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Polylactic acid (PLA), derived from renewable resources, has the advantages of rigidity, thermoplasticity, biocompatibility, and biodegradability, and is widely used in many fields such as packaging, agriculture, and biomedicine. The excellent processability properties allow for melt processing treatments such as extrusion, injection molding, blow molding, and thermoforming in the preparation of PLA-based materials. However, the low toughness and poor thermal stability of PLA limit its practical applications. Compared with pure PLA, conditions such as processing technology, filler, and crystallinity affect the mechanical properties of PLA-based materials, including tensile strength, Young's modulus, and elongation at break. This review systematically summarizes various technical parameters for melt processing of PLA-based materials and further discusses the mechanical properties of PLA homopolymers, filler-reinforced PLA-based composites, PLA-based multiphase composites, and reactive composite strategies for PLA-based composites.
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http://dx.doi.org/10.1002/marc.202400380 | DOI Listing |
Phys Chem Chem Phys
September 2025
Department of Physics, Mizoram University, Aizawl-796004, India,.
It is anticipated that wide-bandgap semiconductors (WBGSs) would be useful materials for energy production and storage. A well-synthesized, yet scarcely explored, diamond-like quaternary semiconductor LiZnGeS has been considered for this work. Herein, we have employed two well-known functionals GGA and mGGA within a framework of density functional theory (DFT).
View Article and Find Full Text PDFNanoscale
September 2025
College of Physics, Hebei Normal University, Shijiazhuang 050024, China.
MoSe nanosheet/Si heterojunction photodetectors were fabricated by a mechanical exfoliation method, and their electrical and optical properties at different temperatures were investigated. It was found that the MoSe nanosheet/Si heterojunction device exhibited excellent rectification characteristics at room temperature, and the rectification ratio gradually decreased with the decrease of temperature. The temperature-dependent electrical properties of the MoSe/Si heterojunction device were actually caused by the inhomogeneity of the potential barrier.
View Article and Find Full Text PDFInorg Chem
September 2025
Malta-Consolider Team and Department of Analytical and Physical Chemistry, University of Oviedo, Oviedo E-33006, Spain.
Hydrated magnesium sulfates (MgSO·HO) are known to form multiple hydration states ( = 0-11) and are essential in planetary science and thermochemical energy storage. Despite their significance in detecting extraterrestrial water reservoirs or in mineral (de)hydration cycles, it is still necessary to understand how the structure-property relationships of these materials evolve at different hydration levels when pressure is applied. Through a systematic first-principles computational investigation, we elucidate the key structural factors governing the densification mechanism under hydrostatic pressure of MgSO·HO crystals.
View Article and Find Full Text PDFLab Chip
September 2025
Department of Engineering Design, Indian Institute of Technology Madras, India.
Microfluidic devices offer more accurate fluid flow control and lower reagent use for uniform nanoparticle synthesis than batch synthesis. Here, we propose a microfluidic device that synthesizes uniform iron oxide nanoparticles (IONPs) for highly efficient intracellular delivery. The 3D-printed device was fabricated, comprising two inlets in the T-shaped channel with an inner diameter of 2 mm, followed by a helical mixing channel with a single outlet.
View Article and Find Full Text PDFLangmuir
September 2025
Institute of Technology for Carbon Neutralization, Yangzhou University, Yangzhou 225127, Jiangsu, China.
To expand the application scope of carbon steel, imparting superhydrophobicity to its surface offers an effective strategy to overcome its inherently poor corrosion resistance. However, in marine environments, conventional superhydrophobic coatings often suffer from limited mechanical durability and inadequate long-term corrosion protection. In this study, a durable superhydrophobic bilayer coating composed of PDMS-MWCNTs (top layer) and PDMS (bottom layer) was developed to address these challenges.
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