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Article Abstract
The new compound [(NC)Ru(ap)](μ-1,4-CH) (ap = 2-anilinopyridinate) was prepared to address the open question of whether a 1,4-phenylene bridge can mediate intermetallic electronic coupling. As a manifestation of strong coupling, hole delocalization between the Ru centers on the IR time scale (10 s) was established using spectroelectrochemistry. An orbital mechanism for coupling was elaborated with DFT analysis.
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