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Article Abstract
In the absence of ligand, CsCO-promoted cross-coupling reaction of arenes with cyano-/nitro-substituted aryl halides in DMSO affording biaryls is reported. The cyano/nitro group in biaryls is useful and convenient for further transformation. The formation of dibenzofurans resulting from the reactions between arenes and 1-bromo-2-iodobenzene is also reported. On the basis of control experiments and theoretical studies, a radical mechanism is proposed for the formation of biaryls.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8223439 | PMC |
| http://dx.doi.org/10.1021/acsomega.1c01736 | DOI Listing |
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