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This study investigates the effects of porous obstruction quantity on the explosion dynamics of CH/H hybrid fuel mixtures in semiconfined pipelines through integrated experimental and numerical approaches. High-frequency pressure transducers and ultrahigh-speed cameras were employed to record overpressure evolution and flame morphology, while numerical simulations incorporating the Charlette flame wrinkling model elucidated turbulence-flame interaction mechanisms. The study compared configurations with sequential porous obstructions to single-obstruction setups, revealing that obstruction number and blockage ratio critically govern flame speed, peak overpressure, and turbulent intensity. Under sequential-obstruction conditions, the flame transitions from laminar to turbulent after passing the first obstacle, exhibiting a 13.8-28.7% velocity enhancement. The second obstruction reduces turbulence effects, and suppression efficiency decays with increasing obstacle count. Overpressure analysis demonstrates that at an 87% blockage ratio, sequential obstructions elevate maximum overpressures at monitoring points PT1 and PT2 by 66.2 and 96.9%, respectively, compared to single-obstruction configurations. The deflagration index migrates toward ignition-adjacent regions, indicating enhanced explosion severity. Numerical validation confirms the Charlette model's precision in predicting flame front dynamics and capturing extreme flow-field variations (Mach number ≤1.00, vorticity peaks ≤40,000 s ) between obstacles. This work provides theoretical foundations for hydrogen-mixed gas explosion mitigation and pipeline safety design.
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http://dx.doi.org/10.1021/acsomega.5c04168 | DOI Listing |
Angew Chem Int Ed Engl
September 2025
State Key Laboratory of Bioinspired Interfacial Materials Science, Bioinspired Science Innovation Center, Hangzhou International Innovation Institute, Beihang University, Hangzhou, 311115, China.
Electrochemical nitrogen fixation-a sustainable pathway for converting abundant N into NH using renewable energy-holds transformative potential for revolutionizing artificial nitrogen cycles. Nevertheless, even the state-of-the-art catalytic systems also suffer from inadequate N adsorption capacity, which critically limits ammonia production rates and Faradaic efficiency (FE). To overcome this bottleneck, we strategically leveraged the antiferroelectric properties of SnO to establish dipole-dipole interactions with N molecules, synergistically enhancing both N adsorption and activation kinetics.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, P. R. China.
Exhaled breath analysis offers noninvasive, early lung cancer detection via volatile organic compound (VOC) biomarkers, surpassing blood-based methods. Surface-enhanced Raman spectroscopy (SERS) is ideal for this purpose, combining molecular fingerprint specificity with single-molecule sensitivity. However, conventional SERS substrates face a fundamental limitation: while porous materials such as metal-organic frameworks effectively adsorb VOCs through their subnanometer pores (0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Key Laboratory of Atomic and Molecular Physics & Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, China.
Overcoming the persistent challenges of high operating temperatures and poor selectivity in metal oxide semiconductor (MOS) gas sensors, this work enhances defect sites in the sensing material through heterostructure construction and builds mesoporous architectures using MOF-derived carbon skeletons as templates. The synergistic effects of multiple mechanisms significantly improve gas-sensing performance, successfully fabricating a ZnO/PCS flexible room-temperature gas sensor with exceptional room-temperature DMF detection capabilities. The nitrogen-containing porous carbon skeletons (PCSs) template shows a stable mesoporous microstructure with large pore volume.
View Article and Find Full Text PDFAnal Chim Acta
November 2025
College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, 266109, China. Electronic address:
Background: The separation of structural isomers is always a challenging task for liquid chromatography because of their similar physicochemical property. Research has found that materials with regular microporous structures exhibit excellent isomer separation performance. However, as the most easily available chromatographic material, silica stationary phases with regular and small mesopore structure have not yet been prepared, and it remains to be confirmed whether narrow pores in silica materials have the enhancing effect on shape selectivity in the separation of structural isomers.
View Article and Find Full Text PDFAm J Infect Control
September 2025
Department of Food Science, 745 Agricultural Mall Drive, Purdue University, West Lafayette, IN USA 47907. Electronic address:
Background: Manual wiping of surfaces, a primary method in preventing hospital acquired infections, can vary significantly in its ability to eliminate bacteria and prevent cross-contamination.
Methods: Four liquid-based cleaning and disinfecting formulations comprised of hydrogen peroxide (HP), ethoxylated alcohol (EA), quaternary ammonium compounds (Quat and Quat2), or a water-based control were evaluated for their bactericidal efficacy in combination with three different wiping materials: microfiber, polypropylene, and cotton. Each chemistry and wipe combination were evaluated for its ability to reduce microbial contamination on a hard, non-porous surface measuring one meter.