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The integration of satellite-based observations into hydrological models contributes to achieving more precise simulations, thus supporting hazard mitigation and policy-making especially in poorly gauged basins. Sub-monthly Terrestrial Water Storage (TWS) observations derived from the Gravity Recovery and Climate Experiment (GRACE) mission have been shown to contain useful information for the prediction and monitoring of sub-monthly water storage anomalies such as floods. This study assesses, for the first time, the benefits and challenges of integrating sub-monthly TWS into a large-scale hydrological model during flood events. The experiment is carried out for the Brahmaputra River Basin and the integration is performed through the state-of-the-art of sequential Data Assimilation (DA) with the aim of improving model water storage estimates. The results indicate that the daily TWS DA, based on the Ensemble Kalman Filter (EnKF), successfully introduces the observed sub-monthly TWS variability into the model (differences below 10 mm with daily GRACE TWS). The daily TWS DA spatially and vertically downscales storage updates with precise timing and distribution. Especially, it modifies the river storage compartment, where sub-monthly variations are expected during floods. In contrast, the updates of monthly TWS DA, implemented through both an EnKF and an Ensemble Kalman Smoother (EnKS), introduce undesired peaks in the TWS time series. Choosing an adequate model covariance localization is found to be crucial for daily TWS DA. Finally, the statistical characteristics of the daily TWS DA and the translation of water storage updates into river discharge are investigated, and recommendations for future developments are provided.
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http://dx.doi.org/10.1016/j.scitotenv.2025.179181 | DOI Listing |
J Sci Food Agric
September 2025
College of Food Science & Technology, Shanghai Ocean University, Shanghai, China.
Background: Kaempferol (KAE), a bioactive flavonoid, has limited solubility and stability in water. Zein-gum arabic (GA) nanoparticles (NPs) are promising carriers for KAE, but the influence of preparation methods on their structure and properties remains unclear. This study investigated the effect of preparation method on the structure and properties of KAE-loaded zein-GA NPs.
View Article and Find Full Text PDFFood Chem X
August 2025
School of Life Science, Anqing Normal University, Jixian North Road1318, Yixiu District, Anqing 246052, Anhui Province, China.
Frozen storage deteriorates the texture and digestibility of frozen rice dough by damaging gliadin structure and starch integrity. This study investigated carboxymethyl chitosan (CMCh) and sodium carboxymethyl cellulose (CMCNa) as cry-oprotectants to mitigate these effects. Comprehensive analysis utilizing nuclear magnetic resonance (NMR), texture profile analysis (TPA), dynamic contact angle measurement (DCAT21), reversed-phase high-performance liquid chromatography (RP-HPLC), and circular dichroism (CD) demonstrated that 1.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
School of Chemistry and Life Resources, Renmin University of China, Beijing, 100872, China.
Through molecular dynamics simulations of imidazolium-based ionic liquid-water mixtures, it was found that the trace water leads to an anomalous non-monotonic change in the diffusion coefficients of ionic liquid, characterized by an initial decrease followed by an increase. Hydrogen bond analysis revealed that this unusual trend is governed by the weighted hydrogen bond lifetime, reflecting the stability of the hydrogen-bond network, rather than simply the number or energy of hydrogen bonds.
View Article and Find Full Text PDFJ Hazard Mater
September 2025
Key Laboratory of Northwest Water Resource, Environment and Ecology, MOE, Xi'an University of Architecture and Technology, Xi'an 710055, PR China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, PR China; Collaborative Innovation Ce
Rainfall events significantly increase dissolved organic matter (DOM) and disinfection by-product (DBP) precursors in the reservoir, threatening water supply security. However, the vertical variations and ecological drivers of DBP precursors in the deepwater stratified reservoir during rainfall events remain poorly understood. This study investigated DOM composition, DBP precursors, nutrients, metals, and algae in the Sanhekou Reservoir under stormwater influence.
View Article and Find Full Text PDFJ Phys Chem A
September 2025
Department of Basic Science, School of Arts and Sciences, The University of Tokyo, Komaba, Meguro, Tokyo 153-8902, Japan.
Desorption processes of HO molecules from AlO(HO) ( = 3, 5, 7) and AlO(HO)H ( = 4, 6, 8) clusters were investigated using gas-phase thermal desorption spectrometry to evaluate the HO storage capacity and mechanisms of aluminum oxide clusters. The clusters stored approximately 10 HO molecules at ∼300 K, depending on the size (), and released them upon heating. Even after heating to ∼1000 K, 2-4 HO molecules remained bound.
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