Synthesis and Characterization of a New Aluminosilicate Molecular Sieve from Aluminosilica Perhydrate Hydrogel.

A novel structure aluminosilicate molecular sieve, named BUCT-3, was prepared by dynamic hydrothermal synthesis, and the critical factor to obtain the new structure is using an active silicon and aluminum source, aluminosilica perhydrate hydrogel. Meanwhile, only high content of O-O bonds can ensure the pure phase of BUCT-3. Through the characterization of x-ray powder diffraction (XRD), Fourier transform infrared spectra (FTIR), scanning electron microscopy (SEM), and so on, some structure and morphology information of BUCT-3 molecular sieves as well as the special silicon and aluminum source was obtained. It's worth noticing that the O-O bonds of reactants can be reserved in the products, and thus, help us to get a new structure with cell parameters a = 8.9645 Å, b = 15.2727 Å, c = 11.3907 Å, α = 90°, β = 93.858°, γ = 90°. The crystal system is monoclinic. Though the thermostability of BUCT-3 is not satisfactory, its potential application derived from O-O bonds cannot be neglected.