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Efficient electrocatalysts are in great demand for renewable energy storage systems. Herein, we propose an ultrafast heating strategy to fabricate an efficient Ir/CP-UH catalyst for the oxygen evolution reaction (OER). Experimental results demonstrated that the ultrasmall Ir nanoparticles (≈1-3 nm) and clusters (<1 nm) were highly dispersed on the carbon paper support after a short thermal shock (∼5 s). The catalyst showed a low overpotential of 260 mV at 10 mA cm-2 and remarkable mass activity of about 13.8 times higher than that of the current state-of-the-art commercial Ir/C catalyst. This ultrafast heating strategy can also be applied to other catalyst systems for OER and other electrochemical reactions.
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http://dx.doi.org/10.1039/d1cc01999f | DOI Listing |
Chemistry
September 2025
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing, 102249, China.
This study introduces the HydroTherm-Flow Smart Window (HTF Window), the first groundbreaking integration of thermochromic windows and Fe-Cr redox flow batteries (Fe-Cr RFBs), achieving dual functionalities of dynamic solar modulation-via dual-band (visible + near-infrared, NIR) modulation-and high-efficiency energy storage in a single component. Leveraging tunable hydroxypropyl cellulose (HPC) hydrogels, it enables ultrafast optical switching and autonomous nighttime opacity, overcoming the slow response and privacy limitations of conventional thermochromic systems. By repurposing the window as a compact electrolyte reservoir, it reduces the RFB spatial footprint while enhancing ionic conductivity by 30% via hydrogel "ion highways," achieving 77% energy efficiency with a 40% reduction in the solar heat gain coefficient.
View Article and Find Full Text PDFAdv Sci (Weinh)
September 2025
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, School of Materials Science and Engineering, South China University of Technology, Guangzhou, Guangdong, 510640, P. R. China.
Inspired by the electron-withdrawing ability of nitroxide radicals, a novel open-shell material, EDOT-TPAO is reported, synthesized via one-step demethylation and oxidation of its closed-shell precursor, EDOT-TPAOMe. Time-dependent density functional theory calculations confirm an acceptor-donor-acceptor configuration of EDOT-TPAO where radical termini act as electron acceptors. This structural transformation narrows the optical bandgap from 2.
View Article and Find Full Text PDFNat Commun
August 2025
Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, Jena, Germany.
The field of computationally controlled light faces a strong demand for new platforms capable of providing adaptable light generation to meet the requirements of advanced photonic technologies. Here, we present the concept of computationally optimized nonlinear frequency conversion in programmable liquid-core fibers that enables real-time tunable and reconfigurable nonlinear power distribution through computationally optimized dispersion landscapes. The concept combines a temperature-sensitive mode in a liquid-core fiber, particle swarm optimization, fission of ultra-fast solitons, and a computer-controlled heating array to create a feedback loop for controlling output spectra via local temperature-induced dispersion modulation.
View Article and Find Full Text PDFInorg Chem
September 2025
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, Guangdong 519082, P. R. China.
Convenience, sensitivity, and selectivity are of great significance for water detection in environmental monitoring and industrial processes. We have synthesized two 0D hybrid manganese halides [CHN]MnBr and [CHN]MnBr·HO, which undergo sensitive reversible transition between green and red emission driven by reversible uptake/removal of coordination water molecules stimulated by being exposed to a high-humidity atmosphere/mildly heated at 60 °C. The former structure has a high photoluminescence quantum yield (PLQY) of 81%.
View Article and Find Full Text PDFACS Nano
August 2025
State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China.
Photocatalytic reduction of uranium from wastewater containing high concentrations of fluoride is crucial from both environmental and sustainability perspectives. However, the coordination of fluorine and uranyl ions to U(VI)-F complexes with high bond strengths poses challenges for photocatalysts. Electrostatic interactions induced by photocatalysis to dissociate U(VI)-F complexes provide an effective method for the extraction of uranium from wastewater containing fluorine.
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