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Article Abstract
Herein, we report a twisted cubic Cu(I)Ti(IV)-oxo cluster stabilized by - formed 2,2'-biphenolate ligands from the oxidative coupling of phenols. The 2,2'-biphenolate-functionalized Cu(I)Ti(IV)O cluster shows short Cu⋯C contacts and exhibits smaller HOMO-LUMO gaps than those of reported Ti(IV)O.
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