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Optical anti-counterfeiting and encryption have become a hotspot in information security. However, the advanced optical anti-counterfeiting technology still suffers from low security by single-luminescent mode. Herein, we present a novel multi-mode anti-counterfeiting strategy based on KLuSiO: Tb/Bi (KLSO: Tb/Bi) phosphors for the first time. KLSO not only provides various lattice sites for Bi ions occupying to achieve tunable luminescence but can also be non-equivalently substituted by Tb ions to produce persistent or thermo-luminescence. Furthermore, in the pattern "8888" constructed by the mixture of polyacrylic acid (PAA) with KLSO: Tb/Bi phosphors, we selectively trigger the three luminescent modes of Bi and Tb ions to realize the design of differential display in the fields of thermal response, time resolution, and luminescence color for optical anti-counterfeiting. The differentiated display can only be presented under specific multi-stimuli response, which further improves the security of information. Our work provides a new insight for designing advanced materials and can be expected to inspire future studies to explore optical anti-counterfeiting technology.
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http://dx.doi.org/10.1016/j.jcis.2021.10.046 | DOI Listing |
The development of novel optical self-healing materials holds significant importance for applications in anticounterfeiting and information encryption, but remains a formidable challenge. This study presents a fluorescent self-healing material designed for 2D/3D printing anticounterfeiting applications, exhibiting outstanding properties such as high transmittance, excellent mechanical strength, and remarkable self-healing efficiency. The triple dynamic bond networks provide robust mechanical and self-healing capabilities, with the polymer demonstrating a tensile strength of 26.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
School of Materials Science and Engineering, Changchun University of Science and Technology Changchun, 130022, Jilin, People's Republic of China.
The synergistic effect of various ions with optical properties is an important method to regulate the Er ion upconversion luminescence process. However, the energy processes between them are complicated and difficult to separate, and it is challenging to clarify the results of each process when multiple ions are co-doped. Herein, a series of NaYF:Er were synthesized by the low-temperature combustion method, and the luminescence color of Er ions was modulated by doping Yb ions and Tm ions.
View Article and Find Full Text PDFNat Mater
September 2025
Department of Physics, University of Colorado, Boulder, CO, USA.
Time crystals are unexpected states of matter that spontaneously break time-translation symmetry either in a discrete or continuous manner. However, spatially mesoscale space-time crystals that break both space and time symmetries have not been reported. Here we report a continuous space-time crystal in a nematic liquid crystal driven by ambient-power, constant-intensity unstructured light.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
College of Science, Northeastern University, Shenyang, Liaoning 110819, China.. Electronic address:
Constructing perovskite heterostructures with restricted interface charge transfer is crucial for improving stability and optoelectronic performance, as well as expanding multifunctional applications. Herein, a one-step solvent-free thermal assisted epitaxial growth strategy is proposed to construct BaMoO/CsPbX (X = Cl, Br, I) heterostructures. Derived from the high lattice matching of 90.
View Article and Find Full Text PDFNanoscale
September 2025
Department of Materials Science and Engineering, Indian Institute of Technology Delhi, New Delhi 110016, India.
Quantum dots (QDs) have garnered significant attention for their unique size-dependent optical and electronic properties, enabling their widespread use in applications ranging from high-efficiency photovoltaics and light-emitting diodes to biomedical imaging and quantum computing. Their tunable emission, high photo-stability, and ease of surface modification make them ideal candidates for precision nanotechnology applications. In this work, we explore a novel and rapidly emerging application of QDs in hardware security through the development of Quantum Dot-based Physical Unclonable Functions (QD-PUFs).
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