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We test the common assumption that organic carbon (OC) storage occurs on sand-sized soil particles only after the OC storage capacity on silt- and clay-sized particles is saturated. Soil samples from a Brookston clay loam in Southwestern Ontario were analysed for the OC concentrations in bulk soil, and on the clay (<2 μm), silt (2-53 μm) and sand (53-2000 μm) particle size fractions. The OC concentrations in bulk soil ranged from 4.7 to 70.8 g C kg(-1) soil. The OC concentrations on all three particle size fractions were significantly related to the OC concentration of bulk soil. However, OC concentration increased slowly toward an apparent maximum on silt and clay, but this maximum was far greater than the maximum predicted by established C sequestration models. In addition, significant increases in OC associated with sand occurred when the bulk soil OC concentration exceeded 30 g C kg(-1), but this increase occurred when the OC concentration on silt + clay was still far below the predicted storage capacity for silt and clay fractions. Since the OC concentrations in all fractions of Brookston clay loam soil continued to increase with increasing C (bulk soil OC content) input, we concluded that the concept of OC storage capacity requires further investigation.
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http://dx.doi.org/10.1038/srep27173 | DOI Listing |
Sci Total Environ
September 2025
School of Civil Engineering, Sichuan Agricultural University, Chengdu, 611830, China; Sichuan Higher Education Engineering Research Center for Disaster Prevention and Mitigation of Village Construction, Sichuan Agricultural University, Chengdu, 611830, China.
Biochar has emerged as a promising soil amendment for improving soil quality and mitigating environmental impacts, such as nutrient leaching. This study evaluated the impacts of ball-milled bamboo nano-biochar on water infiltration dynamics, retention capacity, and nitrogen‑phosphorus leaching in sandy loam soil using controlled column experiments and leaching experiments with five application doses alongside bulk biochar and untreated controls. Experimental results demonstrated that nano-biochar application significantly enhanced soil water retention capacity compared to the raw soil.
View Article and Find Full Text PDFEnviron Technol
September 2025
College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, People's Republic of China.
The soil in reclaimed shale gas sites is compacted and suffers from issues like poor drainage, drought conditions, and nutrient deficiency, posing challenges for agricultural production. In this study, rare earth tailings were incorporated into biochar at different mass ratios (rare earth tailings: biochar = 1:1, 1:2, 1:3, 1:4). Subsequently, a series of rare earth tailings-doped biochar materials (REE-BC) were prepared by calcination at 700°C.
View Article and Find Full Text PDFNew Phytol
September 2025
State Key Laboratory of Nutrient Use and Management, College of Resources and Environmental Sciences, National Academy of Agriculture Green Development, China Agricultural University, Beijing, 100193, China.
Microbial nitrate ammonification is a crucial process to retain nitrogen (N) in soils, thereby reducing N loss. Nitrate ammonification has been studied in enrichment and axenic bacterial cultures but so far has been merely ignored in environmental studies. In particular, the capability of arbuscular mycorrhizal fungi (AMF) to regulate nitrate ammonification has not yet been explored.
View Article and Find Full Text PDFEnviron Sci Technol
September 2025
Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources, Ministry of Education, Wuhan University of Technology, Wuhan 430070, China.
Rapidly expanding nascent ecosystems at glacier forefields under climate warming dramatically enhance the terrestrial carbon (C) sink. Microbial C fixation and degradation, closely implicated in nitrogen (N) transformation and plant-soil-microbe interactions, significantly regulate soil C accumulation. However, how shifts in microbial functional potential impact soil C sequestration during vegetation succession remains unclear.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Pacific Northwest National Laboratory, Richland, Washington 99354, United States.
Water-ion interactions govern the physicochemical properties of aqueous solutions, impacting the structure of the hydrogen bonding network and ion diffusivities. To elucidate these effects under alkaline conditions relevant to diverse application spaces, we examined NaOD-DO solutions using two-dimensional infrared spectroscopy (2D-IR), small-angle X-ray scattering (SAXS), and nuclear magnetic resonance spectroscopy (NMR). Vibrational energy transfer between the donor anion SeCN, used as a 2D-IR probe, and the acceptor anion OD was used to track the average separation distance of ions in the DO solutions, while SAXS and NMR experiments measured the structure of the bulk DO solvent.
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