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Norfloxacin (NOR) has raised growing concerns over food safety and environmental sustainability due to its persistence and bioaccumulation. The luminescence turn-on effect induced by NOR offers a promising approach for the development of advanced sensing platform and anticounterfeiting platform. In this work, two novel one-dimensional chain-like lanthanide coordination polymers, and , were successfully synthesized through a facile one-step hydrothermal approach. Interestingly, demonstrates a pronounced luminescence turn-on effect upon reaction with NOR, functioning as a highly selective and sensitive probe for NOR detection, with a detection limit as low as 0.03 μM and a rapid response time (<20 s). The sensing performance is maintained in complicated real-world matrices, including dairy products (milk, eggs), lake water, and tap water. Notably, portable test strips fabricated by immobilizing onto filter paper enable on-site visual identification of NOR contamination within minutes, demonstrating excellent practicality. In addition, the stimuli-responsive luminescence turn-on behavior of and supports their potential application in advanced anticounterfeiting technologies. This work provides a dual-functional platform that integrates luminescence sensing and security features, offering new opportunities for real-time antibiotic monitoring and anticounterfeiting systems.
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http://dx.doi.org/10.1021/acs.analchem.5c03290 | DOI Listing |
Mater Horiz
September 2025
College of Science, Henan Agricultural University, 63 Agricultural Road, Zhengzhou 450002, Henan, P. R. China.
Latent fingerprints (LFPs), as critical carriers of personal identification information, present a long-standing challenge for high-resolution imaging in forensic science. Aggregation-induced emission luminogens (AIEgens), known for their superior luminescence in aggregated or high-viscosity environments, have emerged as ideal candidates for high-contrast fingerprint visualization. In this study, we designed a series of novel AIEgens by introducing diphenylamine (DPA) donor groups at the 3- and 11-positions of a quinazolinone core, effectively constructing twisted intramolecular charge transfer (TICT) systems.
View Article and Find Full Text PDFInorg Chem
August 2025
Institute for New Energy Materials & Low Carbon Technologies, School of Chemistry and Chemical Engineering, School of Materials Science & Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China.
A luminescent lanthanide metal-organic framework, [(TD)Eu(HCO)(DMF)] (Eu-TD, TD/HBTDB = 4,4'-(benzo[][1,2,5] thiadiazole-4,7-diyl)dibenzoic acid), was synthesized via a solvothermal method by coordinating Eu ions with the strongly emissive ligand HBTDB. Single-crystal X-ray diffraction analysis reveals that the Eu-TD is in the hexagonal system with space group 622. Eu-TD demonstrated exceptional selectivity toward Al ions, exhibiting remarkable sensitivity with a low detection limit (limit of detection (LOD) = 0.
View Article and Find Full Text PDFAnal Chem
September 2025
Department of Chemistry and Materials and Nanofiber Engineering Center of Jiangxi Province, Jiangxi Normal University, Nanchang 330022, China.
Norfloxacin (NOR) has raised growing concerns over food safety and environmental sustainability due to its persistence and bioaccumulation. The luminescence turn-on effect induced by NOR offers a promising approach for the development of advanced sensing platform and anticounterfeiting platform. In this work, two novel one-dimensional chain-like lanthanide coordination polymers, and , were successfully synthesized through a facile one-step hydrothermal approach.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2026
Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, 393 Binshui West Road, Tianjin 300387, PR China. Electronic address:
Procaterol, a third-generation long-acting β₂-adrenergic receptor agonist, is widely used in asthma and chronic obstructive pulmonary disease (COPD) treatment. Rapid and sensitive detection of Procaterol is essential for both clinical monitoring and environmental surveillance. This study presents a facile and gram-scale synthesis of tubular silver-based Metal-organic framework (MOF) MONT by employing an ultrasonic-assisted green synthesis strategy (20 kHz ultrasound, 100 W power, 30 min).
View Article and Find Full Text PDFInorg Chem
September 2025
Key Laboratory of Magnetic Molecules and Magnetic Information Materials Ministry of Education & School of Chemistry and Chemical Engineering of Shanxi Normal University, Taiyuan, Shanxi 030032, P. R. China.
The development of dual fluorescence sensors is crucial for reliable and sensitive antibiotic detection. This study reports two isostructural heterobimetallic metal-organic frameworks (MOFs), which are formulated as {[(CH)NH][ZnM(O)(BTC)]·2HO} (M = Co (), Ni (), and HBTC = 1,3,5-benzenetricarboxylic acid) with a (3,6)-connected three-dimensional (3D) dual-channel framework, showing excellent chemical stability and tunable fluorescence. Notably, these MOFs enable ultrasensitive sensing of chloramphenicol (CAP), nitrofurantoin (NFT), nitrofurazone (NFZ), and tetracycline (TC).
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