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In contrast to conventional heat treatment processes, electropulsing not only heats an alloy, but also exerts some other positive effects during the heating process. In this paper, the microstructural evolution and mechanical properties of a deformed Zr40Ti5Al4V alloy after electropulsing treatment were investigated. The results showed that when the charging voltage was 2 kV, there was a slight decrease in dislocation density due to the electron wind which softened the alloy even though the highest temperature of the specimen during the treatment was only 86 °C. Increasing the charging voltage to 6 kV not only further increased the heating temperature, but accelerated the phase transformation process of α″ → β → α. The presence of the α phase strengthened the alloy but notably deteriorated its ductility. A full and refined β phase microstructure could be obtained when the charging voltage was increased to 8 kV. This simultaneously increased the strength and ductility of the alloy.
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http://dx.doi.org/10.3390/ma12213560 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
College of Chemistry and Chemical Engineering, Institute of Interdisciplinary Studies, Hunan Normal University, Changsha 410081, China.
The oxygen evolution reaction (OER) in conventional zinc-air batteries (ZABs) involves a complex multielectron transfer process, leading to slow reaction kinetics, high charging voltage, and low energy efficiency. To address these limitations, a zinc-ethanol/air battery (ZEAB) system that strategically replaces the OER with the ethanol oxidation reaction (EOR) possessing a lower thermodynamic potential has been proposed. Herein, a bimetallic catalyst CuCo-embedded nitrogen-doped carbon (CuCo-20%-1), derived from a Cu/Co/Cd co-coordinated metal-organic precursor, is synthesized and exhibits an excellent performance for both EOR and ORR.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China. Electronic address:
Transition metal fluorides because of the high electronegativity of fluorine may enhance the local electron density of the metal sites and promote water molecule dissociation and charge transfer. However, enhancing the intrinsic activity of fluorides to improve material stability remains a challenge. Herein, we develop an innovative four-step synthetic strategy (electrochemical deposition → co-precipitation → ligand exchange → in situ fluorination) to engineer three-dimensional porous Fe-doped CoF nanocubes vertically anchored on MXene (Fe-CoF/MXene/NF).
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
School of Chemistry and Chemical Engineering, Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China.
Additive assisted strategies play a crucial role in optimizing the morphology and improving the performance of organic solar cells (OSCs), yet the molecular-level mechanisms remain unclear. Here, we employ molecular dynamics (AIMD) and density functional theory (DFT) to elucidate the influence of typical additives of 1,8-diiodooctane (DIO) and 3,5-dichlorobromobenzene (DCBB) on molecular packing, electronic structures, and charge transport. It can be observed that both additives can enhance the stacking properties of the donor and acceptor materials, yet they have different effects on the local electrostatic environment.
View Article and Find Full Text PDFChem Asian J
September 2025
School of Medical Information Engineering, Shenyang Medical College, Shenyang, Liaoning, 110043, P. R. China.
The rational design of electrode materials with outstanding energy and power density for supercapacitors (SCc) and high-performance electrocatalysts in alkaline media plays an indispensable role in the application of energy storage and overall water splitting. In this paper, we prepared NiCoFe layered ternary hydroxides (LTH) using a hydrothermal synthesis method. The sample with a Ni/Co/Fe ratio of 1:2:0.
View Article and Find Full Text PDFSmall
September 2025
Institute of Chemistry, Academia Sinica, Taipei, 115201, Taiwan.
Achieving high capacitance while maintaining rapid charge transport and structural stability remains a major challenge in the design of battery-type supercapacitor electrodes. Herein, a molecularly engineered strategy is presented for constructing hierarchical hybrid electrodes by integrating petal-like NiCu-LDH nanosheets onto 3D HBC-x (x = H, F, OMe)-functionalized CNT paper via a one-step hydrothermal process. The incorporation of HBC effectively mitigates CNT agglomeration and constructs an interconnected conductive framework that enhances charge transport, shortens ion diffusion paths, and reduces internal resistance.
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