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Using solar energy to achieve seawater desalination and sewage disposal has received tremendous attention for its potential possibility to produce clean freshwater. However, the low solar-thermal conversion efficiency for solar absorber materials obstacles their practical applications. Herein, Ag nanoparticles modified floating carbon cloth (ANCC) are first synthesized via wet impregnation, photoreduction, and low-temperature drying strategy, which could float on the water and absorb the solar energy efficiently. It is worth noting that vaporization rate of ANCC with a high wide-spectrum absorption (92.39%) for the entire range of optical spectrum (200-2500 nm) is up to 1.36 kg h m under AM 1.5, which corresponds to solar-thermal conversion efficiency of ∼92.82% with superior seawater desalination and sewage disposal performance. Plasmon Ag promotes the conversion efficiency obviously compared to the pristine carbon cloth because the surface plasmon resonance effect could increase the local temperature greatly. After the desalination, the ion concentrations (Mg, K, Ca, and Na ions) in water are far below the limit of drinking water. Such high-performance floating ANCC material may offer a feasible and paradigm strategy to manage the global water contamination and freshwater shortage problem.
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http://dx.doi.org/10.1021/acsami.8b20665 | DOI Listing |
Langmuir
September 2025
Xianyang Key Laboratory of Solar Thermal Conversion Materials, Shaanxi Polytechnic University, Xianyang 712000, China.
Solar-driven interfacial evaporation (SDIE) is an emerging eco-friendly and low-carbon technology and has been widely studied in the field of photothermal applications in recent years. With the attention and development of SDIE in innovation fields, new strategies, structures, and typical materials are gradually being developed and applied. Therefore, it is important to report on these latest developments.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
School of Physics and Astronomy, Beijing Normal University, Beijing 100875, China. Electronic address:
Phase change materials (PCMs)-integrated solar-thermal-electric generators (STEGs) have emerged as a promising platform for sustainable solar energy harvesting, yet faces critical challenges including liquid phase instability, insufficient photothermal efficiency, and limited thermoelectric output. Herein, we engineered hierarchical photonic confinement through the assembly of plasmonic CuS nanoparticles, broadband-absorbing MoS nanosheets, and porous bacterial cellulose (BC). In this tripartite architecture, BC matrix provides robust structural integrity and enhances heat transfer via its 3D interconnected nanoporous structure; MoS nanosheets enable extended photon harvesting across the ultraviolet to near-infrared spectrum; CuS nanoparticles amplify near-field optical effects through localized surface plasmon resonance.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2025
Department of Chemistry, Instituto de Investigación Química de la Universidad de La Rioja (IQUR), Universidad de La Rioja, C/Madre de Dios 53, Logroño, 26004, Spain.
Solar energy storage is key to overcome the intermittent character of sunlight. We present a sustainable solution based on norbornadiene-quadricyclane pairs for molecular solar thermal (MOST) energy storage working in highly concentrated neutral water solutions and solid state. Photochemical preparation of high-energy, metastable isomers in previously unattainable 1.
View Article and Find Full Text PDFNanoscale
August 2025
Hunan Key Laboratory of Nanophotonic and Devices, School of Physics, Central South University, Changsha, 410083, China.
Photothermal conversion materials can efficiently convert solar energy into directly usable heat energy, thereby reducing carbon emissions. However, most photothermal conversion materials are complex to prepare and have a long cycle, and their photothermal performance is not ideal. These problems limit their practical application.
View Article and Find Full Text PDFChemSusChem
August 2025
Department of Chemistry and Chemical Engineering, Chalmers University of Technology, 41296, Gothenburg, Sweden.
Two low molecular weight acceptor-acceptor norbornadiene (NBD) photoswitches functionalized with meta- and ortho-substituted pyridine and cyano groups are presented. These molecular systems can be converted between four states in response to light, acid, base, and heat. Quantitative conversion to higher energy metastable quadricyclane (QC) photoisomers is achieved upon UV irradiation, with photoisomerization quantum yields of 37% and 24% for NBD 1 and 2.
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