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The graphene/h-BN heterostructures exhibit a unique plasmon-phonon polaritons coupling mode in the mid-IR frequency spectrum, with adjustable excitation intensity through external voltage. Such an innovation opens up avenues for designing low-power, subwavelength, and electrically tunable devices. A grating structure is introduced in this paper to overcome the constraints posed by previous probe-based methods for wavevector matching. The grating structure simplifies the experimental setup, enhancing the practicality and scalability of the heterostructures. Furthermore, an investigation is conducted into the optical properties and electrical tunability of the grating-integrated graphene/h-BN heterostructures. Numerical simulations and theoretical calculations reveal remarkable electrical tunability of optical transmission characteristics in the type-I band, especially at an incident frequency of 23.816 THz. As external voltage increases, the dispersion curve undergoes a noticeable red shift, reaching a maximum negative absorptivity of -207.36% at 5 V, with reflectivity decreasing to 4.60%. Electric field distribution maps indicate a substantial enhancement in electric field intensity within graphene/h-BN/graphene parts of the structure at 5 V, with the change in electric field direction primarily contributing to the negative absorption. Additionally, the transmittance spectrum confirms the effective modulation of 23.816 THz light transmissivity through adjustments in external voltage, with values of 22.14% at 4 V and 302.77% at 5 V, respectively. The findings provide a foundation for applying graphene/h-BN heterostructures in integrated photonic systems, light manipulation, optical sensing and other fields.
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http://dx.doi.org/10.1364/OE.559287 | DOI Listing |
The graphene/h-BN heterostructures exhibit a unique plasmon-phonon polaritons coupling mode in the mid-IR frequency spectrum, with adjustable excitation intensity through external voltage. Such an innovation opens up avenues for designing low-power, subwavelength, and electrically tunable devices. A grating structure is introduced in this paper to overcome the constraints posed by previous probe-based methods for wavevector matching.
View Article and Find Full Text PDFPhys Rev Lett
July 2025
University of Science and Technology of China, Deep Space Exploration Laboratory, Hefei, Anhui 230026, China.
Moiré superlattices enable engineering of correlated quantum states through tunable periodic potentials, where twist angle controls periodicity but dynamic potential strength modulation remains challenging. Here, we develop a high-pressure quantum transport technique for van der Waals heterostructures, achieving the ultimate pressure limit (∼9 GPa) in encapsulated moiré devices. In aligned graphene/h-BN, we demonstrate that pressure induces a substantial enhancement of the moiré potential strength, evidenced by the suppression of the first valence bandwidth and the near-doubling of the primary band gap.
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2025
Key Laboratory of Life-Organic Analysis of Shandong Province, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273100, China.
Constructing heterojunctions is a proven strategy for developing efficient photocatalytic hydrogen evolution catalysts. In this work, we design graphene/hexagonal boron nitride (h-BN) lateral heterostructures that combine graphene's exceptional charge transport with h-BN's stability. Using state-of-the-art many-body green's function theory (MBGFT) simulations, we establish a band engineering framework through dimensional control, demonstrating that precise modulation of graphene and h-BN domain sizes enables continuous visible-spectrum band gap tuning for efficient hydrogen generation.
View Article and Find Full Text PDFSmall Methods
August 2025
Key Laboratory of Organic Integrated Circuit, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, China.
2D van der Waals multiheterostructures serve as an extensively studied material due to their unique physical properties. However, the multicomponent heterostructure is difficult to obtain on a large scale and is limited by the conventional method of mechanical stacking, which hinders their potential applications. Here a precursor-modulated chemical vapor deposition strategy is reported for selectively growing vertical multiheterostructures, lateral multiheterostructures, and their combinate stackings.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
Yancheng Polytechnic college, Yancheng 224005, China.
We have computationally demonstrated a new method for generating pure spin current with the photogalvanic effect (PGE) by constructing transport junctions using h-BN/graphene/h-BN van der Waals (vdW) heterostructure leads. It has been observed that the pure spin current without any accompanying charge current induced by the PGE can consistently be obtained, regardless of photon energy and polarization/helicity angle, as well as the specific type of polarization (linear, circular, or elliptical). The mechanism lies in the structural inversion symmetry and real space spin polarization antisymmetry of the junctions.
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