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In topological physics, it is commonly understood that the existence of the boundary states of a topological system is inherently dictated by its bulk. A classic example is that the surface Fermi-arc states of a Weyl system are determined by the chiral charges of Weyl points within the bulk. Contrasting with this established perspective, here, we theoretically and experimentally discover a family of topological chiral bulk states extending over photonic Weyl metamaterial waveguides, solely induced by the waveguide boundaries, independently of the waveguide width. Notably, these chiral bulk states showcase discrete momenta and function as tunnels that connect Fermi-arc surface states living in different two-dimensional spaces via a third dimension. Our work offers an alternative mechanism for robust chiral bulk transport of waves and highlights the boundaries as a new degree of freedom to regulate bulk Weyl quasiparticles.
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http://dx.doi.org/10.1103/PhysRevLett.134.196601 | DOI Listing |
Adv Mater
September 2025
Key Lab of Artificial Micro- and Nano-Structures of Ministry of Education of China, School of Physics and Technology, Wuhan University, Wuhan, 430072, China.
Sequential deposition technique is widely used to fabricate perovskite films with large grain size in perovskite solar cells (PSCs). Residual lead halide (PbI) in the perovskite film tends to be decomposed into metallic lead (Pb) under long-term heating or light soaking. Here, a chiral levetiracetam (LEV) dopant containing α-amide and pyrrolidone groups is introduced into the PbI precursor solution.
View Article and Find Full Text PDFNat Mater
September 2025
National Key Laboratory of Advanced Micro and Nano Manufacture Technology, Department of Micro/Nano Electronics, School of Integrated Circuits, Shanghai Jiao Tong University, Shanghai, China.
Black phosphorus nanoribbons (BPNRs) with a tunable bandgap and intriguing electronic and optical properties hold strong potential for logic applications. However, efficiently producing high-quality BPNRs with precise control over their size and structure remains a great challenge. Here we achieved high-quality, narrow and clean BPNRs with nearly atomically smooth edges and well-defined edge orientation at high yield (up to ~95%) through the sonochemical exfoliation of the synthesized bulk BP crystals with a slightly enlarged lattice parameter along the armchair direction.
View Article and Find Full Text PDFOrg Biomol Chem
August 2025
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of, Sciences, Vavilova Str., 28, bld. 1, Moscow, 119334, Russia.
A sterically controlled pathway towards iminodioxocines, hydrobenzamides and ONO pincer ligands - amine-bis(phenols) - is developed by exploiting the reaction between sterically hindered salicylaldehydes and ammonia. Iminodioxocines, which are unlocked by this (first) general pathway, show unprecedented reactivity towards common organolithium reagents, enabling the diastereoselective synthesis of amine-bis(phenols) in almost quantitative yields. The corresponding 2-step procedure - to replace the previous low-yielding 5-step synthetic protocol - addresses the key challenges of the traditional Mannich condensation, such as the failure to introduce NH functionalities into the amine-bis(phenol) core and substituents into its benzylic positions.
View Article and Find Full Text PDFAdv Mater
August 2025
Department of Physics, Graduate School, Daegu University, Gyeongbuk, 38453, Republic of Korea.
Weyl metals, known for their topological structure and chiral anomaly, exhibit nonlinear transport that defies conventional theory. In this study, ZrTe, an inversion-symmetric Dirac semimetal tunable to a Weyl state by magnetic field, is investigated, and rectification (alternating current (AC) to direct current (DC) conversion) and third harmonic generation in longitudinal configurations is revealed. Despite its bulk inversion symmetry, symmetry-forbidden rectification and a dynamic phase transition arising from the chiral anomaly are observed.
View Article and Find Full Text PDFACS Nano
August 2025
Department of Physics, Engineering Physics, and Astronomy, Queen's University, Kingston, Ontario K7L 3N6, Canada.
N-Heterocyclic carbenes (NHCs) that have wingtip groups with low steric bulk, such as 1,3-dimethyl-benzimidazol-2-ylidene (NHC), form bis-complexes with metal atoms when they are deposited onto Au(111) surfaces . These complexes self-assemble into three different lattices: a herringbone, a double-herringbone, and a chiral kagome lattice. The static properties of these lattices have been studied with scanning tunneling microscopy and theoretical methods.
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