One-pot synthesis of ordered mesoporous silver nanoparticle/carbon composites for catalytic reduction of 4-nitrophenol.

J Colloid Interface Sci

College of Material Science and Engineering, Key Laboratory of Advanced Structural Materials, Ministry of Education, Changchun University of Technology, Changchun 130012, China. Electronic address:

Published: June 2014


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Article Abstract

Ordered mesoporous silver nanoparticle/carbon composites have been produced by a "one-pot" synthesis method. They have open mesopores (4.2-5.0 nm), large specific surface areas (465-584 m(2) g(-1)) and high pore volumes (0.29-0.50 cm(3) g(-1)) and contain stable, confined but accessible Ag nanoparticles. As a result, they show high performance in catalytic reduction of 4-nitrophenol (4-NP). The mesostructure and particle size as a function of Ag content were studied and correlated with the catalytic activity. The ordered mesoporous carbon framework and highly dispersed Ag nanoparticles make the material a novel system for effective contacting with the reactants and catalysis of the reaction.

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http://dx.doi.org/10.1016/j.jcis.2014.02.029DOI Listing

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