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An enhanced water flux and anti-fouling nanocomposite ultrafiltration membrane based on quaternary ammoniumpropylated polysilsesquioxane (QAPS)/cellulose acetate (QAPS@CA) was fabricated by in situ sol-gel processing via phase inversion followed by quaternization with methyl iodide (CHI). Membrane characterizations were performed based on the contact angle, FTIR, SEM, and TGA properties. Membrane separation performance was assessed in terms of pure water flux, rejection, and fouling resistance. The 7%QAPS@CA nanocomposite membrane showed an increased wettability (46.6° water contact angle), water uptake (113%) and a high pure water permeability of ∼370 L m h bar. Furthermore, the 7%QAPS@CA nanocomposite membrane exhibited excellent bactericidal properties (∼97.5% growth inhibition) against Escherichia coli (E. coli) compared to the bare CA membrane (0% growth inhibition). The 7%QAPS@CA nanocomposite membrane can be recommended for water treatment and biomedical applications.
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http://dx.doi.org/10.1016/j.chemosphere.2021.133144 | DOI Listing |
J Hazard Mater
September 2025
College of Veterinary Medicine, Northeast Agricultural University, Harbin 150030, PR China; Key Laboratory of the Provincial Education Department of Heilongjiang for Common Animal Disease Prevention and Treatment, College of Veterinary Medicine, Northeast Agricultural University, Harbin 150030, PR C
Silicon dioxide nanoparticles (SiO NPs) are a novel material with a wide range of applications whose cumulative effects in the body pose certain health risks. The types of gastric injuries caused by different-sized SiO NPs and their mechanisms, however, remain unclear. Based on this, we established a mouse subchronic exposure model (10 mg/kg/d, 21 consecutive days of tube-feeding) with different SiO NP sizes (50, 300, and 1000 nm) in conjunction with in vitro MC9 and BMMCs models (160 μg/mL exposure for 24 h) to explore the gastric injury mechanisms.
View Article and Find Full Text PDFWater Res
September 2025
State Key Laboratory of Soil Pollution Control and Safety, Department of Environmental Science, Zhejiang University, Hangzhou 310058, China; Future Environment Laboratory, Innovation Center of Yangtze River Delta, Zhejiang University, Jiaxing 314100, China. Electronic address:
Accelerating the rate-limiting surface Fe(III)/Fe(II) redox cycling is pivotal for efficient iron-mediated Fenton-like decontamination, yet conventional reductants (e.g., toxic hydroxylamine, thiosulfate) suffer from secondary toxicity, self-quenching, and heavy metal leaching.
View Article and Find Full Text PDFJ Environ Manage
September 2025
Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse, Shandong Key Laboratory of Environmental Processes and Health, School of Environmental Science and Engineering, Shandong University, Qingdao, 266237, China. Electronic address:
Anaerobic self-forming dynamic membrane (AnSFDM) bioreactors have attracted increasing attention owing to their cost-effectiveness and lower carbon footprint. AnSFDM formation is the initial process of their operation and of pivotal importance for determining the basic characteristics of AnSFDMs. Nevertheless, the effect of operational parameters on the AnSFDM formation process has not been studied in a systematical and quantitative manner.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Environmental Science and Engineering Program, Biological and Environmental Science and Engineering (BESE) Division, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia.
Solar-driven desalination has emerged as a sustainable and efficient solution for addressing global water scarcity, especially beneficial in remote, off-grid, and disaster-affected regions. Among emerging technologies, photothermal membrane distillation (PMD) stands out due to its effective solar-energy conversion, scalability, and simplicity. Here, we report a hybrid PMD membrane fabricated by electrospinning MXene (TiCT) nanosheets integrated with silver nanoparticles (AgNPs) onto a poly(vinylidene fluoride--hexafluoropropylene) (PH) substrate.
View Article and Find Full Text PDFSci Total Environ
September 2025
Faculty of Civil and Environmental Engineering, Technion, Israel. Electronic address:
The marine surface microlayer (SML) is distinct from the subsurface water by physical, chemical and biological properties. Being the interface, the SML regulates mass and energy transfer between the ocean and the overlying atmosphere. Given the wide surface area covered by oceans, even small change in flux may have a significant global impact.
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