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In this paper, we developed a method of fabricating polymer microstructures at various angles on a single substrate via synchrotron X-ray lithography coupled with simple dimensional transformations. Earlier efforts to create various three-dimensional (3D) features on flat substrates focused on the exposure technology, material properties, and light sources. A few research groups have sought to create microstructures on curved substrates. We created tilted microstructures of various angles by simply deforming the substrate from 3D to two-dimensional (2D). The microstructural inclination angles changed depending on the angles of the support at particular positions. We used convex, concave, and S-shaped supports to fabricate microstructures with high aspect ratios (1:11) and high inclination angles (to 79°). The method is simple and can be extended to various 3D microstructural applications; for example, the fabrication of microarrays for optical components, and tilted micro/nanochannels for biological applications.
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http://dx.doi.org/10.3390/ma11081460 | DOI Listing |
J Chem Phys
September 2025
School of Mathematical and Physical Sciences, University of Sheffield, Hicks Building, Hounsfield Road, Sheffield S3 7RH, United Kingdom.
The development of the microstructure during polymeric spinodal decomposition can be monitored in real time using small-angle scattering. Information about the microstructure can be deduced from measurements of the structure factor-a quantity directly proportional to the scattered intensity. While the time evolution of the structure factor can be measured relatively easily, modeling it has proved to be much more difficult.
View Article and Find Full Text PDFJ Food Sci
September 2025
College of Light Industry and Food Technology, Zhongkai University of Agriculture and Engineering, Guangzhou, China.
To address post-harvest issues of litchi, including browning, water loss, and nutrient degradation, a moisture microenvironment-regulating electro spun membrane was prepared by incorporating hydrophobic carnauba wax (CW)@nano silica (SiO) composite powder into a polyethylene terephthalate (PET) matrix via electro spinning. The dynamic water penetration equilibrium was evaluated by monitoring the water vapor absorption of the electrospun membrane within 12 h, while the effects of CW@SiO on the micro-structure, mechanical properties, hydrophobicity, and thermal stability were investigated. Results showed that the tensile strength of the PET-2.
View Article and Find Full Text PDFACS Omega
August 2025
Institute for Polymers, Composites and Biomaterials (IPCB) U.O.S. of Catania, CNR, Via P. Gaifami 18, 95126 Catania, Italy.
This study explored the potential of blending poly-(ether sulfone)/disulfonated poly-(ether sulfone) (PES/SPES) at various weight ratios with and without polyvinylpyrrolidone (PVP) to enhance the membrane properties for potential applications like fuel cells, water treatment, and lithium-ion battery separators. SPES was appropriately synthesized as a copolymer constituted of alternated unsulfonated (ES) and disulfonated (SES) sequences, achieving a degree of sulfonation of about 100%. SPES improved the membrane's hydrophilicity, while PVP acts as compatibilizer of PES/SPES blends and pore creator.
View Article and Find Full Text PDFNanoscale
September 2025
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing 210023, China.
As the demand for renewable energy continues to rise, developing efficient solar energy harvesting technologies has become increasingly important. In this paper, we propose a plasmon absorber utilizing nanocavity arrays to achieve ultra-broadband absorption of solar energy. The results show that the absorber achieves an average absorption rate of 95.
View Article and Find Full Text PDFChemSusChem
September 2025
TUM School of Natural Sciences, Department of Physics, Chair for Functional Materials, Technical University of Munich, James-Franck-Str. 1, 85748, Garching, Germany.
Photocatalytic water splitting enables the generation of green hydrogen (H). In this framework, water and sunlight are the sustainable sources. Photocatalyst-loaded hydrogel materials have already shown their potential as a water storage and catalyst host matrix for H production.
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