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Although the theoretical energy density of lithium-oxygen batteries is extremely high, pulverization of lithium metal anode obviously influences batteries cycling performance. In this work, the cathode was coated with a membrane to protect the lithium anode from moisture attacking and avoid the pulverization. The membrane is composed of polyethylene oxide and poly tetra fluoroethylene, which improves the cycle life of the lithium-oxygen batteries cycles to 230 times, with a limited specific capacity of 1000 mAh·g, at a current density of 100 mA·g. Furthermore, the batteries perform stable charge and discharge cycles for 55 times in the air atmosphere, with the relative humidity greater than 50%. It demonstrates this strategy provides a new direction for the development of high-performance lithium-oxygen batteries.
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http://dx.doi.org/10.1016/j.jcis.2020.09.096 | DOI Listing |
ACS Nano
September 2025
Key Laboratory of Eco-chemical Engineering, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China.
Development of aprotic lithium-oxygen (Li-O) batteries suffers from slow cathode reaction kinetics, numerous side reactions, and large polarization, which are intimately related to the discharge product of LiO. Here, we designed and prepared a modified CoO nanoparticle with atomic Ru substitution at octahedral Co sites supported by carbon nanocages (RuCoO@HCNs) as a cathode catalyst. The asymmetrical octahedral Ru-O-Co units trigger a strong electron coupling effect, leading to charge redistribution and optimization of the d-orbital energy levels, thus facilitating oxygen activation and conversion into superoxide anions during discharging.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
School of Energy, Soochow University, Suzhou 215006, China. Electronic address:
The lithium‑oxygen battery (LOB) has emerged as an appropriate candidate for next-generation power supply system, owing to the ultrahigh theoretical energy density (3480 Wh kg) and relatively low cost. However, some intrinsic challenges, including high redox overpotentials, limited rate capability, and poor cyclic life, continue to hinder the practical deployment of lithium‑ oxygen batteries. The fundamental limitations originate from sluggish oxygen reduction/evolution reaction (ORR/OER) kinetics and parasitic side reactions, which can be effectively mitigated by employing efficient cathode electrocatalysts.
View Article and Find Full Text PDFNanomicro Lett
September 2025
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan, 250061, People's Republic of China.
CoS electrocatalysts with mixed valences of Co ions and excellent structural stability possess favorable oxygen evolution reaction (OER) activity, yet challenges remain in fabricating rechargeable lithium-oxygen batteries (LOBs) due to their poor OER performance, resulting from poor electrical conductivity and overly strong intermediate adsorption. In this work, fancy double heterojunctions on 1T/2H-MoS@CoS (1T/2H-MCS) were constructed derived from the charge donation from Co to Mo ions, thus inducing the phase transformation of MoS from 2H to 1T. The unique features of these double heterojunctions endow the 1T/2H-MCS with complementary catalysis during charging and discharging processes.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
Department of Materials Science and Engineering, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 61186, South Korea. Electronic address:
A composite quasi-solid-state electrolyte (QSE) integrating sulfonated poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and silicon dioxide (SiO) nanofillers is developed for lithium‑oxygen (Li-O) batteries. The inclusion of SiO nanofillers into the host polymer matrix helps in retaining the liquid electrolyte, enhancing ionic conductivity, mechanical stability, and structural integrity. Sulfonation of PVDF-HFP improves lithium-ion transport, reduces the shuttle effect of the lithium iodide (LiI) redox mediator, and suppresses lithium dendrite growth through uniform lithium deposition.
View Article and Find Full Text PDFRSC Adv
August 2025
Department of Advanced Materials Science and Engineering, Mokpo National University 61 Dorim-ri, 1666 Yeongsan-ro, Cheonggye-myeon, Muan-gun 58554 Jeonnam South Korea
The development of high-performance lithium-oxygen (Li-O) batteries is hindered by challenges including high overpotential and limited cycle life. In this paper, we report the cost-effective and scalable synthesis of a ZnO electrocatalyst directly integrated onto carbon paper a simple dipping and thermal treatment method. The resulting ZnO-on-carbon composite (ZnO on P50) was employed as the cathode in a non-aqueous Li-O battery.
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