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Slope failures in Bangladesh's Chittagong division are a growing concern, with fatalities increasing from 19 in 2000 to 162 in 2017 and projected to rise further. This study aims to identify the most vulnerable rock formation and assess Carboxymethyl Cellulose (CMC) as a solution for enhancing shale strength and mitigating slope failures. The research began by evaluating weathering susceptibility and stability of different rock layers, revealing the high instability of shale in the Bhuban Formation. Slake durability tests measured cation concentration to understand shale instability mechanisms. Laboratory experiments, including immersion tests and grained-and-molded shale specimens, examined CMC's potential to improve shale stability. Results indicated that the shale of the Bhuban Formation had the highest hammer value variations, indicating increased weathering susceptibility. Shale instability was attributed to illite layer dissolution, releasing K. Intact shale specimens treated with CMC showed enhanced penetration resistance, shear strength, and deformation behavior, suggesting CMC's potential in increasing shale stability. Grained-and-molded shale specimens treated with CMC demonstrated increased shear strength, critical shear displacement, and contraction deformational behavior. Optical microscopy and scanning electron microscopy revealed the formation of cross-links between shale grains, contributing to improved shale stability. Further research is needed to explore the application of CMC for enhancing in situ rock slope stability. This study emphasizes the importance of addressing slope failures in the Chittagong division and provides insights into mitigating the risks through CMC-based interventions.
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http://dx.doi.org/10.1038/s41598-023-44417-8 | DOI Listing |
Sci Rep
August 2025
Department of Mechanical Engineering, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia.
The unconfined compressive strength of organic-rich clay shale is a fundamental parameter in geotechnical and energy applications, influencing drilling efficiency, wellbore stability, and excavation design. This study presents machine learning-based predictive models for unconfined compressive strength estimation, trained on a comprehensive dataset of 1217 samples that integrate non-destructive indicators such as ultrasonic pulse velocity, shale fabric metrics, wettability potential and destructive field-derived parameters. A dual-model framework was implemented using Support Vector Machine, Decision Tree, K-Nearest Neighbor, and Extreme Gradient Boosting (XGBoost) algorithms.
View Article and Find Full Text PDFNat Commun
August 2025
Frontiers Science Center for High Energy Material, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China.
Seawater desalination and wastewater purification from brackish water, shale gas extraction, and industrial processes remain vital but challenging. Membrane distillation offers a promising solution yet struggles with low flux, membrane fouling, and the permeation of volatile organic compounds alongside water vapor. Here, we introduce an omniphobic ZIF-8 composite membrane that traps volatile organic compounds under vacuum through crystal phase transitions and enhances water evaporation via linkage swing within hydrophobic micropores.
View Article and Find Full Text PDFGels
August 2025
School of Petroleum Engineering, Xi'an Shiyou University, Xi'an 710065, China.
To address the issue of drilling fluid performance drop and wellbore instability induced by desorption between treatment agents and clay in the high-temperature environment of ultra-deep drilling, this study synthesized three organosilicon polymers (ADE, ADM, ADD) with different substituents. The study confirmed that the covalent bond significantly improved the high-temperature adsorption resistance of clay, which is closely related to the interface behavior of gels. Through rolling recovery, rheology, and filtration experiments for performance evaluation, these organic silicon polymers showed excellent high-temperature performance: the shale rolling recovery rate exceeded 80% at 210 °C, and the filtration loss was reduced to 14 mL, with a reduction rate of 53.
View Article and Find Full Text PDFDuring the process of oil and gas drilling, due to the existence of pores or micro-cracks, drilling fluid is prone to invade the formation. Under the action of hydration expansion of clay in the formation and liquid pressure, wellbore instability occurs. In order to reduce the wellbore instability caused by drilling fluid intrusion into the formation, this study proposed a method of forming a dynamic hydrogen bond cross-linked network weak gel structure with modified nano-silica and P(AM-AAC).
View Article and Find Full Text PDFACS Nano
September 2025
State Key Laboratory of Continental Shale Oil, Joint International Research Laboratory of Advanced Chemical Catalytic Materials & Surface Science, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, PR China.
Developing high-performance supported metal catalysts for the Heck cross-coupling reaction of aryl halides is appealing but challenging. Single atom catalysts (SACs) have shown potential for various reactions, but insufficient metallic properties and electronic quantum states of the mononuclear metal sites can not efficiently catalyze complicated molecular transformations. Herein, we report an efficient heterogeneous catalyst with highly exposed subnanometric palladium ensembles decorated over oxygen vacancy-containing yttrium oxide (Pd/YO) designed to overcome these limitations.
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