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In this work, SiC and Cu particles were utilized to enhance the thermal and mechanical properties of Al matrix composites. The ball-milling and cold-compact methods were applied to prepare Al matrix composites, and the uniform distribution of SiC and Cu particles in the composite confirms the validity of our preparation method. After characterizing the thermal conductivity and the compressibility of the prepared composites, results show that small particles have a higher potential to improve compressibility than large particles, which is attributed to the size effect of elastic modulus. The addition of SiC to the Al matrix will improve the compressibility behavior of Al matrix composites, and the compressibility can be enhanced by 100% when SiC content is increased from 0 to 30%. However, the addition of SiC particles has a negative effect on thermal conductivity because of the low thermal conductivity of SiC particles. The addition of Cu particles to Al-SiC MMCs could further slightly improve the compressibility behavior of Al-SiC/Cu MMCs, while the thermal conductivity could be enhanced by about 100% when the Cu content was increased from 0 to 30%. To meet the need for low density and high thermal conductivity in applications, it is more desirable to enhance the specific thermal conductivity by enlarging the preparation pressure and/or sintering temperature. This work is expected to supply some information for preparing Al matrix composites with low density but high thermal conductivity and high compressibility.
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http://dx.doi.org/10.3390/ma12172770 | DOI Listing |
Int J Biol Macromol
September 2025
Jiangsu Provincial Key Lab for The Chemistry and Utilization of Agro-forest Biomass, Jiangsu Key Lab of Biomass Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China.
Aramid films are potential separator candidates for high-safety lithium-ion batteries (LIBs) due to their inherent flame retardancy and outstanding thermal stability. However, both weak liquid electrolyte wettability and poor mechanical properties of aramid separators for lithium-ion batteries result in low ionic conductivity and unsatisfactory electrochemical performance for LIBs. Herein, a novel asymmetric porous composite separator composed of a relatively dense nanocellulose (CNC) layer and a porous poly(m-phenylene isophthalamide) (PMIA) supporting layer has been fabricated by using a water-induced phase conversion process.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Key Laboratory of Bio-Based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin, 150040, China. Electronic address:
With the exhaustion of fossil fuels, prior phase change materials are characterized by such drawbacks as poor thermal conductivity, weak shape stability, and high costs. Therefore, the preparation of phase change materials with brilliant thermal-insulating properties, high thermal conductivity, and leakage-free properties has emerged as a crucial research focus. Herein, a sericultural mulberry branch-derived (SMB) composite phase change material was prepared by deep eutectic solvent pretreated SMB and vacuum-assisted impregnated paraffin wax with cupric oxide (CuO).
View Article and Find Full Text PDFAdv Mater
September 2025
Graduate School of Carbon Neutrality, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Ulsan, 44919, Republic of Korea.
Spiro-OMeTAD has remained the benchmark hole-transporting material (HTM) in state-of-the-art perovskite solar cells, owing to its favorable energy level alignment and excellent interfacial compatibility. However, its practical implementation is critically hindered by the intrinsic instabilities introduced by conventional dopants such as lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and 4-tert-butylpyridine (tBP). While these dopants enhance electrical conductivity, they concurrently initiate multiple degradation pathways-including ionic migration, radical deactivation, and moisture/thermal-induced morphological failure-thereby compromising device longevity and reproducibility.
View Article and Find Full Text PDFChemistry
September 2025
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing, 102249, China.
This study introduces the HydroTherm-Flow Smart Window (HTF Window), the first groundbreaking integration of thermochromic windows and Fe-Cr redox flow batteries (Fe-Cr RFBs), achieving dual functionalities of dynamic solar modulation-via dual-band (visible + near-infrared, NIR) modulation-and high-efficiency energy storage in a single component. Leveraging tunable hydroxypropyl cellulose (HPC) hydrogels, it enables ultrafast optical switching and autonomous nighttime opacity, overcoming the slow response and privacy limitations of conventional thermochromic systems. By repurposing the window as a compact electrolyte reservoir, it reduces the RFB spatial footprint while enhancing ionic conductivity by 30% via hydrogel "ion highways," achieving 77% energy efficiency with a 40% reduction in the solar heat gain coefficient.
View Article and Find Full Text PDFSmall
September 2025
Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials (MoE), National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), State Key Laboratory of Advanced Polymeric Materials, College of Chemistry, Sichuan University, Chengdu, 610064, China.
The LiAlTi(PO) (LATP)-polymer composite solid electrolyte offers environmental stability and safety for high-energy lithium metal batteries (LMBs), yet suffers from interfacial instability and high interfacial resistance. Herein, a Janus self-supporting skeleton (J-SSK) is engineered via multi-scale coupling of poly(vinylidene fluoride-trifluorethylene) (PVDF-TrFE), LATP, 2-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl) ureido) ethyl methacrylate (UPyMA) monomer, where intermolecular multiple hydrogen bonds reinforce mechanical robustness while the Janus structure isolates LATP from direct Li contact. In situ copolymerizing vinylene carbonate (VC) and UPyMA monomer in J-SSK to construct Janus composite quasi-solid electrolyte (J-CQSE) achieves seamless integration of electrode/electrolyte interfaces and establishes hierarchical coupling across J-SSK, polymer matrix, and lithium salts.
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