of optically active V and optically inactive neutral boron vacancy (V) defects. To address these issues, we employ electron energy loss spectroscopy (EELS) combined with scanning transmission electron microscopy (STEM) using monochromated 30-keV electrons, effectively reducing background interference.
View Article and Find Full Text PDFMikrochim Acta
August 2025
Anhui Province Industrial Generic Technology Research Center for Alumics Materials, Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei, 235000, People's Republic of China. sa15
Boron-doped CeO (B-CeO) modified electrodes were developed for the sensitive detection of p-nitrophenol (PNP). The CeO and B-CeO nanomaterials were characterized via various techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS), and the successful doping of B and the maintenance of the crystal structure of CeO were confirmed. The B-CeO showed an average particle size ranging from 50 to 100 nm.
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