Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Solid-state electrolytes (SSEs) have emerged as transformative alternatives to traditional liquid electrolytes, addressing critical challenges while enabling safer, wider operational voltage windows and higher density batteries. High ionic conductivity inorganic solid-state electrolytes (HC-ISEs), such as LGPS (LiGePS), exhibit exceptional ionic conductivity but suffer from interfacial instability, grain boundaries resistance, poor compatibility with lithium metal anodes, and environmental sensitivity. Recent studies have revealed that engineered disorder, through cationic site disordering, amorphous phase integration, and glass-ceramic structural irregularities, can optimize ion diffusion pathways, mitigate interfacial resistance, and enhance electrochemical stability. This review systematically analyzes how controlled disorder elevates HC-ISEs' performance, explores strategies to tailor disordered architectures, and underscores their pivotal role in realizing next-generation solid-state batteries with high reliability and energy density.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acsnano.5c07439 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Ultrafast Al⁺ Conduction through Cooperative Bonding in Disordered Polycarbonate-Polyether Electrolytes.
Small Methods
September 2025
Hebei Key Laboratory of Optic-Electronic Information and Materials, National & Local Joint Engineering Laboratory of New Energy Photoelectric Devices, College of Physics, Science and Technology, Hebei University, Baoding, 071002, China.
As a new generation of high-energy-density energy storage system, solid-state aluminum-ion batteries have attracted much attention. Nowadays polyethylene oxide (PEO)-based electrolytes have been initially applied to Lithium-ion batteries due to their flexible processing and good interfacial compatibility, their application in aluminum-ion batteries still faces problems. To overcome the limitations in aluminum-ion batteries-specifically, strong Al coordination suppressing ion dissociation, high room-temperature crystallinity, and inadequate mechanical strength-this study develops a blended polymer electrolyte (BPE) of polypropylene carbonate (PPC) and PEO.
View Article and Find Full Text PDFFunctionalization of Defective Covalent Organic Frameworks for High-Performance Solid-State Electrolytes.
Small
September 2025
School of Materials Science and Engineering, East China Jiaotong University, Nanchang, 330013, China.
Covalent organic frameworks (COFs) exhibit outstanding structural tunability, clearly defined ion pathways, and remarkable thermal/chemical stabilities, rendering them highly promising candidates for applications in solid-state electrolytes. However, it remains a challenge to develop a versatile method to incorporate both ionic groups and electron-withdrawing units into a single framework for effectively improving the lithium-ion conductivity. Herein, a series of novel [3+3] defective COFs is successfully synthesized featuring active amine/aldehyde anchoring sites for subsequent post-modification, and regulates the ion conductivity through elaborately tuning the anionic/cationic groups and weak/strong electron-withdrawing units.
View Article and Find Full Text PDFHigh Performance Sulfide Solid-State Battery Electrolytes Regulation Mechanism: A Review.
Angew Chem Int Ed Engl
September 2025
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, China.
Sulfide solid electrolytes (SEs) exhibit excellent ionic conductivity and good mechanical properties, but their poor air stability and solid-solid contact performance seriously hinder the wide application of sulfide all-solid-state batteries (ASSBs). Herein, this paper reviews the history and the major breakthroughs in the development of sulfide SEs. The theories of hard-soft-acid-base theory and glass structure theory, as well as several strategies to improve the chemical stability of sulfide SEs, are discussed emphatically.
View Article and Find Full Text PDFA solid-state battery capable of 180 C superfast charging and 100% energy retention at -30 °C.
Proc Natl Acad Sci U S A
September 2025
Department of Materials Science and Engineering, City University of Hong Kong, Kowloon, Hong Kong 999077, China.
Solid-state electrolytes (SSEs) are being extensively researched as replacements for liquid electrolytes in future batteries. Despite significant advancements, there are still challenges in using SSEs, particularly in extreme conditions. This study presents a hydrated metal-organic ionic cocrystal (HMIC) solid-state ion conductor with a solvent-assisted ion transport mechanism suitable for extreme operating conditions.
View Article and Find Full Text PDFSolid-State Supercapacitors with Enhanced Performance Using Al-Doped Li Ion Perovskite Electrolyte Integrated with Carbon Aerogel Electrode.
ACS Omega
September 2025
Department of Physics, Birla Institute of Technology and Science, Pilani, Pilani Campus, Vidya Vihar, Pilani, Rajasthan 333031, India.
We report the performance of solid-state ceramic supercapacitors (SSCs) based on a novel composite electrolyte comprising aluminum-doped lithium lanthanum titanate perovskite, LiLaTiAlO (Al-doped LLTO), and the ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIM BF). Rietveld refinement of X-ray diffraction data confirms the preservation of the tetragonal perovskite phase after Al substitution, indicating structural stability of the host lattice. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy further corroborate the successful incorporation of Al without forming secondary phases.
View Article and Find Full Text PDF