Potential release of legacy nitrogen from soil surrounding onsite wastewater leaching pools.

This study examined whether the accumulation of nitrogen (legacy nitrogen) within and surrounding leaching pools for onsite wastewater treatment may act as a source of nitrogen contamination to groundwater upon changes to the quantity and/or composition of the influent to the pool. In this study, one concrete leaching pool with neutral pH (A, pH 6.9) and one leaching pool after acid washing (B, pH 3.7) were selected to examine the quantity and composition of legacy nitrogen in the surrounding soil, as well as evaluate the potential release of this nitrogen under two environmentally relevant leaching scenarios: (i) the concrete leaching pool serves as the final discharge unit for aerobic treatment unit (ATU) effluent; (ii) extreme weather events (flash flood/heavy rains) act to increase the quantity and dilute the composition of flow to the pool. Core sample analysis showed that organic nitrogen accounts for the majority (97.3-99.7%) of the total nitrogen (TN) at site A (4.1 ± 0.6 mg N/g soil) and site B (3.0 ± 0.4 mg N/g soil); while ammonium was the major form of inorganic nitrogen present at the sites. The TN accumulated under the two leaching pools was equivalent to approximately 17-39 days of nitrogen loading to the system. pH had a significant impact on the mass of TN leached from the soil, while no significant difference in leached TN was observed for the two leaching scenarios. The amount of TN leached from the soil matrix was not affected by the flow rate (18.6 mL/d in scenario i vs. 547.2 mL/d in scenario ii) or flow pattern (intermittent dosing vs. continuous flow). The quantity of TN leached from soils in both scenario (i) and (ii) was low and accounted for 2.6-8.9% of the total nitrogen in the soil.