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Transition metal nitride (TMNs) electrocatalysts have attracted tremendous attentions for their unique electron structure, high activity, and excellent stability. Herein, a two-dimensional (2D) graphene-like structured nickel-molybdenum nitride (Ni-MoN) on nickel foam (NF), is prepared via facile hydrothermal and following nitridation process. The as-prepared Ni-MoN-450 (pyrolysis at 450 °C) displays good hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) performances in alkaline media. Only 22 mV and 117 mV are needed to achieve current densities of 10 mA cm and 500 mA cm in 1.0 M KOH, respectively, toward HER. The assembled two-electrode system, with the synthesized Ni-MoN-450 as the anode and cathode, exhibits good performance to achieve 1000 mA cm in 1.0 M KOH + 25 °C and 6.0 M KOH + 80 °C. Moreover, it also presents long-term stability under large-current density, which verified its robust property.
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http://dx.doi.org/10.1016/j.jcis.2023.01.069 | DOI Listing |
Phys Chem Chem Phys
August 2025
Department of Mathematics and Physics, Nanjing Institute of Technology, Nanjing 211167, China.
Exploring graphene-like two-dimensional materials with exceptional electro-optical properties is highly appealing for optoelectronic devices. Utilizing the PBE + + BSE method, the stability and electro-optical properties of a new h-BCN monolayer were investigated systematically, as well as the effects of strain. The h-BCN monolayer was dynamically stable in a broad range of strain and possessed a moderate indirect bandgap.
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2025
College of Physics, Hebei Key Laboratory of Photophysics Research and Application, Hebei Normal University, Shijiazhuang 050024, China.
Transition metal monoxides (MOs) have long been recognized for their versatile electronic and catalytic properties, yet their two-dimensional (2D) forms remain largely unexplored. In this study, we theoretically design a bilayer MO sheet featuring a graphene-like hexagonal lattice. Through systematic screening of various transition metals, we identify nine stable MO bilayers.
View Article and Find Full Text PDFMaterials (Basel)
July 2025
Materials Research Group, Ceará Center for Technology and Industrial Quality (NUTEC), Fortaleza 60440-552, CE, Brazil.
In this study, flotation tests were conducted on a laboratory scale using a sample of microcrystalline graphite ore from the Canindé region, Ceará, Brazil. The objective was to investigate the grinding time, reagent dosage, and purification process for obtaining graphene-based nanomaterials. Natural graphite has a stacked planar structure and exhibits polymorphism with rhombohedral, hexagonal, and turbostratic geometries, characteristics that directly influence its properties and technological applications.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2025
School of Materials Science and Engineering, Anhui University of Technology, Maanshan, Anhui 243002, China; Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen & Electricity of Anhui Province, Maanshan, Anhui 243002, China. Electronic address:
Two-dimensional (2D) transition metal carbides (a MXene material) have garnered significant attention owing to their exceptional catalytic performance in magnesium-based hydrogen storage systems. However, existing studies on metal-based MXene catalysts have predominantly focused on elucidating how multivalent metal species facilitate hydrogen transport pathways, while largely neglecting the structural configuration, spatial distribution, and mechanistic roles of carbon components within these materials. Herein, we first study the intrinsic mechanism of in situ hydrogenolysis-engineering of representative Ti-based MXene (TiC) systems based on density functional theory (DFT) calculations.
View Article and Find Full Text PDFPhys Chem Chem Phys
June 2025
School of Physics, Shandong University, Jinan 250100, China.
In this study, we theoretically investigate the magnetoelectric and magnetoelastic properties of the novel two-dimensional magnetic material CrP with two different structures, among which the graphene-like CrP structure exhibits ferromagnetism. Interestingly, its perpendicular magnetic anisotropy and magnetic ground state are sensitive to external pressure, exhibiting magnetic switching behavior. The system exhibits half-metallic properties, but the magnetic changes induced by external mechanical strain and electronic properties show multifaceted coupling phenomena.
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