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Self-powered ultraviolet photodetectors hold significant potential for diverse applications across both military and civilian fields. Owing to its wide bandgap, high electron mobility, and adaptability to various substrates, gallium oxide (GaO) serves as a crucial material for fabricating self-powered ultraviolet photodetectors. Photodetectors based on p-n heterojunctions of conductive polymers and gallium oxide have great application potential benefiting from unique advantages of conductive polymers. This review provides an extensive overview of typical ultraviolet photodetectors based on conductive polymer/gallium oxide heterojunctions, focusing on the physical structure, fabrication process, and photoelectric properties of heterojunction devices formed by GaO with conductive polymers like polythiophene, polyaniline, and polycarbazole, etc. Different conductive polymers yield varying performance improvements in the fabricated devices: polythiophene/GaO devices exhibit high conductivity and flexible bandgap tuning to meet diverse wavelength detection needs; PANI/GaO devices feature simple fabrication and low cost, with doping control to enhance charge carrier transport efficiency; polycarbazole/GaO devices offer high thermal stability and efficient hole transport. Among them, the polythiophene/GaO device demonstrates the most superior overall performance, making it the ideal choice for high-performance GaO-based photodetectors and a representative of such research. This review identifies the existing technical challenges and provides valuable insights for designing more efficient GaO/conductive polymer heterojunction photodetectors.
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http://dx.doi.org/10.3390/polym17101384 | DOI Listing |
ACS Nano
September 2025
School of Microelectronics, University of Science and Technology of China, Hefei, Anhui 230026, China.
Superlinear photodetectors hold significant potential in intelligent optical detection systems, such as near-field imaging. However, their current realization imposes stringent requirements on photosensitive materials, thereby limiting the flexibility of the device integration for practical applications. Herein, a tunable superlinear GaO deep-ultraviolet gate-all-around (GAA) phototransistor based on a p-n heterojunction has been proposed.
View Article and Find Full Text PDFNano Lett
September 2025
Department of Chemical and Biological Engineering, Seoul National University, Seoul 08826, Republic of Korea.
Lateral homojunction photodetectors (PDs) offer high responsivity and fast response, yet challenges in tailoring carrier concentrations in two-dimensional transition-metal dichalcogenides (TMDs) have limited their implementation. Here, we demonstrate a high-performance self-powered monolithic lateral p-i-n homojunction PD using multilayer WS. To our knowledge, this study is the first report of achieving tunable, multilevel compensation doping via WO formation using only time-controlled and region-selective ultraviolet (UV)/ozone oxidation.
View Article and Find Full Text PDFNat Commun
September 2025
State Ley Laboratory of Integrated Optoelectronics, Key Laboratory for UV Light-Emitting Materials and Technology of Ministry of Education, School of Physics, Northeast Normal University, Changchun, China.
Single-pixel imaging is emerging as a promising alternative to traditional focal plane array technologies, offering advantages in compactness and cost-effectiveness. However, the lack of solar-blind photodetectors combining fast-response and high-sensitivity has constrained their application in the deep ultraviolet spectrum. This work introduces a self-powered solar-blind photodetector based on a heterostructure comprising a GaO photosensitive layer, an AlN barrier layer, and an N-polar AlGaN:Si contact layer.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
State Key Laboratory of Silicon and Advanced Semiconductor Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China.
Organic photodetectors (OPDs) have great potential in optical communication and biomedical imaging. Wavelength-selective response can be achieved by employing filter-free OPDs with various organic semiconductors. Herein, solution-processed OPDs are fabricated with typical electron acceptors (i.
View Article and Find Full Text PDFHexagonal boron nitride (hBN) and Al-doped BxAl1-xN films were grown on Si(100) substrates by means of a radio frequency magnetron sputtering technique. These films have been fabricated into hBN/Si and BAlN/Si heterojunctions, respectively. The heterojunction of hBN/Si exhibited an excellent response to vacuum ultraviolet (VUV) light at 185 nm.
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