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As robots undertake increasingly complex tasks, such as real-time visible image sensing, environmental analysis, and weather monitoring under harsh conditions, design of an appropriate robot shell has become crucial to ensure the reliability of internal electronic components. Several key factors, such as the cooling efficiency, visible transparency, mechanical performance, and weathering resistance of the shell material, are proposed in this research to ensure future robot functionality. In this study, a polymeric double-layered shell for fabrication by stereolithography 3D printing was designed, featuring a porous outer layer and a spherical inner shell. The inner spherical shell provides approximately 90% transmission in the visible to near-infrared wavelength range (450-1050 nm) and ensures the proper functioning of the optical devices, such as cameras, lidar, and solar cells, inside the robot. In addition, the inner shell material displays high emittance in the mid-infrared range (5-20 μm) to facilitate effective radiative cooling and protect the robot control system from thermal damage. The 3D-printed inner shell is exposed to a real environment for three months, and its stable optical and mechanical performance confirms its weather resistance ability. Moreover, the 3D-printed outer robot shell promotes mechanical strength while the robot is moving. The optimal 50% porous outer shell is designed to protect the inner shell from continuous moving impact. Finite element simulations are also used to show that the 50% porosity of the outer shell significantly reduces the strain energy upon impact. Compared with a conventional single-layer design with a strain energy of 130 mJ, the double-layered shell with 50% porosity exhibits a reduced strain energy of 22.09 mJ. This double-layered design, which offers excellent weather resistance, high visible transparency, and effective radiative cooling, is promising for future applications in both land and water robot shells.
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http://dx.doi.org/10.1021/acsomega.4c09954 | DOI Listing |
Research (Wash D C)
September 2025
Institute of Medical Research, Northwestern Polytechnical University, Xi'an, China.
The inhibition of dependent glutamine metabolism is an effective treatment for triple-negative breast cancer (TNBC) starvation, but it is limited by compensatory glycolysis and inadequate delivery efficiency. Herein, we construct a pH-responsive size/charge-reprogrammed micelle with hierarchical delivery characteristics for TNBC suppression with glutamine depletion and vessel blockade. It consists of a positively charged prodrug micelle chemically grafted with the glutamine transport inhibitor V9302 as the inner core layer, the neovascular disruptor CA4P adsorbed in the middle layer, and a pH-responsive peelable polymer as the outer shell.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
College of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR China.
The flammability and poor ultraviolet (UV) aging resistance of polylactic acid (PLA) limit its applications outdoors and in fields requiring flame retardancy. To address these limitations, this study designed ammonium polyphosphate (APP) as the core, the biopolymer chitosan (CS) as the inner shell, and lignin (LK) as the outer shell. CS and LK are deposited on the surface of APP via electrostatic interaction in the aqueous phase to prepare a core-shell structure flame retardant APP@CS@LK with anti-UV aging properties.
View Article and Find Full Text PDFCarbohydr Polym
November 2025
Key Laboratory of Fermentation Engineering (Ministry of Education), Hubei Key Laboratory of Industry Microbiology, Hubei University of Technology, Wuhan 430068, China. Electronic address:
The polyunsaturated fatty acids in fish oil are prone to oxidation and have poor dispersibility, which limits their use in the food sector. In this work, oil-in-water emulsions stabilized by chitin nanocrystals (ChNC) were prepared via high-speed homogenization. Anionic carboxymethyl cellulose (CMC) was assembled onto cationic ChNC-stabilized emulsion droplet surfaces via layer-by-layer self-assembly technology to construct ChNC/CMC (Ch-C) bilayer emulsions with rigid inner layer and flexible outer shell structures.
View Article and Find Full Text PDFJ Appl Polym Sci
August 2025
Department of Biomedical Engineering, University of Houston.
Recent advances in neural regeneration have demonstrated the importance of incorporating proteins into polymeric capsules to provide both topographical and biochemical cues to cells. Coaxial electrospinning has emerged as a versatile technique for embedding delicate bioactive agents within core-shell nanofibers, enabling controlled and sustained drug release. In this study, we employed a design-of-experiment approach to systematically investigate how controllable parameters in coaxial electrospinning influence the diameter and size distribution of aligned poly (ethylene oxide-poly(l-lactide-co-glycolide) nanofibers loaded with nerve growth factor (NGF).
View Article and Find Full Text PDFAnal Chem
September 2025
Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei, Anhui 230031, China.
Despite the various advantages of upconversion nanoparticles (UCNPs), the paradoxes of high luminescence resonance energy transfer (LRET) efficiency and low quantum yield remain a bottleneck for broader sensing applications. Herein, novel sandwich-structured UCNPs (SWUCNPs, NaYbF:(30%Gd)@NaYbF:Er(2%)@NaYF) with a core-middle shell-outer shell structure were synthesized. The SWUCNPs maintained a high LRET efficiency by confining the luminescent center of Er in the middle shell.
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