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Development of materials that serve as efficient blue emitters in solution-processable OLEDs is challenging. In this study, we report three derivatives of -symmetric 1,3,5-tris(thien-2-yl)benzene-based highly luminescent room temperature columnar discotic liquid crystals (DLCs) suitable as solid-state emitters in OLED devices. When employed in solution-processed OLEDs, one of the derivatives having the highest photoluminescence quantum yield exhibited a maximum EQE of 4.7% and CIE chromaticity of (0.16, 0.05) corresponding to the ultra deep-blue emission. The finding is sufficiently significant in the field of DLC-based deep blue emitters.
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http://dx.doi.org/10.1039/d1sm01558c | DOI Listing |
ACS Appl Mater Interfaces
September 2025
School of Chemistry & Materials Engineering, Fuyang Normal University, Fuyang 236037, China.
Halide perovskite quantum dots (QDs) have demonstrated outstanding performance in light-emitting applications. However, the performance of blue perovskite QDs lags far behind that of their red and green counterparts, especially those with color coordinates approaching (0.131, 0.
View Article and Find Full Text PDFChemistry
August 2025
Fachbereich Physik, Universität Konstanz, 78457, Konstanz, Germany.
We report on the new star-shaped triazatruxene (TAT) tetrad 1, where three peripheral TAT moieties connect to a central TAT through propargylic spacers. The insulating nature of the linkers results in separate, partially overlapping blue and yellow-orange emissions from the peripheral and central TATs. This renders 1 a multicolor emitter, whose emission color can be tuned by the choice of the excitation wavelength and the solvent.
View Article and Find Full Text PDFSci Rep
August 2025
School of Microelectronics, Shanghai University, Shanghai, 201899, China.
The blue-green light micro light-emitting diode (Micro-LED) based on Augmented Reality Heads-up Display (AR-HUD) requirements is designed using COMSOL software, and the photo-thermal properties of Micro-LED are coupled with multi-physical fields. By designing the addition of graphene film combined with heat sink for heat dissipation, the thermal management scheme of Micro-LED is further optimized, and the effect of graphene film thickness on the heat dissipation performance is investigated to improve the photoelectric conversion efficiency and reduce the effect of high junction temperature on the performance and reliability of the device. The main factors affecting the performance of a thin graphene emitter are the source power input and the source-emitter contact area ratio, where the thermal performance changes more obviously with increasing power input and decreasing area ratio.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), Guangxi Key Laboratory of Chemistry and Molecular Engineering of Medicinal Resources, University Engineering Research Center for Chemistry of Characteristic Medicinal Resources (Guangxi),
This study presents the synthesis of a gadolinium-based metal-organic framework (Gd-MOF) via coordination between Gd ions and 1,2,4,5-tetrakis (4-carboxyphenyl) benzene (HTCPB). Gd-MOF demonstrated pronounced aggregation-induced electrochemiluminescence (AIECL) performance. With potassium persulfate (KSO) as a co-reactant, Gd-MOF exhibited a significantly stronger and more stable cathodic electrochemiluminescence (ECL) response, with improved ECL efficiency compared with the HTCPB ligand alone.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2025
Shenzhen Key Laboratory of New Information Display and Storage Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, P.R. China.
The organic light-emitting diode (OLED) performance of multi-resonance thermally activated delayed fluorescence (MR-TADF) emitters is fundamentally constrained by their slow reverse intersystem crossing (RISC) and pronounced aggregation-caused quenching (ACQ). Herein, through regioselective borylation, we design and synthesize a series of blue MR-TADF emitters. The regioisomerization-directed twist configuration synergistically enhances RISC while suppressing ACQ, without compromising spectral purity.
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