A near-infrared amine/HSO probe with colorimetric and fluorescent ultrafast response and its application in food samples and visual evaluation of salmon freshness.

Food Res Int

College of Food Science and Technology, Bohai University, Food Safety Key Lab of Liaoning Province, National & Local Joint Engineering Research Center of Storage, Processing and Safety Control Technology for Fresh Agricultural and Aquatic Products, Jinzhou 121013, China.

Published: February 2025


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Article Abstract

A multifunctional near-infrared fluorescent probe (Sycy) is synthesized by the one-step condensation reaction of syringaldehyde and tricyanofuran. Sycy can detect HSO within 150 s in the red wine and sugar samples with a low detection limit of 3.5 μM. Sycy also has an obvious response to 13 volatile amines through colorimetric and fluorescent channels. Sycy recognizes representative diethylamine (DEA) with a large stokes shift (131 nm), low detection limit (7.11 μM), ultrafast response within 5 s, and fluorescence imaging DEA in living cells. The sensing tag loaded with Sycy can monitor the freshness of salmon by observing colorimetrical and fluorescent changes of the tag with the naked eye. In addition, quantitative determination of HSO and evaluation of fish freshness can be achieved with smartphone assistance, improving the detection accuracy. Sycy can be prepared into fluorescent ink and be applied to the field of material and information storage.

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http://dx.doi.org/10.1016/j.foodres.2024.115613DOI Listing

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