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A facile hydrothermal method to prepare In-doped CoO porous nanosheets is reported in this paper for the first time. The prepared samples were made into gas sensors, and their sensing properties, such as response, response time, recovery time, selectivity and stability, have been researched systematically. These results indicate that the sensor fabricated with 1.0 at% In-doped CoO porous nanosheets shows a high response of 6.81 to 50 ppm and an obvious response of 1.4 to 1 ppm HS. What's more, this sensor exhibited a high selectivity and outstanding long-term stability toward HS. The excellent gas sensing performance was mainly ascribed to two reasons. (i) Doping with In increases the concentration of charge carriers, oxygen-deficient regions and the chemisorbed oxygen, which enhances the gas response. (ii) The rough porous structure is conducive to gas adsorption and capture, and provides many active sites for the sensing reaction. Therefore, 1.0 at% In-doped CoO porous nanosheets could be used as a sensing material in future applications.
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http://dx.doi.org/10.1039/c9dt01043b | DOI Listing |
J Colloid Interface Sci
August 2025
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, Zhejiang, PR China. Electronic address:
The sluggish kinetics of the oxygen evolution reaction (OER) necessitate the use of efficient, non-precious metal catalysts. This work reports the rational design of an indium-doped bimetallic metal-organic framework (MOF-74-CoIn) as a precatalyst, achieved through post-synthetic modification of MOF-74-Co. Structural and spectroscopic analyses confirm that In(III) incorporation induces CoO bond contraction while preserves the overall structural integrity.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2022
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistryand Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China.
Selective methanol synthesis CO hydrogenation has been thoroughly investigated over defective In-doped m-ZrO using density functional theory (DFT). Three types of oxygen vacancies (Ovs) generated either at the top layer (O1_v and O4_v) or at the subsurface layer (O2_v) are chosen as surface models due to low Ov formation energy. Surface morphology reveals that O1_v has smaller oxygen vacancy size than O4_v.
View Article and Find Full Text PDFSmall
November 2019
School of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore, 637459, Singapore.
An efficient and low-cost electrocatalyst for reversible oxygen electrocatalysis is crucial for improving the performance of rechargeable metal-air batteries. Herein, a novel oxygen vacancy-rich 2D porous In-doped CoO/CoP heterostructure (In-CoO/CoP FNS) is designed and developed by a facile free radicals-induced strategy as an effective bifunctional electrocatalyst for rechargeable Zn-air batteries. The electron spin resonance and X-ray absorption near edge spectroscopy provide clear evidence that abundant oxygen vacancies are formed in the interface of In-CoO/CoP FNS.
View Article and Find Full Text PDFInorg Chem
August 2018
State Key Laboratory of Radiation Medicine and Protection, School for Radiological and interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions , Soochow University, Suzhou 215123 , China.
A luminescent lanthanide metal-organic framework [Tb(OH)(HO)(IDA)(COO)]·4Cl·2HO (Tb-IDA, IDA = iminodiacetic acid) was hydrothermally synthesized and structurally characterized. Monitoring ultraviolet radiation was achieved by correlating the dosage with the luminescence color change in doped GdTbEu-IDA compound. A linear relationship is developed across a broad range from blue to yellow within a CIE chromaticity diagram.
View Article and Find Full Text PDFInorg Chem
October 2008
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4 Canada.
Fast oxide ion conducting Ce 1- x M x O 2-delta (M = In, Sm; x = 0.1, 0.2) and Ce 0.
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