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The synergy between the memristive effect and negative differential resistance (NDR) offers promising prospects for advancing electronic devices and circuits. Predictable outcomes include the development of devices with improved performance and functionality that are applicable across a wide range of fields, from computing architecture to neuromorphic engineering. Despite the growing body of literature exploring this convergence, the effective implementation of the NDR effect in memristors faces many challenges. Several memristive materials-including VO, TaO, and chalcogenides-have demonstrated promising NDR effects. Among them, niobium oxide uniquely combines steep (<3 ns), endurable (>10 cycles) negative differential resistance with biophysically plausible spiking dynamics-enabled by its dual current-controlled and thermally driven mechanisms-making it ideal for energy-efficient neuromorphic primitives. This paper reviews the complex phenomenon of NDR and its applications in niobium oxide memristors while analyzing its potential future applications in electronic systems. By outlining the NDR effect and its applications in niobium oxide memristors, this paper aims to provide valuable insights for researchers in the field.
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http://dx.doi.org/10.1039/d5nr02491a | DOI Listing |
Small
September 2025
Department of Materials Science, Key Laboratory of Automobile Materials, MOE and State Key Laboratory of High Pressure and Superhard Materials, International Center of Future Science, Jilin University, Changchun, 130012, China.
Molybdenum disulfide (MoS) exhibits excellent lubrication capacity rooted in its layered structure, but it suffers significant structural and functional deterioration due to oxidation in ambient environments, limiting its applications. Concerted efforts are focused on enhancing the antioxidation ability of MoS, but challenges remain. This work conceptualizes and demonstrates a contrarian design of MoS-based film via metal incorporation and oxidation based on consideration of key fundamental principles of thermodynamics, chemistry, and physical mechanics.
View Article and Find Full Text PDFInt J Mol Sci
August 2025
Faculty of Space Technologies, AGH University of Kraków, al. A. Mickiewicza 30, 30-059 Kraków, Poland.
Anodised metal matrices represent a versatile and multifunctional platform for the development of advanced materials with tunable physicochemical properties. Through electrochemical oxidation processes-commonly referred to as anodisation-metals such as aluminium, titanium, niobium, zinc and tantalum can be transformed into structured oxide layers with defined porosity, thickness and surface morphology. These methods enable the fabrication of ordered nanoporous arrays, nanotubes and nanowires, depending on the process parameters and the type of metal.
View Article and Find Full Text PDFNanoscale
August 2025
College of Physics and Energy, Fujian Normal University, Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, Fuzhou, 350117, China.
The synergy between the memristive effect and negative differential resistance (NDR) offers promising prospects for advancing electronic devices and circuits. Predictable outcomes include the development of devices with improved performance and functionality that are applicable across a wide range of fields, from computing architecture to neuromorphic engineering. Despite the growing body of literature exploring this convergence, the effective implementation of the NDR effect in memristors faces many challenges.
View Article and Find Full Text PDFAdv Mater
August 2025
College of Smart Materials and Future Energy, Fudan University, Shanghai, 200433, China.
Reversible hydrogen storage in magnesium hydride (MgH) remains hindered by intrinsic, complicated kinetic barriers associated with both hydrogen release and uptake, particularly under mild conditions. In this work, graphene-confined, low-crystallinity niobium oxide nanoparticles are developed to optimize the kinetic barriers across all stages of hydrogen absorption and desorption in MgH. This is realized by the synergistic effect of in situ-generated stable multivalent niobium oxide (NbO) and the electronically modulating graphene.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2025
NaMLab gGmbH, 01187 Dresden, Germany.
The pristine state of hafnium-based ferroelectric devices exhibits various unwanted properties, such as imprinting and peak splitting, which diminish with bipolar cycling. The incorporation of a niobium oxide layer at different positions in metal-ferroelectric-metal and metal-ferroelectric-insulator-metal stacks is used to modify the pristine state of the device. X-ray photoelectron spectroscopy and transmission electron microscopy measurements are used to investigate the influence of niobium oxide on the zirconium hafnium oxide layer.
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