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This study presents a techno-economic optimization of hydrogen production using hybrid wind-solar systems across six Australian cities, highlighting Australia's green hydrogen potential. A hybrid PV-wind-electrolyzer-hydrogen tank (PV-WT-EL-HT) system demonstrated superior performance, with Perth achieving the lowest Levelized Cost of Hydrogen (LCOH) at $0.582/kg, Net Present Cost (NPC) of $27.5k, and Levelized Cost of Electricity (LCOE) of $0.0166/kWh. Perth also showed the highest return on investment, present worth, and annual worth, making it the preferred project site. All locations maintained a 100% renewable fraction, proving the viability of fully decarbonized hydrogen production. Metaheuristic validation using nine algorithms showed the Mayfly Algorithm improved techno-economic metrics by 3-8% over HOMER Pro models. The Gray Wolf and Whale Optimization Algorithms enhanced system stability under wind-dominant conditions. Sensitivity analysis revealed that blockchain-based dynamic pricing and reinforcement learning-driven demand response yielded 8-10% cost savings under ± 15% demand variability. Nevertheless, regional disparities persist; southern cities such as Hobart and Melbourne exhibited 20-30% higher LCOH due to reduced renewable resource availability, while densely urbanized cities like Sydney presented optimization ceilings, with minimal LCOH improvements despite algorithmic refinements. Investment in advanced materials (e.g., perovskite-VAWTs) and offshore platforms targeting hydrogen export markets is essential. Perth emerged as the optimal hub, with hybrid PV/WT/B systems producing 200-250 MWh/month of electricity and 200-250 kg/month of hydrogen, supported by policy incentives. This work offers a blueprint for region-specific, AI-augmented hydrogen systems to drive Australia's hydrogen economy toward $2.10/kg by 2030.
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http://dx.doi.org/10.1038/s41598-025-17506-z | DOI Listing |
J Phys Chem B
September 2025
Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012, China.
Understanding hydrogen bonding and ion-specific interactions in water, sodium sulfate (NaSO), and acetonitrile (ACN) systems remains challenging due to their complex, dynamic nature. Here, Raman spectroscopy is employed to probe hydrogen bonding networks and ion reorganization in NaSO aqueous solutions with different ACN concentrations. The results indicate that, at low ACN concentrations in the ternary solutions, hydrogen bonding between ACN and water molecules disrupts the original hydration structure of the ions, resulting in the formation of small ion clusters via electrostatic interactions.
View Article and Find Full Text PDFMicrob Cell Fact
September 2025
Biochemistry Division, Chemistry Department, Faculty of Science, Tanta University, Tanta, 31257, Egypt.
Background And Aim: Synthetic dyes in the textile industry pose risks to human health and environmental safety. The current study aims to examine the efficacy of a novel esterase derived from an endophyte fungus in decolorizing diverse dyes, focusing on its production, purification, optimization, and characterization.
Results: Trichoderma afroharzianum AUMC16433, a novel fungal endophyte with esterase-producing ability, was first detected from the cladodes of Opuntia ficus indica by ITS-rRNA sequencing.
Environ Sci Pollut Res Int
September 2025
Department of Dyes and Chemical Engineering, Bangladesh University of Textiles, Dhaka, Bangladesh.
This study quantitatively evaluated the adsorption performance of natural bentonite for removing three dye classes-cationic (Basic dye: BEZACRYL RED GRL), anionic (Reactive dye: AVITERA LIGHT RED SE), and non-ionic (Disperse dye: BEMACRON BLUE HP3R) from synthetic textile wastewater. Batch adsorption experiments were conducted under varying conditions of contact time (15-90 min), adsorbent dosage (20-60 g L⁻), pH (4 and 12), and temperature (25-100 °C), with dye concentrations quantified by UV-Vis spectroscopy. At a contact time of 30 min and room temperature (25 °C), maximum removal efficiencies reached 99.
View Article and Find Full Text PDFNat Chem
September 2025
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA.
Proton transfer plays an important role in both hydrogen and oxygen evolution reactions during electrocatalytic water splitting to produce green hydrogen. However, directly adapting the conventional proton/deuterium kinetic isotope effect to study proton transfer in heterogeneous electrocatalytic processes is challenging. Here we propose using the shift in the Tafel slope between protic and deuteric electrolytes, or the Tafel slope isotope effect, as an effective probe of proton transfer characteristics.
View Article and Find Full Text PDFOrg Lett
September 2025
Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Wushan Rd-381, Guangzhou 510641, P.R. China.
Herein, we report the first regio- and enantioselective synthesis of tetrahydropyrido[2,3-]pyrazines using a chiral iridacycle catalyst. Pyridyl diamines and diketones undergo sequential annulation and asymmetric transfer hydrogenation of the generated pyrido[2,3-]pyrazine intermediates. This method provides diverse fused N-heterocycles in high yields (up to 95%) and enantioselectivity (98.
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