428 results match your criteria: "Clausthal University of Technology[Affiliation]"

Topic models are a useful and popular method to find latent topics of documents. However, the short and sparse texts in social media micro-blogs such as Twitter are challenging for the most commonly used Latent Dirichlet Allocation (LDA) topic model. We compare the performance of the standard LDA topic model with the Gibbs Sampler Dirichlet Multinomial Model (GSDMM) and the Gamma Poisson Mixture Model (GPM), which are specifically designed for sparse data.

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Interaction of Cyanoacrylate with Metal Oxide Surfaces (Cu, Al).

Chemphyschem

May 2023

Clausthal Center for Materials Technology, Clausthal University of Technology, Agricolastrasse 2, 38678, Clausthal-Zellerfeld, Germany.

The front cover artwork is provided by Prof. Maus-Friedrichs' group at the Clausthal University of Technology. The image shows the molecular interaction formed at the interface between the adhesive cyanoacrylate and a natively oxidized copper or aluminium surface.

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A rising interest in a strong hydrogen economy as a part of the future net-zero economy results in an increasing necessity to store hydrogen as a raw material or an energy carrier. Experience and studies show that storing hydrogen in deep underground sites could enable microbial conversion of hydrogen. To predict and examine the loss of hydrogen, laboratory studies, and analysis are essential.

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Article Synopsis
  • Microplastics are a significant environmental issue, necessitating a reduction in both petrochemical and bio-based plastics, as they accumulate in food chains and pose risks to animals and humans.
  • The study explored various advanced oxidation processes (AOPs) like ultrasounds and ultraviolet irradiation to enhance the biodegradability of polylactic acid (PLA) films, treating them for durations of 1 to 6 hours.
  • Results showed that PLA films achieved up to 90% weight loss using a commercial enzyme cocktail during composting, and notably, PLA was transformed into bacterial nanocellulose post-enzymatic hydrolysis.
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This study presents a novel data-driven approach for calculating multiphase flow rates in electrical submersible pumped wells. Traditional methods for estimating flow rates at test separators fail to identify production trends and require additional costs for maintenance. In response, virtual flow metering (VFM) has emerged as an attractive research area in the oil and gas industry.

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Although microwave photonic approaches have been used for fiber sensing applications before, most contributions in the past dealt with evaluating the sensor signal's amplitude. Carrying this topic on, the authors previously presented a scheme for the interrogation of fiber sensors that was based on a fiber Bragg grating's phase response for the electrical signal. However, neither has the measurement setup been analyzed nor have the amplitude and phase-based approaches been compared in detail before.

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The paired antennal lobes were long considered the sole primary processing centers of the olfactory pathway in holometabolous insects receiving input from the olfactory sensory neurons of the antennae and mouthparts. In hemimetabolous insects, however, olfactory cues of the antennae and palps are processed separately. For the holometabolous red flour beetle , we could show that primary processing of the palpal and antennal olfactory input also occurs separately and at distinct neuronal centers.

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The reaction of mercaptoacetic acid esters with pentachloro-2-nitro-1,3-butadiene provides the appropriate precursors for the synthesis of 2,3,4-trisubstituted benzo[]quinolines. These heterocycles are easily accessible via a single-step reaction with naphthalen-1-amine or anthracen-1-amine as the precursor. Due to the steric bulk and high electron density ring, the ring closure of benzo[]quinolines takes place exclusively.

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Using a quartz crystal microbalance with dissipation monitoring (QCM-D), the complex high-frequency viscosity, = η' - η'', of concentrated solutions of a monoclonal antibody (mAb) was studied with respect to its dependence on temperature, , and concentration, . Lysozyme and bovine serum albumin (BSA) served as reference materials. Viscoelasticity was found for the mAb solution, while the reference materials behaved like Newtonian liquids.

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Using a reinforcement-learning algorithm, we model an agent-based simulation of a public goods game with endogenous punishment institutions. We propose an outcome-based model of social preferences that determines the agent's utility, contribution, and voting behavior during the learning procedure. Comparing our simulation to experimental evidence, we find that the model can replicate human behavior and we can explain the underlying motives of this behavior.

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The interaction of silane and water is discussed controversially in literature: some authors suggest monosilane and water react kinetically and sufficiently fast enough to remove water, while others state the reaction occurs only at elevated temperatures. This question is of technological interest for the removal of unavoidable water residues in Ar gases. Thermodynamic calculations show that virtually complete removal of water is expected with superstoichiometric silane addition.

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Imidazolium salts were prepared which possess 2-ethoxyethyl pivalate or 2-(2-ethoxyethoxy)ethyl pivalate groups as amphiphilic side chains with oxygen donors as well as -butyl substituents as hydrophobic groups. The N-heterocyclic carbenes of the salts, characterized by Li and C NMR spectroscopy as well as by Rh and Ir complex formation, were used as starting materials for the preparation of the corresponding imidazole-2-thiones and imidazole-2-selenones. Flotation experiments in Hallimond tubes under variation of the air flow, pH, concentration and flotation time were performed.

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Interaction of Cyanoacrylate with Metal Oxide Surfaces (Cu, Al).

Chemphyschem

May 2023

Clausthal Center for Materials Technology, Clausthal University of Technology, Agricolastrasse 2, 38678, Clausthal-Zellerfeld, Germany.

Cyanoacrylates are an extremely reactive class of adhesives. Despite their commercial use as instant adhesives, the adhesion mechanism, especially to technically relevant oxidized metal surfaces, has not yet been sufficiently investigated. In the present work, ultra-thin ethyl cyanoacrylate films are deposited on copper oxide and aluminum oxide by spin coating and cured there.

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Effect of Noise on Determining Ultrathin-Film Parameters from QCM-D Data with the Viscoelastic Model.

Sensors (Basel)

January 2023

Polymer Science, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.

Quartz crystal microbalance with dissipation monitoring (QCM-D) is a well-established technique for studying soft films. It can provide gravimetric as well as nongravimetric information about a film, such as its thickness and mechanical properties. The interpretation of sets of overtone-normalized frequency shifts, ∆/, and overtone-normalized shifts in half-bandwidth, ΔΓ/, provided by QCM-D relies on a model that, in general, contains five independent parameters that are needed to describe film thickness and frequency-dependent viscoelastic properties.

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Article Synopsis
  • A new series of organic dyes featuring a diquat moiety as an electron acceptor have been synthesized and characterized, with their properties supported by DFT calculations.
  • These dyes were tested in the aerobic thiocyanation process involving indoles and pyrroles, demonstrating impressive photocatalytic activity under visible light, achieving yields of up to 97%.
  • The study also discusses the photocatalytic performance of standalone diquat and methyl viologen and their interaction in forming an electron donor-acceptor complex.
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Green Manufacturing for Herbal Remedies with Advanced Pharmaceutical Technology.

Pharmaceutics

January 2023

Institute for Separation and Process Technology, Clausthal University of Technology, Leibnizstr. 15, 38678 Clausthal-Zellerfeld, Germany.

Herbal remedies are in most cases still manufactured with traditional equipment installations and processes. Innovative chemical process engineering methods such as modeling and process intensification with green technology could contribute to the economic and ecologic future of those botanicals. The integration of modern unit operations such as water-based pressurized hot water extraction and inline measurement devices for process analytical technology approaches in traditional extraction processes is exemplified.

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Using electrolysis systems to degrade organics in wastewater encourages this technique to remove micropollutants (MPs) in different types of water. In this work, a cell consisting of an anode as a boron-doped diamond (BDD) electrode combined with a gas diffusion (GDE) cathode without a separator showed that MPs degradation can be effectively achieved. Investigating different operating parameters, it was stated that applying a low current density (2 mA/cm) and setting the Reynolds number of the electrolyte flow through the cell at the laminar range raised the treatment time by 3-fold at the same energy demand.

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Microbial fuel cells are a promising technology for future wastewater treatment, as it allows cleaning and power generation simultaneously. The bottleneck of microbial fuel cells is often its cathodes because they determine the power output. Gas diffusion electrodes might overcome this bottleneck due to their low production costs and high oxygen reduction rates.

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The experimental data in this submission is related to parts of the dissertation "Bruchkurvenmodellierung von kohlenstofffaserverstärkten Kunststoffen bei mehrachsig nichtproportionaler Ermüdungsbeanspruchung" [1] and partly to further publications on the fatigue of carbon fibre-reinforced plastic [2]. The background to the experimental investigations is the need to better understand the behavior of fiber-reinforced plastics under various multiaxial loads. For this purpose, comprehensive tests ranging from uniaxial tests on unidirectional up to multiaxial tests on multidirectional specimens are conducted.

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Research and industry are calling for additively manufactured multi-materials, as these are expected to create more efficient components, but there is a lack of information on corrosion resistance, especially since there is a risk of bimetallic corrosion with two metallic components. In this study, the corrosion behaviour of a multi-material made of 316L and CuSn10 is investigated before and after a stress relief annealing using linear sweep voltammetry. For this purpose, a compromise had to be found in the heat treatment parameters in order to be able to treat both materials together.

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Filigree structures can be manufactured via two-photon polymerization (2PP) operating in the regime of nonlinear light absorption. For the first time, it is possible to apply this technique to the powder processing of ceramic structures with a feature size in the range of the critical defect sizes responsible for brittle fracture and, thus, affecting fracture toughness of high-performance ceramics. In this way, tailoring of advanced properties can be achieved already in the shaping process.

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Chitosan is a biopolymer that, due to its versatile bioactive properties, has applications in several areas, including food, medicine and pharmaceuticals. In the field of tissue engineering, chitosan can be used, for example, as a dressing to treat wounds or dermal damage, such as burns or abrasions. This work deals with the controlled release of tea tree oil from chitosan-based polymeric films and droplets containing gold nanoparticles (AuNP).

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Modeling acoustic cavitation with inhomogeneous polydisperse bubble population on a large scale.

Ultrason Sonochem

September 2022

Clausthal University of Technology, Institute of Applied Mechanics, Adolph-Roemer-Straße 2A, 38678 Clausthal-Zellerfeld, Germany.

A model for acoustic cavitation flows able to depict large geometries and time scales is proposed. It is based on the Euler-Lagrange approach incorporating a novel Helmholtz solver with a non-linear acoustic attenuation model. The method is able to depict a polydisperse bubble population, which may vary locally.

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Understanding Braess' Paradox in power grids.

Nat Commun

September 2022

Chair for Network Dynamics, Center for Advancing Electronics Dresden (cfaed) and Institute for Theoretical Physics, Technical University of Dresden, 01062, Dresden, Germany.

The ongoing energy transition requires power grid extensions to connect renewable generators to consumers and to transfer power among distant areas. The process of grid extension requires a large investment of resources and is supposed to make grid operation more robust. Yet, counter-intuitively, increasing the capacity of existing lines or adding new lines may also reduce the overall system performance and even promote blackouts due to Braess' paradox.

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