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As a new functional graded lattice structure construction strategy, the relative density gradient strategy has a promising future due to its ease of realization in various lattice structures. This paper proposes a BCC lattice structure combining two different lattice single cells. Based on this, the single cells of different structures are assigned different relative density gradients, resulting in 18 combined gradient lattice structures. Based on proving the experimental feasibility of numerical simulation, the mechanical properties and energy absorption characteristics of the combined gradient lattice structure are investigated by numerical simulation. When applied to composite lattice structures, the proposed wave-like gradient design significantly improves mechanical properties. Among the various gradient strategies examined, several have achieved mechanical performance close to that of uniform lattice structures. To some extent, this approach mitigates the common drawback of gradient lattice structures-where the relative density of the weakest layer is consistently lower than the interlayer relative density of uniform lattice structures-resulting in varying degrees of mechanical performance degradation compared to their uniform counterparts. The proposed linearly enhanced gradient strategy (Strategy-LE) possesses higher SEA and CLE values when the lattice structure is subjected to compressive loading, with an improvement of 6.36% in SEA and 61.6% in CLE over the uniform structure. Through the relative density gradient design, the adaptability of the BCC lattice structure in actual complex application scenarios is greatly enhanced, and the energy-absorbing properties of the lattice structure are greatly improved.
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http://dx.doi.org/10.3390/ma18153652 | DOI Listing |
Phys Chem Chem Phys
September 2025
Department of Physics, Indian Institute of Technology (ISM) Dhanbad, Jharkhand-826004, India.
Here, Ln-Li co-doped YO@ZnO core-shell heterostructures were synthesized by three different techniques - intermediate layer conversion method, a hydrothermal method, and an interlayer mediated hydrothermal method. The synthesis procedure is optimized based on the thickness and compactness of the developed shell. The growth kinetics and synthesis mechanism of each adopted method have been explained in detail using XRD, FESEM, TEM, SAED, and EDX characterization techniques.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Yunnan Key Laboratory of Non-ferrous Metals Vacuum Metallurgy, Kunming University of Science and Technology, Kunming, 650093, China.
To address palladium supply-demand challenges and conventional recovery inefficiencies, this study develops a lithium-mediated electrodeposition process for efficient palladium recycling from spent catalysts. Density functional theory calculations identified a controlled Pd→LiPd (Pd)→LiPdO (Pd) transformation pathway, and experimental verification confirmed that LiPd precursors underwent oxidative transformation into LiPdO with structural inheritance. LiPdO exhibited Pd-O coordination and underwent rapid dissolution in dilute hydrochloric acid.
View Article and Find Full Text PDFACS Nano
September 2025
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
The integration of Mn in NaMnFe(PO)PO (NMFPP) enhances the energy density but compromises the Na mobility and structural stability due to limited electron hopping and pronounced Jahn-Teller effects. To address this, a structurally compatible anionic substitution strategy is implemented by partially replacing PO with bulkier and less electronegative SiO groups. The reinforced cathode exhibits enhanced rate performance, which is attributed to lattice expansion induced by the larger SiO units, thereby facilitating Na diffusion and reducing impedance during charge-discharge processes, as supported by GITT and DRT analyses.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Shanxi Center of Technology Innovation for Advanced Power Battery Material, School of Chemistry and Chemical Engineering, Shanxi Normal University, Taiyuan 030032, China. Electronic address:
Against the backdrop of global carbon neutrality target driving the transformation of energy structure, alcohol fuel cells (AFCs) show great application potential; However, the sluggish kinetics of their anodic alcohol oxidation reaction hinders the commercialization of AFCs. Metallene is a novel 2D material with potential application prospect in the field of electrocatalysis. In this paper, PdMoW trimetallene has been successfully produced by a one-pot wet-chemical method, which displays a unique two-dimensional curved ultrathin graphene structure.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
College of Physics and Electronic Information, Yunnan Key Laboratory of Optoelectronic Information Technology, Yunnan Normal University, Kunming 650500, China. Electronic address:
Antimony trisulfide (SbS) has emerged as a promising inorganic semiconductor for optoelectronics due to its distinctive anisotropic crystal structure and suitable bandgap (∼1.7 eV). While hydrothermal synthesis remains challenging for achieving high crystallinity and controlled morphology, we developed an innovative dual‑sulfur precursor strategy utilizing sodium thiosulfate (STS) and thioacetamide (TAA) at a 7:2 M ratio with SbCl.
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