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To overcome shortcomings of the traditional freeze-thaw method for PVA hydrogel preparation, we develop a one-step mild method, which induces PVA crystallization to form hydrogels through small molecules containing hydroxyl and carboxyl groups. The obtained hydrogels showed high mechanical properties, untypical plasticity with short gelation time and repeatable sol-gel transformation.
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http://dx.doi.org/10.1039/d1cc00578b | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Department of Chemistry, Fatima Jinnah Women University, Rawalpindi 46000, Pakistan.
Significant progress has been achieved in PbS colloidal quantum dot solar cells (CQDSCs) by concentrating on structural engineering, band-alignment engineering, and enhancing the interfacial functionality of colloidal quantum dots (CQDs). Nonetheless, designing a durable and efficient photovoltaic device still represents a considerable obstacle for scientists in this domain. The present work demonstrates that the photovoltaic performance of PbS CQDSCs can be increased by adding 1-5 wt % yttrium into the zinc oxide (YZO) ETL.
View Article and Find Full Text PDFOrg Lett
September 2025
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China.
A palladium-catalyzed construction of amino β-lactone derivatives is described herein. This method applies readily available aryl amines and alkenyl carboxylic acids as starting materials, providing the amino β-lactone under mild reaction conditions in one step. The deuterium labeling experiment revealed that the β-H elimination process after aminopalladation was effectively suppressed under the excess amount of I, thus enabling further oxidation and reductive elimination to afford the target amino β-lactones.
View Article and Find Full Text PDFNat Commun
September 2025
Henan Key Laboratory of Diamond Optoelectronic Material and Devices, Key Laboratory of Material Physics, Ministry of Education, School of Physics, Zhengzhou University, Zhengzhou, China.
Fluorescent carbon dots (CDs) have garnered significant attention for their unique optoelectronic properties and applications, but their practical employment is hampered by the excessive synthesis temperature, tedious post-processing and limited solid-state luminescence efficiency. Herein, we develop a facile molten salt method to achieve the one-step synthesis of full-color CDs with efficient solid-state emission. Comprehensively, kilogram-scale solid-state CDs with a quantum yield of 90% can be readily synthesized via a salt-assisted approach under mild conditions (100-142 °C) within 10 min.
View Article and Find Full Text PDFNat Commun
September 2025
College of Chemistry and Chemical Engineering, Hunan University, Changsha, China.
Supported small and dense high-entropy-alloy nanoparticles (HEA-NPs) are promising functional materials for many applications. However, their synthesis remains a grand challenge because the extreme heating typically required to raise the entropic contribution to the formation of a solid solution unavoidably causes the sintering of HEA-NPs. Herein, we present a one-step continuous-flow spray pyrolysis strategy to synthesize multicomponent (from quinary to denary) HEA-NPs with an average size of <2 nanometers and metal loadings of ~30 wt% uniformly dispersed on various carbon substrates, including graphene and carbon black.
View Article and Find Full Text PDFNat Commun
August 2025
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China.
Acetone is a crucial chemical and solvent with extensive industrial applications, traditionally synthesized from propane through multi-step processes that demand high temperatures and pressures. Here, we report a selective one-step conversion of propane to acetone using a heterogeneous electro-Fenton process (h-EFP) under mild conditions. In this process, concentrated ·OH radicals are generated in an iron/carbon hybrid cathode via a two-electron oxygen reduction reaction followed by HO conversion.
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